• Title/Summary/Keyword: $CH_4$ addition

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Factors Influencing COVID-19 AstraZeneca (ChAdOx1) Vaccination and Side Effects among Health Care Workers in an Acute General Hospital (중소병원 의료기관 종사자의 COVID-19 AstraZeneca (ChAdOx1) 백신 접종 영향요인과 접종 후 이상 반응 실태조사)

  • Lee, Sunhwa;Choi, Jeong Sil
    • Journal of Korean Biological Nursing Science
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    • v.23 no.4
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    • pp.318-329
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    • 2021
  • Purpose: This study was conducted to identify factors affecting COVID-19 vaccination and associated side effects among health care workers in a small and medium-sized hospital. Methods: In May 2021, 301 workers out of a total of 670 working in a small and medium-sized hospital in Gyeonggi-do, were surveyed. The small and medium-sized hospital treats patients with COVID-19. Health care workers across different medical institutions responded with self-reported internet questionnaires. Factors influencing COVID-19 vaccination were analyzed via logistic regression. Results: Out of 301 subjects, 89.0% showed an intention to inoculate, and 85.7% were vaccinated against COVID-19. The most frequent reason for vaccination was responsibility as a medical worker. The fear of adverse reactions was the most frequent reason for non-vaccination. Adverse reactions after inoculation occurred in 70.9% of cases, and 30.6% were referred for treatment of adverse reactions. The factors ultimately influencing COVID-19 vaccination were vaccination intention, previous side effects from other vaccinations, occupation, and age. Conclusion: In order to improve the effectiveness of COVID-19 vaccination, a systematic approach is required to determine the risk factors associated with the young age of the administrative staff/personnel, subjects with a history of side effects associated with other vaccines, and health care workers who do not intend to be vaccinated. It is important to develop strategies to improve immunization. In addition, accurate and essential information regarding the side effects of vaccination is needed, along with appropriate education and publicity.

Preparation and Application of Rehmannia Glutinosa Extract Incorporated Functional Chitosan Based Biomaterials (지황 추출물 첨가 chitosan 기반 기능성 바이오 소재 제조 및 응용)

  • Lee, Si-Yeon;Kim, Kyeong-Jung;Kim, Youn-Sop;Yoon, Soon-Do
    • Applied Chemistry for Engineering
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    • v.33 no.2
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    • pp.195-201
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    • 2022
  • The main objective of this work is to prepare Rehmannia glutinosa extract (RE) incorporated functional chitosan (CH) based biomaterials and evaluate their physical properties, RE release properties, inhibitory effect of melanogenesis, and antioxidant and elastase inhibitory activities. RE incorporated CH based biomaterials were synthesized by a casting method and UV curing process. The surface and cross sections of prepared biomaterials were characterized by a field emission scanning electron microscope (FE-SEM). The physical properties such as tensile strength and elongation at break were also investigated. To apply the transdermal drug delivery system, RE release properties were examined with pH 4.5, 5.5, and 6.5 buffer solutions and artificial skin test at 36.5 ℃. Results indicated that RE release of RE incorporated biomaterials with/without the addition of plasticizers [glycerol (GL) and citric acid (CA)] at pH 6.5 was about 1.10 times higher than that of at pH 4.5. In addition, results of the artificial skin test verified that RE was released constantly for 6 h. To verify the applicability of the prepared biomaterials, tyrosinase, 2,2-diphenyl-1-picrylhydrazyl (DPPH), and elastase assays were investigated. Results indicated that RE incorporated biomaterials added CA exhibited tyrosinase activation, DPPH radical scavenging activity rate, and elastase activation of 45.12, 89.40, and 59.94%, respectively.

