• Bulletin of the Korean Chemical Society
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• v.19 no.5
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• pp.501-503
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• 1998

In this work, we applied the 1D $11^B$ nutation NMR method for the analysis of the local structural environments in powdered borosilicates $(SiO_2-B_2O_3)$. Spin dynamics during a rf irradiation for spin I=3/2 was analytically calculated with a density ma trix formalism. Spectral simulation programs were written in MATLAB on a PC. Two borosilicates prepared by the sol-gel process at different stabilization temperature were used for the 1D $11^B$ nutation NMR experiment. The $11^B$ NMR parameters, quadrupole coupling constants $(e^2qQ/h)$ and asymmetry parameters (η), for each borosilicate were extracted from the nonlinear least-squares fitting. The effects of heat treatments on the local structures of boron sites in borosilicates were discussed.

• Bulletin of the Korean Chemical Society
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• v.13 no.3
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• pp.256-259
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• 1992

The 14-membered tetraaza macrocyclic ligand 1,8-diethyl-5,12-dimethyl-1,4,8,11-tetraazacyclote tradeca-4,11-diene(B) can be synthesized as its dihydroperchlorate salt by the one-pot reaction of 2-ethylaminoethylamine, methylvinyl ketone, and perchloric acid in absolute ethanol. The reaction of Ni(II) or Cu(II) ion and the salt yields $[M(B)]^{2+}$ (M = Ni(II) or Cu(II)), which reacts with $NaBH_4$ to produce $[M(D)]^{2+}$ (D = 1,8-diethyl-5,12-dimethyl-1,4,8,11-tetraazacyclote tradecane). The complexes $[M(L)]^{2+}$ (L = B or D) have planar geometry and contain two ethyl groups at the donor nitrogen atoms of the ligands. The red solids $[Cu(B)](X)_2(X)$ = $ClO_4-$ or $PF_6^-$) react with water molecules of atmospheric moisture to produce the purple solids in which water molecules are coordinated to the metal ion. Synthesis, characterization, and the properties of the new N-ethylated macrocyclic ligands and their Ni(II) and Cu(II) complexes are reported.

• Bulletin of the Korean Chemical Society
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• v.16 no.11
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• pp.1067-1074
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• 1995

Reaction of arachno-S2B7H8- with either THF or 1,2-dimethoxyethane upon refluxing condition results in the formation of the previously known compound hypho-S2B7H10-. Protonation of hypho-S2B7H10- with HCl/Et2O generates hypho-2,5-S2B7H11 in good yield. This hypho-S2B7H10- anion has been employed to generate a series of new nido-, arachno-, and hypho-metalladithiaborane clusters. Reaction of the anion with Cp(CO)2FeCl results in direct metal insertion and the formation of a complex containing the general formula (η5-C5H5)FeS2B7H8. Spectroscopic studies of nido-6-CpFe-7,9-S2B7H8 Ⅰ demonstrated that compound Ⅰ was shown to have an nido-type cage geometry derived from an octadecahedron missing one vertex, with the iron atom occupying the three-coordinate 6-position in the cage and the two sulfurs occupying positions on the open face of the cage. Reaction of hypho-S2B7H10- with CoCl2/Li+[C5H5]- gave the previously known complex arachno-7-CpCo-6,8-S2B6H8 Ⅱ. Also, the reaction of the anion with [Cp*RhCl2]2 gave the complex arachno-7-Cp*Rh-6,8-S2B6H8 Ⅲ, the structure of which was shown to be that of complex Ⅱ. The similarity of the NMR spectra of Ⅱ and Ⅲ suggest that Ⅲ adopts cage structure similar to that previously confirmed for Ⅱ. A series of 9-vertex hypho clusters in which the sulfur atoms are bridged by different species isoelectronic with a BH3 unit, such as HMn(CO)4 or SiR2 have been prepared. Compounds Ⅳ,Ⅴ and Ⅵ are each 2n+4 skeletal electron systems and would be expected according to skeletal electron counting theory to adopt hypho-type polyhedral structures derived from an icosahedron missing three vertices. The complex hypho-1-(CO)4Mn-2,5-S2B6H9 Ⅳ was obtained by the reaction of the anion with (CO)5MnBr and has been shown from spectroscopic data to consist of a (CO)4Mn fragment bound to the two sulfur atoms S2 and S5 of hypho-S2B7H10-. Also, similar hypho-type complexes hypho-1-R2Si-2,5-S2B6H8 (R=CH3 Ⅴ, R=C6H5 Ⅵ) have been prepared from the reaction of hypho-S2B7H10- with R2SiHCl.

• The Journal of the Korea institute of electronic communication sciences
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• v.17 no.1
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• pp.13-22
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• 2022

In this paper, we propose single and array antenna with dual linear polarization characteristics for 28 GHz band. The proposed antenna is designed two microstirp feeding structure and Taconic TLY-5 substrate, which is thickness 0.5 mm, and the dielectric constant is 2.2. The size of single patch antenna is 3.4 mm×3.4 mm, and total size of single antenna is 15.11 mm×15.11 mm. Also, the size of array antenna is 3.15 mm×3.15 mm, and total size of array antenna is 21.5 mm×13.97 mm. From the fabrication and measurement results, for 1×2 array antenna, in case of vertical polarization, cross polarization ratios are obtained from 14.23 dB to 20.79 dB and in case of horizontal polarization, cross polarization ratios are obtained from 14.31 dB to 22.74 dB for input port 1. in case of vertical polarization, cross polarization ratios are obtained from 15.75 dB to 25.88 dB and in case of horizontal polarization, cross polarization ratios are obtained from 14.70 dB to 22.82 dB for input port 2.

