• Title/Summary/Keyword: $Al_2O_3$ fiber

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Cyclic Deformation and Fatigue Behavior of Short Fiber Reinforced Metal Matrix Composites (단섬유보강 금속복합재료의 반복적 변형 및 피로특성)

  • 양유창;송정일;한경섭
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.19 no.6
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    • pp.1422-1430
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    • 1995
  • Al6061 alloy reinforced with 15 volume% of Saffil fibers was fabricated by squeeze infiltration method. Uniform distribution of reinforcements and good bondings between reinforcements and matrix alloy were found in the microstructure of composites. Comparing with A16061 matrix alloy, tensile strength and elastic modulus of $Al_{2}$O$_{3}$/Al composites were increased up to 26% and 31%, respectively. Cyclic deformation and fatigue behavior of $Al_{2}$O$_{3}$/Al metal matrix composites were studied. The specimens were cycled using tension-tension(R=0.1) loading and under load controlled fatigue test. Cyclic stress-displacement curve through fatigue test was obtained. Fatigue strength of $Al_{2}$O$_{3}$/Al composites was about 200 MPa, i.e.0.55 of applied stress level(q). During fatigue test, $Al_{2}$O$_{3}$/Al composites displayed cyclic hardening at all applied stress levels. The most of resultant displacement due to permanent plastic deformation occurred in less than the first 5% of fatigue life. Displacement-to-failure of the fatigue test was smaller than that of the tensile test because of accumulative damage by cumulative plastic deformation.

${\gamma}-LiAlO_2$ Coating on Alumina Fibers by the Sol-Gel Method (졸-겔법에 의한 알루미나 화이버의 ${\gamma}-LiAlO_2$ 코팅)

  • 현상훈;홍성안;김완식;신현철
    • Journal of the Korean Ceramic Society
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    • v.31 no.11
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    • pp.1271-1282
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    • 1994
  • The surface of commercial alumina fibers used for reinforcing the MCFC matrix has been coated with ${\gamma}$-LiAlO2 being the same material as the matrix, by the sol-gel method in order to enhance the corrosion resistivity of alumina fibers. Stable LiAlO2 complex polymeric sols for coating was synthesized by mixing aluminum alkoxide polymeric sols with LiNO3 solution. It was found that the LiAlO2 polymeric sol prepared by adding the mixed chelate of acethylacetone and triethanolamine (the mole ratio of AA/TEA = 0.125/0.75) to the 1 mole of the aluminum alkoxide had the excellent stability and coating behavior. The crystalline structure of the dried gel from the ${\gamma}$-LiAlO2 sol was completely transformed into the ${\gamma}$-LiAlO2 at $600^{\circ}C$. The optimum viscosity of the sol for coating the alumina long fibers was 30~40 cP, while it was 12~20 cP in case of the short fiber coating. The ${\gamma}$-LiAlO2 coated alumina fibers without defects fully densified when heat-treated at 120$0^{\circ}C$.

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Influence of Binder and Applied Pressure on Tensile Strength of $AC4C/Al_2O_3$ Composites Made by Squeeze Casting Process (용탕단조법에 의한 Alumina단섬유강화 AC4C기 복합재료의 인장강도에 미치는 점결제 및 가압력의 영향)

  • Yeo, In-Dong;Lee, Chi-Hwan
    • Journal of Korea Foundry Society
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    • v.15 no.2
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    • pp.138-145
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    • 1995
  • The mechanical properties of $Al/Al_2O_3$ composites have been investigated in relation with manufacturing factors such as applied pressure of casting and binder amount of preform. It was found that tensile strength increases with an increase of applied pressure, but decreases with binder amount. Increase of tensile strength is attributable to refinement of microstructure, improvement of intefacial bonding between $Al_2O_3$ short fiber and matrix, decrease of porosity in the matrix. Due to the high thermal stability of alumina short fiber, tensile strength of composites at $150^{\circ}C$ was superior to matrix alloy at room temperature. To evaluate the strength of composites, modified Kelly-Tyson's equation was introduced. Manufacturing factor M was obtained calculating from experimental data. M values were increased with applied pressure, but decreased with binder amount. The initiation of microcrack appeared to be at interface and reinforcement colony. Amount of micro-dimple was increased with applied pressure, and interfacial debonding phenomenon was remarkable with an increase of binder amount.