A Multipath Delay Time Detection Method For $\frac{\pi}{4}$ Shift QPSK Modulation Under The Frequency Selective Fading Environment (주파수 선택성 페이딩 환경하에서 $\frac{\pi}{4}$ shift QPSK 변조방식에 대한 다중파의 시간지역 검출법 제안)

  • 조병진;김대영
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.16 no.10
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    • pp.941-950
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    • 1991
  • channel is severely degraded by multipath delay time spread. In this paper. We propose a simple multipath delay time detection method, which has a merit of in serviceable, yet simple H/W realizability for $\pi/4$ shift QPSK by detecting cross channel interference. A $\pi/4$ shift QPSK signal originally has quadrature channel(Q-ch) component. Thus in order to measure CCI between in-phase channel(I-ch) and quadrature channel(Q-ch), which closely related to multipath delay time, Frequency doubling scheme(frequency doubler) and differential detector is proposed, which makes $\pi/4$ shift QPSK signal look like BPSK and also makes it possible for CCI to be detected at I-ch detector output. To get an information from time varying I-ch output signal under the multipath lading environment, a method for obtaining the mean of the absolute value$(V_{MABS}(t))$ and another one for obtaining the root mean square value$(V_{RMS}(t))$ of CCI are proposed. Furthermore, a relationship between delay spread and CCI is also analyzed. In order to confirm theoretical results, computer simulation has been carried out under the quasi-static and Reyleigh distributed two ray multipath fading environments. A fairly good result was obtained. However it was also shown that this method is sensitive to bandwidth restriction to some extent. In addition, some idea for a simple hardware realization for the frequency doubler are given.

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Effect of Artificial Zeolite on Fermentation and Emission of Ammonia and Methane during Animal Waste Composting (인공제올라이트 처리가 가축분 퇴비의 발효 및 암모니아, 메탄가스 발생에 비치는 영향)

  • Lee, Deog-Bae;Kim, Jong-Gu;Lee, Kyung-Bo;Lee, Sang-Bok;Kim, Jae-Duk
    • Korean Journal of Soil Science and Fertilizer
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    • v.33 no.5
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    • pp.361-368
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    • 2000
  • This study was carried out to investigate the influence of artificial zeolite on the change of temperature, gas emission, water content and chemical properties during the composting process with the mixture of animal feces, broken bark and extruded rice hull. Artificial zeolite was added 0, 0.5, 1, 3 and 5% volume of the raw composting material, and proceeded 1.2m every day with mobile stacking escalator. Temperature was increased, and water content was decreased in the composting pile by addition of artificial zeolite. This caused to accelerate decomposition of organic matter during composting. $NH_3$ was emitted the highest at 6th day after stacking, then decreased gradually. And addition of artificial zeolite caused to decrease greatly in $NH_3$ emission from composting pile. As result of this, content of nitrogen in the compost was increased by addition of artificial zeolite. Emission of $CH_4$ was the highest at early stacking stage, and that was decreased drastically at 8th day. Emission of $CH_4$ was also decreased greatly by addition of artificial zeolite at 5th days after stacking. It may be resulted from adsorption of $CH_4$ into the molecular sieve structure of artificial zeolite and low water content by high temperature fermentation.

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Effect of Acid and Salt on Weight toss of Polyester (PET) fabric by Sodium Hydroxide (산과 염이 폴리에스터 직물의 알칼리 감량에 미치는 영향)

  • Do, Sung-Guk;Cho, Hwan
    • Textile Coloration and Finishing
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    • v.4 no.3
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    • pp.65-73
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    • 1992
  • To control the hydrolysis rate of PET fabric with NaOH, HCl and $CH_3$COOH(HAc), as regulating reagent, were added to the 0.5 M NaOH solution. The concentrations of acids in 0.5 M NaOH were varied. PET fabrics were treated with aqueous solutions of acids in 0.5 M NaOH under different conditions. The weight loss of PET fabric, the rate of hydrolysis, the apparent activation energy (E$_{\alpha}$), the handle value, the etched surface of treated PET fabric, and the effect of salts such as NaCl, $CH_3$COONa(NaAc), and NH$_4$Cl on the weight loss were discussed. Acids in the aqueous 0.5 M NaOH solution decreased the weight loss of PET fabric bacause of neutralization of OH- and the weight loss of PET fabrics treated with corresponding concentration of aqueous NaOH solution to the concentrations of the aqueous solutions of acids in 0.5 M NaOH was lower than that of PET fabrics treated with aqueous solutions of acids in 0.5 M NaOH. The addition of NaCl to aqueous NaOH solution accelerated the reaction of OH- with PET greatly, the addition of NaAc increased the weight loss slightly, but the addition of NH$_4$Cl decreased the weight loss. It was thought that the very remarkable result that NaCl in aqueous NaOH solution promoted the hydrolysis of PET with NaOH would contribute to the conservation of energy and NaOH in the weight loss finishing process of PET fabric. The etched surface and the handle value of treated PET fabric were independent of the difference in the kinds of acids and salts added.nd salts added.

