• Title/Summary/Keyword: $AlQ_3$

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Microstructural Characterization of $CaTiO_3-NdAlO_3$-Based Ceramics

  • Suvorov, Danilo;Drazic, Goran;Valant, Matjaz;Jancar, Bostjan
    • Korean Journal of Crystallography
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    • v.11 no.4
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    • pp.195-199
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    • 2000
  • Ceramics based on CaTiO₃-NdAlO₃ solid solutions were synthesized in order to study their dielectric microwave properties. Microstructural analysis was performed with scanning electron microscopy (SEM) and transmission electron microscopy (TEM) using different analytical methods such as energy-dispersive X-ray spectroscopy (EDXS). It was observed that the heating conditions during sintering and cooling strongly affect the microstructural development of CaTiO₃-NdAlO₃-based ceramics. Various types and concentrations of structural defects were identified, for example, dislocations, twins and/or antiphase boundaries. all such defects resulted in a degradation of the dielectric microwave properties, in particular the quality factor Q. Dielectric properties of CaTiO₃-NdAlO₃-based ceramics can be improved by an appropriate thermal treatment of ceramics which results in a decrease in the concentrations of the identified microstructural defects.

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Magnetic Properties of High Electrical Resistive CoPdAlO Film for RF Device (높은 비저항을 갖는 RF 소자용 CoPdAlO 박막의 자기적 특성)

  • 김택수;이영우;김종오
    • Journal of the Korean Magnetics Society
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    • v.11 no.3
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    • pp.109-113
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    • 2001
  • Presently, an inductor adapted at MMIC (Monolithic Microwave Integrated Circuit) which is used for cellular phone or PHS operates at quasi-microwave range over 800 MHz. However, a W-CDMA (Wideband Code Division Multiple Access) will use about 2 GHz range. Therefore magnetic film device should be compatible up to 2 GHz. We have deposited Co-Pd-Al-O system film using rf sputtering method which is expected up to 2 GHz, and investigated the effect of Pd content and magnetic field annealing. When Pd composition is 19%, Hk was 118 Oe, and ${\mu}$′showed flat frequency characteristics up to 1.5 GHz. The Q factor (=${\mu}$′/${\mu}$") was 23.3 at 1 GHz, 6.7 at 1.5 GHz and 1.5 at 2 GHz, respectively. Resonance frequency was 2 GHz. Therefore Co-Pd-Al-O thin film could be used at over 1 GHz, and also expected as an inductor material for wide band CDMA type cellular phone.

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POLYNOMIAL COMPLEXITY OF PRIMAL-DUAL INTERIOR-POINT METHODS FOR CONVEX QUADRATIC PROGRAMMING

  • Liu, Zhongyi;Sun, Wenyu;De Sampaio, Raimundo J.B.
    • Journal of applied mathematics & informatics
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    • v.27 no.3_4
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    • pp.567-579
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    • 2009
  • Recently, Peng et al. proposed a primal-dual interior-point method with new search direction and self-regular proximity for LP. This new large-update method has the currently best theoretical performance with polynomial complexity of O($n^{\frac{q+1}{2q}}\;{\log}\;{\frac{n}{\varepsilon}}$). In this paper we use this search direction to propose a primal-dual interior-point method for convex quadratic programming (QP). We overcome the difficulty in analyzing the complexity of the primal-dual interior-point methods for convex quadratic programming, and obtain the same polynomial complexity of O($n^{\frac{q+1}{2q}}\;{\log}\;{\frac{n}{\varepsilon}}$) for convex quadratic programming.

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Effect of Impurity Addition on the Microwave Dielectric Properties of $(Ba_{0.93}Sr_{0.07}O)-0.5Sm_2O_3-4.5TiO_2$ Ceramics ($(Ba_{0.93}Sr_{0.07}O)-0.5Sm_2O_3-4.5TiO_2$계 세라믹스의 불순물 첨가에 따른 마이크로파 유전특성)

  • Kim, Tae-Joong;Jang, Jae-Hoon;Lee, Hee-Young
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07b
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    • pp.1148-1151
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    • 2002
  • Dielectric ceramics with nominal composition of $(Ba_{0.93}Sr_{0.07}O)-0.5Sm_2O_3-4.5TiO_2$ was prepared using the conventional mixed oxide process-derived powder. Effect of $SiO_2$, $MnO_2$ and $Al_2O_3$ impurity addition on the microwave properties was examined in some detail. Measured relative permittivity $(\varepsilon_r)$ values were in the range of 53 to 59 and showed little dependence on impurity addition. In contrast, quality factor $(Q{\cdot}f)$ and temperature coefficient of resonant frequency $(\tau_f)$ values were greatly influenced by the type and the amount of impurities. It was found that 0.1~0.2wt% addition of $Al_2O_3$ was most effective for improving the properties, where ${\varepsilon}_r$, $Q{\cdot}f$ and $\tau_f$ values were 57.7, 10000, and +7ppm/$^{\circ}C$, respectively.