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Various Metal Oxide Additions Based on TiO2 and Adsorption Characteristics of Hollow Fiber Adsorbent on Arsenic (TiO2 기반의 다양한 금속산화물 첨가와 중공사형 흡착제의 비소 흡착 특성)

  • Eom, Hanki;Jang, Younghee;Kim, Sung Su
    • Applied Chemistry for Engineering
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    • v.30 no.3
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    • pp.345-351
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    • 2019
  • In this study, the hollow fibers from $TiO_2$ and various metal oxides additives were fabricated and characterized in order to remove the arsenic substance from a contaminated water. Experimental results showed the best arsenic adsorption performance from pristine $TiO_2$ hollow fibers. When metal oxides were added, the metal oxides reduced the acid sites on the surface of $TiO_2$ and the arsenic adsorption performance decreased. However, the long term arsenic adsorption performance was enhanced and showed better performance than that of using pristine $TiO_2$ hollow fibers when $Al_2O_3$ was added during the hollow fiber fabrication. In addition, the arsenic adsorption performance showed a high dependency on the specific surface area of hollow fibers. It was confirmed that the abundancy of Lewis and Bronsted acid sites provided was favorable for the arsenic adsorption. It was also demonstrated that commercially available $TiO_2$ powders can be an attractive candidate material for manufacturing hollow fibers for a small scale water treatment plant.

Preparation of Titanium Carbide Fiber-Reinforced Alumina Ceramic Matrix Composites by Self-Propagating High-Temperature Synthesis

  • Yun, Jondo;Bang, Hwancheol
    • The Korean Journal of Ceramics
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    • v.4 no.3
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    • pp.171-175
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    • 1998
  • $Al_2O_3$-TiC composites were prepared from aluminum, titanium oxide, and carbon fibers by self-propagating high-temperature synthesis(SHS). After the SHS reaction, the TiC phase in the sample was found either fibrous or non-fibrous shape. The fraction of the fibrous TiC phase varied with the amount of $Al_2O_3$ diluent addition. The optimum amount of diluent to make fibrous carbide was determined to be 30%. The fibers were hollow inside and made of multiple grains with a composition of titanium carbide. The hollow fiber formation mechanism was suggested and discussed. The synthesized powders were consolidated to dense composites by hot pressing at $1750^{\circ}C$ under 30 MPa.

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Characteristic Strength of $\delta$-Al$_2$O$_3$/Aluminum Composite by Rheo-compocasting (반용융 가공법에 의한 $\delta$-Al$_2$O$_3$/Aluminum 복합재료의 강도 특성)

  • 이상필;김만수;김석호;윤한기
    • Proceedings of the KWS Conference
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    • 1995.04a
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    • pp.155-159
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    • 1995
  • A16061 alloy reinforced with 10 vol% $\delta$-A1$_2$O$_3$ short fiber have been fabricated by Rheo-compocasting and squeeze casting and extruded at high temperature using conical shape die and curved shape die with various extrusion ratios.. Tensile and hardness tests were carried out to examine mechanical properties of extruded materials and SEM observation of fractured surface was capable of accounting for fracture mechanism and bonding state of fiber and matrix.

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Preparation of High-Efficient Oil-based Nanofluids and It's Application to the Transformer (고효율 나노절연유 제조 및 변압기에의 적용)

  • Yoo, Hyun-Sung;Choi, Cheol;Oh, Je-Myung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.31-32
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    • 2007
  • Oil-based nanofluids are prepared by dispersing spherical and fiber-shaped $Al_2O_3$ and AlN nanoparticles in transformer oil. Two hydrophobic surface modification processes are compared in this investigation. It is obvious that the combination of nanoparticle, surfactant and surface modification process is very important for the dispersity of nanofluids. For ($Al_2O_3$+AIN) particles with 1% volume fraction, the enhancement of thermal conductivity and convective heat transfer coefficient is nearly 11% and 30%, respectively, compared to pure transformer oil. The cooling effect of ($Al_2O_3$+AlN)-oil nanofluids on the heating element and oil itself is confirmed by a natural convection test using a prototype transformer.

