• 제목/요약/키워드: $AlF_3$

검색결과 1,166건 처리시간 0.033초

1.54um 광섬유 광증폭기 Er-doped Zirconiumfluoride 유리제조 (Fabrication of zirconiumfluoride Glasses used for 1.54um Fiber Amplifier)

  • 조운조
    • 한국광학회:학술대회논문집
    • /
    • 한국광학회 1989년도 제4회 파동 및 레이저 학술발표회 4th Conference on Waves and lasers 논문집 - 한국광학회
    • /
    • pp.140-142
    • /
    • 1989
  • 1.54um 파장에서 최대 형광을 나타내는 ZrF4-BaF2-LaF3-AlF3-NaF : ErF3 유리를 built-in-casting 법에 의해 제조하였다. Er+3 이온을 0.2몰부터 4몰까지 첨가하였으며, Er+3 이온의 4I13/2 준위의 lifetime 은 Er+3 이온 0.2몰부터 2몰까지 28msec로 최대값을 갖으며 4몰일때는 급격히 감소하였다.

  • PDF

AlSl 420F 스테인리스강의 Creep 거동 (A Study on the Creep Behavior of AlSl 420F Stainless Steel)

  • 박용권;윤병주;최재하
    • 열처리공학회지
    • /
    • 제13권6호
    • /
    • pp.383-390
    • /
    • 2000
  • The static creep behaviour of AlSl 420F stainless steel was investigated over the temperature range of $540{\sim}585^{\circ}C$ and the stress range of $13{\sim}19kg/mm^2$ (127.4~186.2MPa). Constant stress creep tests were carried out in the experiment. Measured stress exponent, n, for the creep deformation of the alloy under the given conditions was found to vary at the range of 9.59, 9.15, 8.78, and 8.53 for the temperature of 540, 555, 570, and $585^{\circ}C$ respectively. The activation energy, Qc, for the creep deformation was 106.42, 102.58,97.81, and 94.58 kcal/mole for the stress of 13, 15, 17, and $19kg/mm^2$, respectively. Lason-Miller parameter, P, for the crept specimens for AlSl 420F stainless steel was measured as $P=T(log\;t_T+21)$. The empirical static creep rate obtained by the regression analysis was as follows. $${\varepsilon}={\exp}[(3.79{\times}10^{-2}{\sigma}+2.722)T-3.0747{\sigma}+28.109]{\times}{\sigma}^{(-2.367{\times}10^{-2}T+22.33)}{\exp}\left[-\frac{(-2.015{\sigma}+132.580){\times}10^3}{RT}\right]$$ The failure plane were observed, intergranular fracture was dominated by r (round) type crack over the experimental range.

  • PDF

γ-Al2O3 촉매상에서 열분해와 가수분해에 의한 NF3 촉매분해 특성 (Catalytic Decomposition of NF3 by Thermal Decomposition and Hydrolysis of γ-Al2O3)

  • 김용술;박노국;이태진
    • 공업화학
    • /
    • 제26권2호
    • /
    • pp.154-158
    • /
    • 2015
  • 본 연구에서는 $NF_3$의 분해를 위한 ${\gamma}-Al_2O_3$의 촉매활성을 조사하였다. $NF_3$ 분해반응은 고정층 촉매반응기에서 $330{\sim}730^{\circ}C$ 범위의 반응온도와 $3,000{\sim}15,000mL/g-cat{\cdot}h$의 공간속도 조건에서 수행되었고, $NF_3$의 열분해 반응이 촉매분해반응와 비교를 위하여 함께 수행되었다. $400^{\circ}C$의 촉매분해 반응에서 $NF_3$의 전화율은 열분해 반응보다 4배 정도 높았으며, ${\gamma}-Al_2O_3$상에서 $NF_3$의 반응거동은 스팀의 존재에 따라 두 가지 반응경로를 나타내는 것으로 확인되었다. 스팀이 존재하지 않은 조건에서는 기체-고체 반응에 의해서 $NF_3$에 함유된 불소성분은 $AlF_3$로 전이되고, 스팀이 존재하는 조건에서는 가수분해에 의한 촉매적 분해반응이 일어난다. 또한 $NF_3$$500^{\circ}C$ 이상에서 NOx와 HF로 완전히 분해되는 것으로 FT-IR분석에서 확인되었다.