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Production of Hydrogen-Rich Gas from Methane by a Thermal Plasma Reforming (고온 플라즈마 개질에 의한 메탄으로부터 고농도 수소생산)

  • Kim, Seong-Cheon;Lim, Mun-Sup;Chun, Young-Nam
    • Journal of Hydrogen and New Energy
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    • v.17 no.4
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    • pp.362-370
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    • 2006
  • The purpose of this paper was to investigate the reforming characteristics and optimum operating condition of the plasmatron assisted $CH_4$ reforming reaction for the hydrogen-rich gas production. Also, in order to increase the hydrogen production and the methane conversion rate, parametric screening studies were conducted, in which there were the variations of the $CH_4$ flow ratio, $CO_2$ flow ratio, vapor flow ratio, mixing flow ratio and catalyst addition in reactor. High temperature plasma flame was generated by air and arc discharge. The air flow rate and input electric power were fixed 5.1 l/min and 6.4 kW, respectively. When the $CH_4$ flow ratio was 38.5%, the production of hydrogen was maximized and optimal methane conversion rate was 99.2%. Under these optimal conditions, the following synthesis gas concentrations were determined: $H_2$, 45.4%; CO, 6.9%; $CO_2$, 1.5%; and $C_2H_2$, 1.1%. The $H_2/CO$ ratio was 6.6, hydrogen yield was 78.8% and energy conversion rate was 63.6%.

Preparation and Permeation Characteristics of PTMSP-PDMS-Silica/PEI Composite Membranes (PTMSP-PDMS-Silica/PEI 복합막의 제조 및 투과특성)

  • Lee, Hyun-Kyung;Hong, Se-Lyung
    • Membrane Journal
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    • v.18 no.2
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    • pp.146-156
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    • 2008
  • In this study, PTMSP of high permeability and high molecular weight was synthesized, and PTMSP-PDMS graft copolymer was synthesized from poly [1-(trimethylsily)propyne] (PTMSP) and hydroxy-terminated poly(dimethylsiloxane) (PDMS). The PTMSP-PDMS-silica composites were prepared by the addition of 15, 30, or 50 wt% tetraethoxysilane (TEOS) to PTMSP-PDMS graft copolymer by sol-gel process. To investigate the physico-chemical characteristics of PTMSP-PDMS-silica/PEI composite membranes, the analytical methods such as $^1H$-NMR, FT-IR, TGA, XPS, GPC, and SEM have been utilized. The gas permeability and selectivity properties of $H_2,\;O_2,\;N_2,\;CO_2,\;CH_4,\;n-C_4H_{10}$, were evaluated. Permeability of the composite membranes increased as TEOS content and pressure increased. Selectivity of $H_2,\;O_2,\;N_2,\;CO_2,\;CH_4,\;and\;n-C_4H_{10}$, showed the maximum value at 30 wt% of TEOS content and decreased thereafter.

Electric Properties of Carbon Aerogel for Super Capacitors (카본 에어로겔을 이용한 초고용량 커패시터의 전기적 특성)

  • Han, Jeong-Woo;Lee, Kyeong-Min;Lee, Du-Hee;Lee, Sang-Won;Yoon, Jung-Rag
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.23 no.8
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    • pp.660-666
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    • 2010
  • Carbon aerogels are promising materials as electrodes for electrical double layer capacitors (EDLCs). An optimum process is presented for synthesis of nanoporous carbon aerogels via pyrolyzing resorcinol-formaldehyde (RF) organic aerogels, which could be cost-effectively manufactured from RF wet gels. The major reactions between resorcinol and formaldehyde include an addition reaction to form hydroxymethyl derivatives ($-CH_2OH$), and then a condensation reaction of the hydroxymethyl derivatives ($-CH_2-$)- and methylene ether ($-CH_2OCH_2-$) bridged compounds. The textural properties of carbon aerogels obtained were characterized by nitrogen adsorption/desorption analysis and SEM and TEM. The application of the resultant carbon for electrodes of electric double layers capacitor (EDLC) in organic TEABF4/ACN electrolyte indicated that the ESR, as low as 55 $m{\Omega}$, was smaller than for commercially activated carbons. And EDLC with carbon Aerogel electrodes has an excellent stable more than for commercially activated carbons.

