• 한국잠사곤충학회지
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• 제39권2호
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• pp.197-202
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• 1997

To hydrolyze silk fibroin was treated with NaOH solution on various concentrations and times. And it was examined that the addition effects of NaHSO3 solution on the solubility and colouring of silk fibroin. As obtained results are as follows; The more increasement of concentration and time of NaOH treatment, the more increasement of solubility but solubility was slight above 3% concentration of NaOH. Fibroin yield was decreased above 3% concentration. This was due to formation of peptide or amino acids below molecular weight 3,000. Most of molecular weight distribution came out to be under 3,000 in 2% concentration and 4hrs of NaOH treatment. The more increasement of adding concentration and 4hrs of NaOH treatment. The more increasement of adding concentration of NaHSO3, the more reduction of solubility but white index of powder increased. In the results of FT-IR spectras of silk fibroin powder obtained by various concentrations of NaHSO3 treatment, the absorbent peak at 3,400 cm-1 which was considered as -CH=N- (azomethine) was disappeared by the more addition of NaHSO3. It showed that absorbent peak of $\beta$-fibroin moved into low temperature region and transferred to $\alpha$- and random coil structure through the DSC experiment. In the results of amino acid analysis, alkali hydrolysis reduced the oxy amino contents acid like serine and tyrosine, but increased the glycine content by the more addition of NaHSO3.

• 천문학회보
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• 제41권2호
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• pp.43.4-44
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• 2016

The presence of multiple stellar populations is now well established in most globular clusters (GCs) in the Milky Way. The origin of this phenomenon, however, is yet to be understood. In this respect, the study of NGC 2808, an intriguing GC which hosts subpopulations with extreme helium abundances, would help to resolve this problem. In order to investigate chemical abundance patterns among different subpopulations in this GC, we have performed low-resolution spectroscopy for the red-giant-branch (RGB) stars and measured CN & CH bands, and Ca line strength. We have identified at least three subpopulations from the CN abundance distribution. This GC shows CN-CH anti-correlation following the general trend among "normal" GCs. In addition, we have cross-matched our results with the high-resolution data in literature, and found a tight correlation between CN strength and sodium abundance. However, CN is anticorrelated with oxygen abundance, as expected from the well known N(&Na)-O anticorrelation. In this talk, we will discuss the implication of these results.

• International Journal of Automotive Technology
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• 제2권2호
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• pp.77-83
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• 2001

Effect of ethene on the $DeNO_X$ conversion process in a simulated diesel engine operating conditions was investigated experimentally and theoretically. With the addition of even a small amount of ethene the NO to $NO_2$ conversion enhances greatly. The energy required to convert one NO molecule is 27 eV with 250 ppm ethene added, while 137 eV without ethene at 473 K. The effect of energy density, temperature, and the initial concentrations of ethene and oxygen are also discussed and the results show that the increase of the mentioned parameters lead to the promotion of NO oxidation. A kinetic model used in this study shows good agreement with the experimental result. Byproducts like formaldehyde ($CH_2$ 0) and methyl nitrite ($CH_3$ ONO) predicted by model calculation are broken up into CO and $H_2O$ eventually when high energy is delivered to the gas mixture. Sensitivity analysis shows that the main reactions of NO oxidation when ethene is added we: $HO_2+ NO \arrow NO_2 + OH, RO_2 + NO \arrow NO_2 + RO$, where R is a hydrocarbon radical. Also the direct oxidizing reaction of NO with O cannot be neglected.

• 조명전기설비학회논문지
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• 제25권11호
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• pp.103-112
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• 2011

This paper is tried to analysis the optical emission spectroscopy related to the position of inductive load coil and flow rates of methane and oxygen in the RF inductive plasma process. According to the position of load coil, peak of $H_{\alpha}$, $H_{\beta}$, and CH were appeared strongly at the middle position of the coil and it decreased both direction. The electron temperature was approximately 0.9[eV] at that position. Emission intensities of $H_{\alpha}$, $H_{\beta}$, and CH increased linearly by increasing input power. In addition, intensities of $H_{\alpha}$ and $H_{\beta}$ increased by increasing the flow rate of oxygen. It might be ascribed that the oxygen species were bonded with $C_nH_m$ by suppressing the combination with hydrogen atoms. Consequently, the optimal position of the inductive coil is decided to the intermediate position between 4th and 5th turns, the wanted carbon thin-film is possible to deposit by controlling flow rates of methane and oxygen.