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High Speed LTCC 기판 소재의 LTCC 공정 평가

  • Hong, Seung-Hyeok;Sin, Hyo-Sun;Hong, Yeon-U;Yeo, Dong-Hun;Kim, Jong-Hui
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.304-304
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    • 2008
  • 최근 이동통신의 사업의 발달로 인하여 제품의 고속신호 전달에 대한 관심이 부각되고 있다. 이로 인해 고집적 LTCC 모듈로 제작이 가능하고 고속신호 전달이 용이한 저유전율과 낮은 loss특성을 요구하는 소재 개발의 지속적인 연구를 필요로 한다. 지금까지의 ceramic/glass composite에서 주로 사용된 ceramic filler는 $Al_2O_3$로 낮은 유전율을 구현하는데 한계가 있었다. Cordierite는 낮은 유전율(${\varepsilon}r$ < 4)을 나타내는 filler로서 저유전율 기판소재로 사용될 가능성이 높지만 아직까지 보고된 결과들이 미흡한 실정이다. 선행 연구에서 cordierite filler와 $SiO_2-B_2O_3-Al_2O_3$-RO (R Zn, Sr, Ba, Ca)계의 glass를 혼합하여 LTCC 용 기판소재로서의 가능성을 확인한 결과 5.0~5.5 의 낮은 유전율과 1,000~1,500의 Q를 나타내는 것을 확인 하였다. 하지만 sheet로 제작 시 $B_2O_3$ 계로 인해 볼밀 공정에서 슬러리를 응집시켜 점도를 증가(gelation)시키는 현상이 발생하였다. 이를 개선하기 위한 glass 조성의 $B_2O_3$ 함량을 5%줄여 만든 glass를 이용해 미세구조, 유전율과 Q 그리고 강도를 측정하였다.

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Evaluation of Aluminum and Copper Biosorption in Two-Metal System using Algal Biosorbent

  • Lee, Hak-Sung;Volesky, Bohumil
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • v.2 no.2
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    • pp.149-158
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    • 1998
  • Biomass of non-living brown seaweed Sargassun fluitans pretreated with NaOH is capable of taking up more than $10\%$ $(q_{max}$ : 3.85 mmol/g for Al and 1.48 mmol/g for Cu) of its dry weight in the Al and Cu at pH of 4.5. However, the maximum Al and Cu uptakes calculated from Langmuir isotherm were 1.58 mmol/g for Al and 1.35 mmol/g for Cu at pH 3.5. Equilibrium batch sorption study was performed using two-metal system containing Al and Cu. The mathematical model of the two-metal sorption system enabled quantitative estimation of one-metal biosorption inhibition due to the influence of a second metal. NaOH-treated S. fluitans contained 2.19 mmol $(43\;wt.\%)$ carboxyl groups per gram of biomass. A modified form of Langmuir, which assumes binding of Cu as $Cu^{2+}$ and Al as $Al(OH)_2^+,$ was used to model the experimental data. This result agrees with the one of mono-valent sorption for Al in single-metal system. The modified Langmuir model gives the following affinity correlated coefficients: 0.196 for Cu and 6.820 for Ah at pH 4.5, and 2.904 for Cu and 3.131 for Al at pH 3.5. The interference of Al in Cu biosorptive uptake was assessed by `cutting' the three dimensional uptake isotherm surfaces at constant second-metal final concentrations. Equimolar final equilibrium concentrations of Cu and Al of 1 mM at pH 4.5 give Cu and hi uptakes reduced by $82.5\%\;and\;5.4\%,$ respectively. However, these values at pH 3.5 were $55\%\;(Cu)\;and\;31\%$ (Al).

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Synthesis and dielectric properties of the $ZnAl_2O_4$ ceramics for low-firing (저온소결용 $ZnAl_2O_4$ 세라믹스의 합성 및 유전 특성)

  • Kim, Kwan-Soo;Yoon, Sang-Ok;Kim, Shin;Kim, Nam-Hyup;Kim, Yun-Han;Shim, Sang-Heung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.279-279
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    • 2007
  • Synthesis and dielectric properties of glass-ceramic composites with zinc borosilicate glass(here after ZBS glass) were investigated as functions of $ZnAl_2O_4$ phase synthesis method, glass addition (50~60 vol%) and sintering temperature ($600{\sim}950^{\circ}C$ for 2 hrs). The 50 vol% ZBS glass-$Al_2O_3$ and 60 vol% ZBS glass-$ZnAl_2O_4$ ensured successful sintering below $900^{\circ}C$. But the composition of 100-x-y vol% ZBS glass-x vol% $Al_2O_3-y$ vol% ZnO exhibited poor sinterability below $900^{\circ}C$ and the swelling phenomenon occurred in this composite with the large amount of ZBS glass. The sintering behavior of Glass-ceramic composites was affected by the crystallization of $ZnAl_2O_4$ which was formed by the reaction between ZBS glass and $Al_2O_3$. Dielectric constant (${\varepsilon}_r$), $Q{\times}f$ value and temperature coefficient of resonant frequency (${\tau}_f$) of the composite with 50 and 60 vol% ZBS glass contents demonstrated $ZBS-Al_2O_3({\varepsilon}_r=5.7)$, $ZBS-ZnAl_2O_4({\varepsilon}_r=5.8)$ which is applicable to substrate requiring an low dielectric properties.

