• Korean Journal of Metals and Materials
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• v.48 no.5
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• pp.469-475
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• 2010

In this study, the interfacial bond strength of a squeeze infiltrated $Al_{18}B_{4}O_{33}$/AS52 Mg composite was investigated by using a finite element method. Three types of Mg composites with volume fractions of 15, 25 and 35% were fabricated. Three-dimensional models of the composite were developed by using a unit cell model in order to determine the effective elastic modulus of the metal matrix composite and the interfacial bond strength between the whisker and magnesium matrix. After modeling, numerical results were compared with the experimental tensile test results of $Al_{18}B_{4}O_{33}$/AS52 Mg composites. The results showed that the effective modulus of the composite strongly depended on the interfacial strength between the matrix and reinforcement. Based on the numerical and experimental findings, it was found that the strong interfacial bond was achieved by the interfacial reaction product of 30 nm thick MgO, which led to an improvement in the mechanical properties of the $Al_{18}B_{4}O_{33}$/AS52 Mg composites.

• Transactions of the Korean Society of Automotive Engineers
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• v.11 no.5
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• pp.140-146
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• 2003

Metal matrix composites had generated a lot of interest in recent time because of their high specific strength and stiffness in specific properties. It was also highlighted as the material of frontier industry because strength, heat-resistance, corrosion-resistance and wear-resistance were superiored. In this study, the strength properties of $Al_{18}B_{4}O_{33}$/AC4CH composites were represented mixing the binder of $SiO_2$. It was also fabricated by squeeze casting. $Al_{18}B_{4}O_{33}$/AC4CH was fabricated at the melt temperature of $760^{\circ}C$, the perform temperature of $700^{\circ}C$ and mold temperature of $200^{\circ}C$ under the pressure of 83.4MPa. Consequently, fatigue life was observed roughly in the order of AC4CH> nobiner> $SiO_2$, independently on crack propagation direction and stress ratio.

• Korean Journal of Metals and Materials
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• v.46 no.7
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• pp.412-419
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• 2008

Creep behavior of the squeeze infiltrated AS52 Mg matrix composites reinforced with 15 vol% of aluminum borate whiskers($Al_{18}B_4O_{33}w$) fabricated squeeze infiltration method was investigated. Microstructure of the composites was observed as uniformly distributed reinforcement in the matrix without any particular defects of casting pores etc.. Creep test was carried out at the temperature of 150 and $200^{\circ}C$ under the applied stress range of 60~120 MPa. The creep resistance of the composite was significantly improved comparing with the unreinforced AS52 Mg alloy. The creep behavior of composites might be interpreted with the substructure invariant model successfully for the composite. Threshold stress of the composite exist for the creep deformation of the composite. The analysis of the creep behavior of the composite with threshold stress indicated that creep deformation was controlled by the lattice diffusion process of AS52 Mg matrix at given effective stresses and temperatures. Activation energy was also calculated to check lattice diffusion controlled creep behavior of the composite.

• Journal of Korea Foundry Society
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• v.28 no.6
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• pp.268-272
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• 2008

Interfacial characteristics of aluminum borate whisker reinforced AS52 matrix composite was investigated. Peak hardness of AS52 composite was obtained aging at $170^{\circ}C$ for 15h and the aging process was accelerated by the presence of the aluminium borate whisker. The MgO layer, which was the interfacial reaction product between the reinforcement and the Mg matrix, was produced with 20 nm thickness in as-cast condition. As the aging time increased, the thickness of the interfacial reaction layer increased to 50 nm in peak aged condition. The nano-indentation test results indicated that the strength of interface was improved by the aging but over-aging degraded the reinforcement and decreased the interfacial strength which resulted in the decrease of overall composite strength.

• Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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• 2002.05a
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• pp.155-160
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• 2002

Metal matrix composites had generated a lot of interest in recent times because of significant in specific properties. It was also highlighted as the materials of frontier industry because strength, heat-resistant, corrosion-resistant, wear-resistant were superiored. In this study the strength properties of $Al_{18}B_4O_{33}/AC4CH$ were represented mixing the binder of $Al_2O_3$ and $TiO_2$. It was also fabricated by squeeze casting. $Al_{18}B_4O_{33}/AC4CH$ was fabricated at the melt temperature of $760^{\circ}C$ the perform temperature of $700^{\circ}C$ and mold temperature of $200^{\circ}C$ under the pressure of 83.4MPa and observed SEM. Fatigue crack growth rate tests on compact tension specimen(half-size) of thickness 12.5mm were conducted by using sinusoidal waveform. Compact tension specimens(half-size) were used and fatigue crack growth rate da/dN and stress intensity factor range ${\Delta}K$ were analyzed concerning to the R value of 0.1 and 0.05. In order to find out the value of ${\Delta}K$, load amplitude constant method was applied by the standard fatigue testing method describes in ASTM E647-95a. As the results of this study, Fatigue crack growth rate increased with in creasing the load ratio, Consequently, At equivalent stress intensity factors, the fatigue crack growth rates in MMC were faster than those of AC4CH alloy. then the fatigue life and the fatigue crack growth rate was investigated using scanning election microscopy(SEM)

• Proceedings of the KSME Conference
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• 2001.06a
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• pp.363-369
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• 2001

By alternating $Al_{18}B_4O_{33}$/AC4CH composites with Al1050 sheets and then hot pressing, MMC/Al laminate composites have been successfully fabricated as parameters of the laminate structure and the number of Al sheet. Impact properties for laminate composites have been evaluated both in the laminate structure and in the impact load direction. Lamination of Al sheet and MMC layer showed a remarkable improvement in the absorbed impact energy compared to that of monolithic MMC. Laminate composites mounted with Al sheet at the outside of the configuration had a higher impact energy in the edge wise compared to that with Al sheet at the inside. Furthermore, there was an anisotrpy in the impact value of laminate composites, that is, impact values for the flat wise in a constant volume fraction of Al sheet dramatically increased along with Al sheet number, even if impact values fur the edge wise were nearly constant.

• Transactions of the Korean Society of Automotive Engineers
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• v.9 no.5
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• pp.188-194
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• 2001

Metal matrix composites with whisker reinforcements have significant potential for demanding mechanical applications including defense, aerospace, and automotive industries. Especially, metal matrix composites, which are reinforced with aluminum borate whisker, have been used for the part of piston head in automobile because of good specific strength and wear resistance. Aluminum alloy-based metal matrix composites with whisker reinforcements have been produced using squeeze casting method, which is kind of an infiltration method. In this study, AC4CH-based metal matrix composites with $Al_{18}B$_4$O_{33}$ reinforcement have been produced using squeeze casting method, after T6 heat treatment, we evaluated mechanical properties of matrix and MMC composite were evaluated.

• Economic and Environmental Geology
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• v.30 no.1
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• pp.35-49
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• 1997

The coal formation of the Deokpyeong area are interbedded along metapelites of the Ogcheon Supergroup, which are composed mainly of graphite, quartz, muscovite and associated with small amounts of biotite, chlorite, pyrite and barite. The ratios of $SiO_2/Al_2O_3$, $Al_2O_3/Na_2O$ and $K_2O/Na_2O$ of the coaly metapelite are variable and wide range from 1.80 to 10.21, from 27.8 to 388.8 and from 7.6 to 61.8, respectively. These coal formation were deposited in basin of marine environments, and the REE of these rocks are not influenced with metamorphism and hydrothermal alterations on the basis of $Al_2O_3$ versus La, La against Ce, the ratios of La/Ce (0.19 to 0.99) and Th/U (0.02 to 4.75). These rocks also show much variation in $La_N/Yb_N$ (1.19 to 22.89), Th/Yb (0.14 to 21.43) and La/Th (0.44 to 13.67), and their origin is explained by derivation from a mixture of sedimentary and igneous rocks. The wide range in trace and REE element characteristics as Co/Th (0.12 to 2.78), La/Sc (0.33 to 10.18), Sc/Th (0.57 to 5.73), V/Ni (8 to 2347), Cr/V (0.02 to 0.67) and Ni/Co (1.56 to 32.95) of these coaly metapelites argues for inefficient mixing of the various source lithologies during sedimentation. Deep to pale green barium-vanadium muscovites (vanadium-oellacherite) have been found in this coal formations. Modes of occurrence and grain size of muscovite are heterogeneous, but most of the barium and vanadium-bearing muscovites occur along the boundaries between graphite and quartz grains, ranging from 200 to $350{\mu}m$ in length and from 40 to $60{\mu}m$ in width. Results of X-ray diffraction data of the minerals characterized to be monoclinic system with $a=5.249{\AA}$, $b=8.939{\AA}$, $c=20.924{\AA}$ and ${\beta}=95.894^{\circ}$. Representative chemical formula of the muscovite was $(Na_{0.09}K_{1.44}Ba_{0.46})(Al_{2.75}Ti_{0.07}V_{0.56}Fe_{0.08}Mg_{0.50})(Si_{6.12}Al_{1.88})O_{22}$. The V possibly substitute octahedral Al, and the Ba is coupled substitution of $K^+Si^{4+}=Ba^{2+}Na^+Ca^{2+}$, which compositional ranges of V and Ba are from 0.42 to 0.69 and from 0.34 to 0.56 based on $O_{22}$, respectively. Formation mechanism of the barium-vanadium muscovites in the coaly metapelite is shown that the formed by high pressure and temperature from regional metamorphism origanated during diagenesis at the interface between a basinal brine and organic matter.

