• Title/Summary/Keyword: $BiMnO_3$

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A Fuel shortage detected sensor using NTC thermistor of Mn-Ni-Co system (Mn-Ni-Co계 NTC thermistor를 이용한 연료 부족 감지용 센서)

  • 윤중락;김두영;송광호;이헌용
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1995.11a
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    • pp.347-350
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    • 1995
  • In this paper, we fabricated fuel shortage detecting sensor, utilizing NTC thermistor concerned with Mn-Ni-Co system. We would be obtained B constant value of 1930∼2080 and resistivity 387∼430(ohm-cm) additive Bi$_2$O$_3$0∼0.5 wt% to Mn$_3$O$_4$:9wt%, Co$_3$O$_4$:61wt%, NiO:28wt% under 1150∼1250$^{\circ}C$ of sintering temperature. In sensor, we obtained characteristics, which we want, in resistance range 850∼l150$\Omega$, B constant 2000${\pm}$5%. we can see 15 multiplied differences between gasoline and heat dissipation coefficient of air condition.

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Preparation and Electrical Properties of BiFeO3 Films by RF Magnetron Sputtering (RF Magnetron Sputtering에 의한 BiFeO3 박막의 제조 및 전기적 특성)

  • Park, Sang-Shik
    • Korean Journal of Materials Research
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    • v.19 no.5
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    • pp.253-258
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    • 2009
  • Mn-substituted $BiFeO_3$(BFO) thin films were prepared by r.f. magnetron sputtering under an Ar/$O_2$ mixture of various deposition pressures at room temperature. The effects of the deposition pressure and annealing temperature on the crystallization and electrical properties of BFO films were investigated. X-ray diffraction patterns revealed that BFO films were crystallized for films annealed above $500^{\circ}C$. BFO films annealed at $550^{\circ}C$ for 5 min in $N_2$ atmosphere exhibited the crystallized perovskite phase. The (Fe+Mn)/Bi ratio decreased with an increase in the deposition pressure due to the difference of sputtering yield. The grain size and surface roughness of films increased with an increase in the deposition pressure. The dielectric constant of BFO films prepared at various conditions shows $127{\sim}187$ at 1 kHz. The leakage current density of BFO films annealed at $500^{\circ}C$ was approximately two orders of magnitude lower than that of $550^{\circ}C$. The leakage current density of the BFO films deposited at $10{\sim}30\;m$ Torr was about $5{\times}10^{-6}{\sim}3{\times}10^{-2}A/cm^2$ at 100 kV/cm. Due to the high leakage current, saturated P-E curves were not obtained in BFO films. BFO film annealed at $500^{\circ}C$ exhibited remnant polarization(2Pr) of $26.4{\mu}C/cm^2$ at 470 kV/cm.

Varistor Properties and Aging Behavior of ZnO-V2O5-MnO2-Co3O4-La2O3 Ceramics Modified with Various Additives (Cr, Nb, Dy, Bi)

  • Nahm, Choon-Woo;Lee, Sun-Kwon;Heo, Jae-Seok;Lee, Don-Gyu;Park, Jong-Hyuk;Cho, Han-Goo
    • Transactions on Electrical and Electronic Materials
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    • v.14 no.4
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    • pp.193-198
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    • 2013
  • The effects of additives (Cr, Nb, Dy, and Bi) on microstructure, electrical properties, dielectric characteristics, and aging behavior of $ZnO-V_2O_5-MnO_2-Co_3O_4-La_2O_3$ (ZVMCL) ceramics were systematically investigated. The phase formed in common for all ZVMCL ceramics modified with various additives consisted of ZnO grain as a main phase, and $Zn_3(VO_4)_2$ and $ZnV_2O_4$ as the secondary phases. The sintered density and average grain size were in the range of $5.4-5.54g/cm^3$ and $3.7-5.1{\mu}m$, respectively. The ZVMCL ceramics modified with Cr exhibited the highest breakdown field (6,386 V/cm) and the ZVMCL ceramics modified with Nb exhibited the lowest breakdown field (3,517 V/cm). All additives enhanced the nonlinear coefficient (${\alpha}$), by a small or large margin, in particular, additives such as Bi and Nb noticeably increased the nonlinear coefficient, with ${\alpha}=25.5$ and ${\alpha}=23$, respectively. However, on the whole, all additives did not improve the stability against a DC stress, compared with ZVMCL ceramics.

Effect of Lead Free Glass Frit Compositions on Properties of Ag System Conductor and RuO2 Based Resistor Pastes (Ag계 도체 및 RuO2계 저항체 페이스트의 특성에 미치는 무연계 글라스 프릿트 조성의 영향)

  • Koo, Bon-Keup
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.24 no.3
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    • pp.200-207
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    • 2011
  • Abstract: The effect of lead free glass frit compositions on the properties of thick film conductor and resistor pastes were investigated. Two types lead free frits, HBF-A(without $Bi_2O_3$) and HBF-B(with $Bi_2O_3$) were made from $SiO_2$, $B_2O_3$, $Al_2O_3$, CaO, MgO, $Na_2O$, $K_2O$, ZnO, MnO, $ZrO_2$, $Bi_2O_3$. And Ag based conductor pastes and $RuO_2$ based resistor paste were prepared by mixed with these frits and functional phase(Ag and $RuO_2$), and organic vehicle. The properties of thick film conductor and resistor sintered at $850^{\circ}C$ were studied after printing on $Al_2O_3$ substrate. The morphology of the sintered films surface were SEM and EDS were carried out to analysis the chemical composition on resistor surface and state of Ru atom in frit matrix.