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Fabrication of Matrix for Molten Carbonate Fuel Cell by Adding Lower Purity $Al_2O_3$ Fiber (저순도 $Al_2O_3$ 화이버 첨가에 의한 용융탄산염형 연료전지용 매트릭스의 제조)

  • 안현구;이충곤;임희천
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.11a
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    • pp.233-233
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    • 2003
  • 용융탄산염형 연료전지의 성능과 수명은 매트릭스의 기계적 강도, 즉 균열발생과 미세구조 변화에 크게 좌우되고 있다. 매트릭스의 강도 증진은 거대입자를 분산 시키거나 A1$_2$O$_3$ 화이버를 분산시켜 이루어지고 있으며, 그 중 $Al_2$O$_3$ 화이버를 사용하는 경우에는 매트릭스 강화효과에 매우 유리하지만 지금까지 사용한 A1$_2$O$_3$ 화이버가 매우 고가이기 때문에 저가의 A1$_2$O$_3$ 화이버 검토가 요구되고 있다. 본 연구에서는 경쟁력 있는 매트릭스 개발을 목적으로 저순도 및 고순도의 상용 A1$_2$O$_3$ 화이버를 첨가한 매트릭스를 제조하여 미세구조와 강도증진 효과 그리고 단위전지 운전성능을 비교분석 하였다. 실험에 사용한 저순도 A1$_2$O$_3$ 화이버의 길이와 직경은 각각 200 $\mu\textrm{m}$ 와 3 $\mu\textrm{m}$ 이었으며, 고순도 A1$_2$O$_3$ 화이버는 3000 $\mu\textrm{m}$ 와 10 $\mu\textrm{m}$ 이었다.

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Microstructure and high temperature mechanical properties of sapphire/R-Al-O(R = Y, Gd, Er, Ho, Dy) eutectic fibers grown by micro-pulling-down method

  • Hasegawa, K.;Yoshikawa, A.;Durbin, S.D.;Epellbaum, B.M.;Fukuda, T.;Waku, Y.
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.9 no.4
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    • pp.432-436
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    • 1999
  • Fiber growth of $Al_{2}O_{3}/R-Al-O$ (R = Y, Gd, Dy, Ho, Er) eutectic by the micro-pulling down method is described. The thermal stability and strength at elevated temperature of each materials is evaluated in relation to the microstructure.

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Capacitance Properties of Nano-Structure Controlled Alumina on Polymer Substrate (폴리머 기판위에 형성된 나노구조제어 알루미나의 캐패시터 특성)

  • Jung, Seung-Won;Min, Hyung-Sub;Han, Jeong-Whan;Lee, Jeon-Kook
    • Korean Journal of Materials Research
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    • v.17 no.2
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    • pp.81-85
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    • 2007
  • Embedded capacitor technology can improve electrical perfomance and reduce assembly cost compared with traditional discrete capacitor technology. To improve the capacitance density of the $Al_2O_3$ based embedded capacitor on Cu cladded fiber reinforced plastics (FR-4), the specific surface area of the $Al_2O_3$ thin films was enlarged and their surface morphologies were controlled by anodization process parameters. From I-V characteristics, it was found that breakdown voltage and leakage current were 23 V and $1{\times}10^{-6}A/cm^2$ at 3.3 V, respectively. We have also measured C-V characteristics of $Pt/Al_2O_3/Al/Ti$ structure on CU/FR4. The capacitance density was $300nF/cm^2$ and the dielectric loss was 0.04. This nano-porous $Al_2O_3$ is a good material candidate for the embedded capacitor application for electronic products.