Synthesis of Tris(silyl)methanes by Modified Direct Process

  • Lee, Chang Yeop;Han, Jun Su;Yu, Bok Ryeol;Jeong, Il Nam
    • Bulletin of the Korean Chemical Society
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    • v.21 no.10
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    • pp.959-968
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    • 2000
  • Direct reaction of elemental silicon with a mixture of (dichloromethyl)silanes 1 $[Cl_3-nMenSiCHCl_2:$ n = 0 (a), n = 1(b), n = 2(c), n = 3(d)] and hydrogen chloride has been studied in the presence of copper catalyst using a stirred bed reactor equ ipped with a spiral band agitator at various temperatures from $240^{\circ}C$ to $340^{\circ}C.$ Tris(si-lyl) methanes with Si-H bonds, 3a-d $[Cl_3-nMenSiCH(SiHCl_2)_2]$, and 4a-d $[Cl_3-nMenSiCH(SiHCl_2)(SiCl_3)]$, were obtained as the major products and tris(silyl)methanes having no Si-H bond, 5a-d $[Cl_3-nMenSiCH(SiCl_3)_2]$, as the minor product along with byproducts of bis(chlorosilyl)methanes, derived from the reaction of silicon with chloromethylsilane formed by the decomposition of 1. In addition to those products, trichlorosilane and tetra-chlorosilane were produced by the reaction of elemental silicon with hydrogen chloride. The decomposition of 1 was suppressed and the production of polymeric carbosilanes reduced by adding hydrogen chloride to 1. Cad-mium was a good promoter for and the optimum temperature for this direct synthesis was $280^{\circ}C$.

Eco-Friendly Photocatalytic Transformation of Greenhouse Gas CO2 into Precious CH4 Fuel via Cu-Deposited Black TiO2 under Simulated Sunlight Irradiation

  • Dong Jin Kim;Hyun-Cheol Lee;Seung-Ho Shin;Wan-Kuen Jo
    • Journal of Environmental Science International
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    • v.33 no.9
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    • pp.633-643
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    • 2024
  • Hereunder, the eco-friendly photocatalytic CO2 transformation capability of Cu-deposited black TiO2 (Cu/BTiO2) was evaluated to investigate if this photocatalyst proceeds the thermodynamically- and kinetically-satisfactory CO2 transformation into CH4. The clustered Cu-deposited BTiO2 (Cu/BTiO2) and Cu/BTiO2 architectures revealed noticeable photocatalytic CO2 transformation abilities, whereas the pristine TiO2 and BTiO2 catalysts displayed no significant photocatalytic CO2 transformation abilities. Especially, the photocatalytic CO2 transformation rates of a representative Cu/BTiO2 architecture were 104, 209, 272, 322, and 361 μmol/g at the irradiation times of 2, 4, 6, 8, and 10 h, respectively, while the photocatalytic CO2 transformation rates of Cu/BTiO2 were 61, 139, 217, 270, and 309 μmol/g at the same irradiation times, respectively. The promoted photocatalytic CO2 transformation ability of the Cu/BTiO2 architecture was assigned to the excellent electron-hole separation tendency, which was verified by the photoluminescence analysis. The composition ratio of Cu incorporated into BTiO2 in the Cu/BTiO2 architectures was crucial in CH4 generation. In addition, the Cu/BTiO2 architecture displayed eminent photodurability, which was verified by the consecutive experiment cycle, and the mechanistic process for CO2 transformation into CH4 via the Cu/BTiO2 architecture was established. The electronic framework of the Cu/BTiO2 architecture was established on the basis of its band gap and valence band value. Conclusively, the Cu/BTiO2 architecture is an outstanding tool for thermodynamically- and kinetically-satisfactory photocatalytic CO2 transformation into CH4 that application under simulated sunlight irradiation.