• Journal of Digital Convergence
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• v.11 no.12
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• pp.447-452
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• 2013

Berkley Media Access Control (B-MAC) protocol is one of the well-known MAC protocols, which uses adaptive preamble sampling scheme and is designed for wireless sensor networks (WSN). In this paper, we are reviewed about security vulnerability in B-MAC, and analyzed the power which is consumed at each stage of B-MAC protocol according to vulnerability of denial of sleep(DoS) and replay problem. From our analytical results, it can be considered the need of power efficient authentication scheme which provides the reliability, efficiency, and security for a general B-MAC communication. This is the case study of possible DoS vulnerability and its power consumption in B-MAC.

• Resources Recycling
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• v.27 no.4
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• pp.23-28
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• 2018

Distribution data of boric acid in water is necessary to develop a hydrometallurgical process for the recovery of boron from primary and secondary resources containing boron. Boric acid exists as $B(OH)_3$ and $B(OH)_4{^-}$ when solution pH is less than 6 and higher than 12, respectively. In the solution pH range of 6-11, condensation reaction between $B(OH)_3$ and $B(OH)_4{^-}$ results in the formation of some polymers. The mole fraction of the boron polymers such as $B_3O_3(OH)_4{^-}$ and $B_4O_5(OH){_4}^{2-}$ is proportional to the concentration of boric acid.

• Journal of Life Science
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• v.8 no.3
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• pp.272-278
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• 1998

To investigate the effects of different UV-B levels on plant growth, cucumber plants were subjected to three levels of biologically effective ultraviolet-B(UV--$B^{BE}$ radiation [daily dose : 0.03(No UV-B), 6.40(Low UV-B) and 11.30 (High UV-B) kJ $m^{-2}$, UV--$B^{BE}$] in the growth chambers for 3 weeks during the early growth period. High and low levels of UV-B irradiation drastically decreased both dry weight and leaf area, but increased specific leaf weight of cucumber. Plants subjected to UV-B resulted in 30% and 20% reduction of photosynthesis rate by high and low UV-B, respectively. However, respiration rate was not affected by the UV-B. With increasing UV-B intensity, total chlorophyll contents were decreased linearly, while the contents of flavonoid were increased linearly. These results suggest that the present levels of UV-B may affect the growth of cucumber plant compared with a UV-B-free condition. It is likely that the growth of cucumber will be affected by enhanced UV-B due to ozone depletion in the near future.

• Journal of Microbiology and Biotechnology
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• v.11 no.4
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• pp.628-635
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• 2001

Recombinant E. coli DH5$\alpha$ harboring a dextransucrase gene (dsrB742) produced an extracellular dextransucrase in a 2% sucrose medium. The enzyme was purified by DEAE-Sepharose and Phenyl-Sepharose column chromatographies upto a 142.97-fold purification with a 11.11% recovery to near homogeneity. The enzyme had a calculated molecular mass of 168.6 kDa, which was in good agreement with the activity band of 170 kDa on a nondenaturing SDS-PAGE. An expression plasmid was constructed by inserting the dsrB742 into a pRSET expression vector. The activity after expression in E. coli BL21(DE3)pLysS increased about 6.7-fold compared to the extracellular dextransucrase from L. mesenteroides B-742CB. The expressed and purified enzyme from the clone showed similar biochemical properties (acceptor reaction, size of active dextransucrase, optimum pH, and temperature) to B-742CB dextransucrase, however, the ability to synthesize ${\alpha}$-(1$\rightarrow$3) branching decreased in comparison to that of L. mesenteroides B-742CB dextransucrase.

• The Journal of Korean Institute of Electromagnetic Engineering and Science
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• v.11 no.3
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• pp.403-409
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• 2000

In this paper, we measured and analyzed cross polarization discrimination(XPD), signal correlation coefficient($\rho$) and received signal level decrease, for the application of polarization diversity scheme in the up-link of microcell environments. We experimented in a dense building area, a dense residence area, a market area, a school area and etc at 1.9 GHz. Cross polarization discrimination (XPD) is about 6~11 dB, signal correlation coefficient($\rho$) is below 0.7 and received signal level decrease is smaller than 3 dB. The results of comparing polarization diversity with space diversity show that polarization diversity gain is about 2~5 dB higher in the various area. As a results, polarization diversity scheme is more effective than space diversity scheme in microcell environments.

• Journal of Electrical Engineering and Technology
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• v.8 no.1
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• pp.168-175
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• 2013

This paper presents compact dual-band WLAN filter and filter module. They were developed by embedding all of the passive lumped elements into a LTCC substrate. In order to reduce the size/volume of the filter and avoid EM parasitic couplings between the passive elements, the proposed filter was designed using a 3rd order Chebyshev circuit topology and J-inverter transformation technology. The 3rd order Chebyshev bandpass filter was firstly designed for the band-selection of the 802.11b and was then transformed using finite transmission zeros technologies. Finally, the dual-band filter was realized by adding two notch resonators to the 802.11b filter circuit for the band-selection of the 802.11a/g. The maximum insertion losses in the lower and higher passbands were better than 2.0 and 1.3 dB with minimum return losses of 15 and 14 dB, respectively. Furthermore, the filter was integrated with a diplexer to clearly split the signals between 2 and 5 GHz. The maximum insertion and minimum return losses of the fabricated module were 2.2 and 14 dB at 2.4 - 2.5 GHz, and 1.6 and 19 dB at 5.15 - 5.85 GHz, respectively. The overall volume of the fabricated filter was $2.7{\times}2.3{\times}0.59mm^3$.