• 생물정신의학
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• 제21권4호
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• pp.115-117
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• 2014

Variety of biomarkers that are related to the Alzheimer's disease and its diagnosis and progress have been found. However, research lacks in predicting the reaction of the treatment. In addition, there is no definite treatment reaction to the disease but rather it is varied. The purpose of this review article is to study the research of the biomarkers that are able to predict the treatment reaction. There was a research that illustrated a relationship between plasma amyloid ${\beta}$ peptide, cerebrospinal fluid tau, neuroanatomical biomarkers and acetylcholinesterase inhibitors. Polymorphisms in genes of the cholinergic markers AChE, BuChE, ChAT and PON-1 were found to be associated with better clinical response to acetylcholinesterase inhibitors. Many pharmacogenetic studies have been conducted to evaluate the impact of the lipoprotein apolipoprotein E (APOE) genotype on treatment response to acetylcholinesterase inhibitor. However, there is no significant influence of the APOE genotypes on treatment response. Further research is needed to find other predictors of treatment with acetylcholinesterase inhibitors in patients with Alzheimer's disease.

• Journal of Pharmaceutical Investigation
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• 제27권3호
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• pp.199-205
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• 1997

In order to formulate biphenyl dimethyl dicarboxylate(DDB) aqueous solutions, the effects of various solubilizing agents such as cosolvents(PG, PEG 400, glycerin, ethanol), surfactants,$(poloxamer\;407,\;Cremophor^{\circledR}\; RH40,\;Solutol^{\circledR},\;Tween\;80,\;sodium\;lauryl\;sulfate)$, complexation agent$(CELDEX^{\circledR}\;CH-20)$ and others(urea, niacinamide, propylene carbonate, HPMC) on the solubility of DDB in water were evaluated. The solubility of DDB in water was about $0.21\;{\mu}g/ml\;at\;20^{\circ}C$, while its solubility in PEG 400 was 5,000 times higher than that in water. 60% PEG 400 aqueous solution was selected as an optimum solvent system, and surfactants or other solubilizing agents were added to prevent DDB from recrystalization. The addition of surfactants in water increased the solubility of DDB from 15- to 34-fold, however, $CELDEX^{\circledR}\;CH-20$ and other agents studied showed negligible effects on the solubility of DDB in water. The 60% PEG 400 aqueous solution containing 5% $Cremophor^{\circledR}$　RH40 was appeared as the formula of choice. It showed acceptable physical stability after stored for 7 days at $4^{\circ}C$.

• Bulletin of the Korean Chemical Society
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• 제21권1호
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• pp.101-104
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• 2000

Li-graphite intercalation compounds (GICs), synthesized at elevated temperature and pressure, were allowed to decompose spontaneously in the atmosphere. The decomposition processes were analyzed by of X-ray diffraction, DSC analysis, FT-IR measurements, UV/VIS spectrophotometry. The deintercalation reaction of the Li-GICs ceased after 6 weeks and only the residual compounds could be observed. A strong exothermic reaction was observed at 300 $^{\circ}C$ in thermal decomposition, and relatively stable decomposition curves were formed. A few endothermic curves have been observed at 1000 $^{\circ}C.$ After 6 weeks deintercalation reaction time of GICs, many exothermic and endothermic reactions were accompanied at the same time. In addition the reactions of the functional groups such as aromatic rings, nitrogen, $-CH_3$, $-CH_2$ etc. of GDIC obtained by the above reaction were confirmed by FT-IR spectrum. UV/VIS spectrophotometric measurement clearly shows the formation of a minimum energy value ($R_{min}$) for the compounds between Li-GICs as a starting material and Li-GDICs obtained until after 3 weeks of the deintercalation reaction, while they were no clear energy curves from 4 weeks of reaction time, because of the formation of the graphite structure, of high stages and of the Li compounds surrounding the graphite in the deintercalation reaction.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1996년도 추계학술대회 논문집
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• pp.334-337
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• 1996