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The Microwave Dielectric Properties on Glass Frit Addition of Low Temperature Co-fired Ceramic (Glass Frit 첨가에 따른 LTCC용 마이크로파 유전체의 유전 특성)

  • Yoon, Jung-Rag;Lee, Serk-Won;Lee, Heon-Young;Kim, Jee-Gyun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07b
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    • pp.611-615
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    • 2003
  • The crystalline and dielectric properties on $Al_2O_3$ filled glass frit ($CaO-Al_2O_3-SiO_2-MgO-B_2O_3$) with admixtures of $TiO_2$ have been investigated. The dielectric constant value of $7.5{\sim}7.8$, quality factor value of 700 were obtained for glass frit : $Al_2O_3$ (50 : 50 wt%) ceramics. As the amount of $TiO_2$ increased, temperature coefficient of dielectric constant were decreased.

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High Temperature Deformation Behavior of $SiC_p/Al-Si$ Composites ($SiC_p/Al-Si$ 복합재료의 고온변형 특성)

  • 전정식;고병철;김명호;유연철
    • Transactions of Materials Processing
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    • v.3 no.4
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    • pp.427-439
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    • 1994
  • The high temperature deformation behavior of $SiC_p/Al-Si$ composites and Al-Si matrix was studied by hot torsion test in a range of temperature from $270^{\circ}C$ to $520^{\circ}C$ and at strain rate range of $1.2{\times}10_{-3}~2.16{\times}10_{-1}/sec$. The hot restoration mechanisms for both matrix and composites were found to be dynamic recrystallization(DRX) from the investigation of flow curves and microstructural evolutions. The Si precipitates and SiC particles promoted DRX, and the peak strain$({\varepsilon}_p)$ of the composites was smaller than that of the matrix. Flow stresses of $SiC_p/Al-Si$ composites were found to be generally higher than the matrix, but the difference was quite small at higher temperature due to the decrease of capability of load transfer by SiC particles. With increasing temperature, failure strain of matrix and composites are inclined to increase, the increasing value of failure strain for the $SiC_p/Al-Si$ composites was small compared to that of matrix. The stress dependence of both materials on strain rate() and temperature(T) was examined by hyperbolic sine law, $\.{\varepsilon}=A_1[sinh({\alpha}{\cdot}{\sigma})]_n$exp(-Q/RT)

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The Thermal Stability and Elevated Temperature Mechanical Properties of Spray-Deposited $SiC_P$/Al-11.7Fe-1.3V-1.7Si Composite

  • Hao, L.;He, Y.Q.;Wang, Na;Chen, Z.H.;Chen, Z.G.;Yan, H.G.;Xu, Z.K.
    • Advanced Composite Materials
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    • v.18 no.4
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    • pp.351-364
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    • 2009
  • The thermal stability and elevated temperature mechanical properties of $SiC_P$/Al-11.7Fe-1.3V-1.7Si (Al-11.7Fe-1.3V-1.7Si reinforced with SiC particulates) composites sheets prepared by spray deposition (SD) $\rightarrow$ hot pressing $\rightarrow$ rolling process were investigated. The experimental results showed that the composite possessed high ${\sigma}_b$ (elevated temperature tensile strength), for instance, ${\sigma}_b$ was 315.8 MPa, which was tested at $315^{\circ}C$, meanwhile the figure was 232.6 MPa tested at $400^{\circ}C$, and the elongations were 2.5% and 1.4%, respectively. Furthermore, the composite sheets exhibited excellent thermal stability: the hardness showed no significant decline after annealing at $550^{\circ}C$ for 200 h or at $600^{\circ}C$ for 10 h. The good elevated temperature mechanical properties and excellent thermal stability should mainly be attributed to the formation of spherical ${\alpha}-Al_{12}(Fe,\;V)_3Si$ dispersed phase particulates in the aluminum matrix. Furthermore, the addition of SiC particles into the alloy is another important factor, which the following properties are responsible for. The resultant Si of the reaction between Al matrix and SiC particles diffused into Al matrix can stabilize ${\alpha}-Al_{12}(Fe,\;V)_3Si$ dispersed phase; in addition, the interface (Si layer) improved the wettability of Al/$SiC_P$, hence, elevated the bonding between them. Furthermore, the fine $Al_4C_3$ phase also strengthened the matrix as a dispersion-strengthened phase. Meanwhile, load is transferred from Al matrix to SiC particles, which increased the cooling rate of the melt droplets and improved the solution strengthening and dispersion strengthening.