• Korean Journal of Mineralogy and Petrology
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• v.33 no.1
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• pp.11-18
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• 2020

High-pressure synchrotron X-ray powder diffraction experiments were performed on natural illite (K_0.65Al₂(Al_0.65Si_3.35)O₁₀(OH)₂) using diamond anvil cell (DAC) under two different pressure transmitting media (PTM), i.e., water and ME41 (methanol:ethanol = 4:1 by volume). When using water as PTM, occasional heating was applied up to about 250℃ while reaching pressure up to 2.7 GPa in order to promote both hydrostatic conditions and intercalation of water molecules into the layer. When using ME41, pressure was reached up to 6.9 GPa at room temperature. Under these conditions, illite did not show any expansion of interlayer distance or phase transitions. Pressure-volume data were used to derive bulk moduli (K₀) of 45(3) GPa under water and 51(3) GPa under ME41 PTM. indicating no difference in compressibility within the analytical error. Linear compressibilities were then calculated to be β^a = 0.0025, β^b = 0.0029, β^c = 0.0144 under ME41 PTM showing the c-axis is ca. six times more compressible than a- and b-axes. These elastic behaviors of illite were compared to muscovite, one of its structural analogues.

• ALGAE
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• v.38 no.2
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• pp.127-139
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• 2023

Cryptic stages of diverse macroalgae present in natural substrata, "the bank of microscopic forms", were isolated into clonal cultures and identified based on both morphological characteristics and DNA barcoding. Approximately 120 clonal isolates from 308 natural substratum samples were collected from the entire coastline of Kuwait. Amongst these isolates, 77 (64%) were identified through DNA barcoding using the nuclear ribosomal small subunit, RuBisCO spacer (ITS2, tufa, rbcL, psaA, and psbA) and sequencing. Twenty-six isolates (34%) were identified in the division Chlorophyta, 18 (23%) as Phaeophyceae, and 33 (43%) as Rhodophyta. For all DNA sequences in this study, species-level cut off applied was ≥98% homology which depend entirely on the markers used. Three putative new records of Chlorophyta new for the Arabian Gulf were made: Cladophora laetevirens (Dillwyn) Kützing, Ulva torta (Mertens) Trevisan and Ulvella leptochaete (Huber) R. Nielsen, C. J. O'Kelly & B. Wysor in Nielsen, while Cladophora gracilis Kützing and Ulva ohnoi M. Hiraoka & S. Shimada are new records for Kuwait. For Phaeophyceae, Ectocarpus subulatus Kützing and Elachista stellaris Areschoug were new records for the Gulf and Kuwait. In the Rhodophyta, Acrochaetium secundatum (Lyngbye) Nägeli in Nägeli & Cramer, Ceramium affine Setchell & N. L. Gardner, Gelidium pusillum var. pakistanicum Afaq-Husain & Shameel and Dasya caraibica Børgesen are new records for the Gulf and Kuwait, while the red alga Stylonema alsidii (Zanardini) K. Drew is a new record for Kuwait. Several isolates identified corresponded to genera not previously reported in Kuwait and / or the Arabian Gulf, such as Porphyrostromium Trevisan, a new genus from the Bangiales, and two unidentified species for the Planophilaceae Škaloud & Leliaert. The isolates cultivated from substrata enhance understanding of the marine macroalgal diversity in the region and confirmed that the Germling Emergence Method is suitable for determining the actual diversity of a given study area through isolation from cryptic life-history phases.