Si anisotropic etching is a key technology for micromachining. The main advantages of tetramethyl ammonium hydroxide (TMAH)-based solution are their full compatibility with IC process. In this work the anisotropic etching of single crystal Si in a TMAH (($CH_3$)$_4$NOH) based solution was studied. The influence of the addition of IPA to TMAH solution on their etching characteristics was also presented. The crystal planes bounding the etch front and their etch rates were determined as a function of temperature, crystal orientation, and etchant concentration. The etch rates of (100) oriented Si crystal planes decreased linearly with increasing the IPA concentration, The etched (100) planes were covered by Pyramidal-shaped hillocks below 15 wt.%, but very smooth surfaces were obtained above 20 wt.%. The addition of IPA to TMAH solution leads to smoother surfaces of sidewalls etched planes.

• 대한화학회지
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• 제53권5호
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• pp.530-535
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• 2009

디시클로헥실 텔루르염은 에탄올 수용액에서 NaTeH와 디시클로헥실 브롬화물의 반응에 의해 높은 수율로 얻어진다. 일반식 ${(cyclo-C_6H_11)}_2Te(R)X$ (where R = $CH_3$, X = I (1); R = $C_2H_5$, X = Br(2); R = $C_2H_5$, X = I (3); R = C_3H_5$, X = Br (4)) 인 유기텔루로늄의 새로운 시리즈는 그에 상응하는 알킬 할로겐화물과 ${(cyclo-C_6H_11)}_2Te$의 반응에 의해 만들어진다. $NaBPh_4$와 1의 반응은 78% 수율로 화합물 5를 제공하였다. 벤질 브롬화물과 ${(cyclo-C_6H_11)}_2Te$, 4-bromophenacyl bromide의 반응에서는 뜻밖에 각각dibenzylcyclohexyltelluronium 브롬화물과 and bis(4-bromophenacyl)cyclohexyltelluronium bromide을 얻었다. 높은 수율의 tetraphenylborate 유도체는 $NaBPh_4$과 6의 반응으로 얻었다. $CDCl_3$용매에서 $^1H$ NMR분석을 통해 화합물 1 이 알킬 할로겐화물의 제거 반응을 일으킴을 확인할 수 있었다. 새로운 화합물은 전도성, IR, $^1H$와$^{13}C$ NMR, 열분석를 통해 규명되었다.

• 전자공학회논문지
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• 제54권1호
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• pp.33-38
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• 2017

본 논문에서는 채널 당 3.125-Gb/s 동작 속도를 갖는 4-채널 공통-캐소드 VCSEL 다이오드 드라이버 어레이 칩을 구현하였다. 스위칭 동작하는 메인 드라이버의 동작속도 향상을 위해, 액티브 인덕터를 사용한 전치증폭단과 이퀄라이저 기능을 탑재한 입력버퍼단으로 구성하였다. 특히 개선된 입력버퍼단의 경우, 주파수 영역의 피킹으로 대역폭 증대뿐 아니라 비교적 적은 전류로 동작하도록 설계하였다. 본 논문에서 사용한 VCSEL 다이오드는 2.2 V 순방향 전압과 $50{\Omega}$ 기생저항 및 850 fF 기생 캐패시턴스를 갖는다. 또한, 3.0 mA 변조전류 및 3.3 mA 바이어스 전류로 동작하므로, 두 개의 독립적인 전류소스로 구동 가능한 current steering 기반의 메인 드라이버를 설계하였다. 제안한 4-채널 광 송신기 어레이 칩은 $0.11-{\mu}m$ CMOS 공정을 이용하여 제작하였다. 칩 코어의 면적은 $0.15{\times}0.18{\mu}m^2$ 이며, 채널 당 22.3 mW 전력소모를 갖는다.