The Design of Oxide Module for High Temperature Thermoelectric Power Generation (고온 발전용 산화물 열전모듈의 설계)

  • Park, Jong-Won;Yoon, Sun-Ho;Cha, Jeong-Eui;Choi, Seung-Chul
    • Journal of the Microelectronics and Packaging Society
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    • v.15 no.4
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    • pp.93-100
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    • 2008
  • The one and two pair of oxide modules for high temperature thermoelectric power generation were fabricated with $Ca_{2.7}Bi_{0.3}Co_4O_9$(p-type) and $Ca_{0.96}Bi_{0.04}Mn_{0.96}Nb_{0.04}O_3$(n-type) on $Al_2O_3$ substrate. For the optimizing of the design process, contact resistance was derived from the results of the one pair modules, and then the resistance of two pair modules were calculated to use the derived data. Those values were compared with the measured values for the optimizing of this design process. The resistance of calculated and measured two pairs modules was 0.956 $\Omega$ and 1.110 Q $\Omega$ $T_h$=833 K, respectively, the difference of resistance was about 0.15 $\Omega$. From the result, proposed design process is effective for high temperature thermoelectric oxide modules fabrication.

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A Study on the Microwave Dielectric Properties of A1$_2$O$_3$ Ceramics Resonator added with Impurities (불순물 첨가에 따른 A1$_2$O$_3$ 세라믹 공진기의 마이크로파 유전특성에 관한 연구)

  • 이문기;박인길;류기윈;이성갑;이영희
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.11a
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    • pp.64-67
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    • 1997
  • Microwave dielectric properties of A1$_2$O$_3$ ceramics resonator were investigated with impurity addition. Increasing the contents of Bi$_2$O$_3$Q-value and Q $\times$ f were increased. In the specimen with the content of Bi$_2$O$_3$(0.3wt%), dielectric constant, quality factor and temperature coefficient of resonant frequency(TCRF, $\tau$$_{f}$) had a good values of 10.76,23,253(at 9.68[GHz]) and -39.09(ppm/$^{\circ}C$), respectively. The TCRF value was decreased with MnO$_2$ and increased with Sm$_2$O$_3$. La$_2$O$_3$.>.

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Fabrication, Magnetic and Magnetoresistive Properties of Bi-Doped Lanthanum Manganites (Bi 첨가 란탄 망가나이트의 제조, 자기 및 자기저항 특성)

  • 김덕실;조재경
    • Journal of the Korean Magnetics Society
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    • v.9 no.5
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    • pp.239-244
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    • 1999
  • Bi-doped lanthanum magnetics $(La_{0.67-x}Bi_xCa_{0.33}MnO_3(x\;=\;0,\; 0.04,\; 0.1,\; 0.2))$ samples have been prepared by standard ceramic process. The crystallinity and microstructures of the samples have been investigated by x-ray diffractometry and optical microscopy, respectively. The magnetic and magnetoresistive properties of the samples have been measured by vibrating sample magnetometery and van der Pauw method, respectively, at the temperatures ranging of 100 K~300 K with applied magnetic field of 0.4~0.5 T. Good crystallinity and high Curie temperature (275 K) have been obtained for the Bi-doped samples with small dosage (x = 0.04, 0.1) even they were sintered at 120$0^{\circ}C$, which is about 20$0^{\circ}C$ lower than normal sintering temperature of 140$0^{\circ}C$. The Bi-doped samples with the small dosage showed lower relative electrical resistivity and higher magneto-resistive ratio compared to the undoped sample in the most temperatures measured. The Bi-doped samples also exhibited large magnetoresisitve ratio (maximum of 15% for x = 0.1) at room temperature even under a weak magnetic field of 0.4 T.

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A Report on the ESR and Magnetic Structure of BixCa1-xMnO3 (x=0.15, 0.22)

  • Na, S.H.;Kim, J.W.;Choi, S.N.;Park, J.W.
    • Journal of Magnetics
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    • v.11 no.2
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    • pp.95-97
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    • 2006
  • The electron spin resonance signals of $Bi_xCa_{1-x}MnO_3$ have been acquired for two samples of x=0.15 and 0.22. ESR signal of the sample of x=0.15 clearly shows signal shape change into Dysonian with g-value shift at around 165 K so that the charge ordering temperature can be identified. The general features of ESR signal of the two samples well correlate with magnetic susceptibility measurement and also confirm the validity of former investigations.