AlGaN/InGaN HEMTs의 고성능 초고주파 전류 특성 (DC and RF Characteristics of AlGaN/InGaN HEMTs Grown by Plasma-Assisted MBE)

  • 이종욱
    • 한국전자파학회논문지
    • /
    • 제15권8호
    • /
    • pp.752-758
    • /
    • 2004
  • 본 논문에서는 MBE로 성장한 AlGaN/InGaN/GaN 에피층으로 제작된 GaN HEMTs의 특성을 분석하였다. 게이트 전극 길이가 0.5 $\mu$m로 제작된 소자는 비교적 평탄한 전류 전달 특성을 나타내었으며 최대 전류 880 mA/mm, 최대 전달정수 156 mS/mm, 그리고 $f_{r}$$f_{MAX}$는 각각 17.3 GHz와 28.7 GHz가 측정되었다. 또한 표면 처리되지 않은 AlGaN/InGaN/HEMT의 경우 기존의 AlGaN/GaN HEMT와는 달리 펄스 전류 동작 상태에서 전류 와해 현상(current collapse)이 발생하지 않음이 확인되었다. 이 연구 결과는 InGaN를 채널층으로 사용할 경우 표면에 존재하는 트랩에 의한 전류 와해 현상이 발생하지 않는 고성능, 고출력의 GaN HEMT를 제작할 수 있음을 보여준다....

AI 합금 정밀단조를 위한 금형설계 및 공정조건의 영향 (The Effects of the Process and Die Design for Precision Forging of Al Alloys)

  • 이영선;이정환
    • 한국정밀공학회지
    • /
    • 제16권11호
    • /
    • pp.166-173
    • /
    • 1999
  • Al forged parts are many cases with rib-web section which is difficult to manufacture precisely. Therefore, process conditions must be optimized for precision forging of Al alloys. In this study, various process parameters such as die design, lubricant, ram speed, forging temperature have been investigated using the experiment, upper bound theory and F.E.M. simulation to develop the precision forging technology for rib-web shape component. When lubricant is applied to both material and die, shear friction factor is 0.1 which shows best effect of lubricant. It is specific corner radius of die that minimized forging load regarding process conditions, especially according to the ratio of the width of rib and web. In conclusion, optimum corner radius is 2~3mm when the width of rib and web is 3mm and 20mm respectively.

  • PDF

저온소결 $Al_2O_3-TiO_2$ 세라믹의 마이크로파 유전특성에 관한 연구 (Low Temperature sintering of $Al_2O_3-TiO_2$ ceramics)

  • 임은경;김창일;박용준;이영진;남산;백종후
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2007년도 하계학술대회 논문집 Vol.8
    • /
    • pp.252-252
    • /
    • 2007
  • $Al_2O_3-TiO_2$(AT)ceramics shows great promise as a dielectric material for millimeter-wave use. The sintering temperature of AT ceramics was approximately $1450^{\circ}C$ and decreased to $900^{\circ}C$ with the addition of BaCu(B2O5) (BCB) ceramic powder. The presence, of the liquid phase was responsible for the decrease of the sintering temperature. The liquid phase is considered to have a composition similar to the BaO-deficient BCB. The Q-value initially increased with the addition of BCB, but decreased considerably when a large amount of BCB was added, because of the presence of the liquid phase. Good microwave dielectric properties of $Q{\times}f\;=\;16,200\;GHz$, ${\varepsilon}_r\;=\;9$ and ${\tau}_f\;=\;-4\;ppm/^{\circ}C$ were obtained for the 20.0 mol% BCB-added AT ceramics sintered at $900^{\circ}C$ for 2 h.

  • PDF

Characteristics of $Al_2O_3/TiO_2$ multi-layers as moisture permeation barriers deposited on PES substrates using ECR-ALD

  • 권태석;문연건;김웅선;문대용;김경택;박종완
    • 한국진공학회:학술대회논문집
    • /
    • 한국진공학회 2009년도 제38회 동계학술대회 초록집
    • /
    • pp.457-457
    • /
    • 2010
  • Flexible organic light emitting diodes (F-OLEDs) requires excellent moisture permeation barriers to minimize the degradation of the F-OLEDs device. Specifically, F-OLEDs device need a barrier layer that transmits less than $10^{-6}g/m^2/day$ of water and $10^{-5}g/m^2/day$ of oxygen. To increase the life time of F-OLEDs, therefore, it is indispensable to protect the organic materials from water and oxygen. Severe groups have reported on multi-layerd barriers consisting inorganic thin films deposited by plasma enhenced chemical deposition (PECVD) or sputtering. However, it is difficult to control the formation of granular-type morphology and microscopic pinholes in PECVD and sputtering. On the contrary, atomic layer deoposition (ALD) is free of pinhole, highly uniform, conformal films and show good step coverage. Thus, $Al_2O_3/TiO_2$ multi-layer was deposited onto the polyethersulfon (PES) substrate by electron cyclotron resonance atomic layer deposition (ECR-ALD), and the water vapor transmission rates (WVTR) were measured. WVTR of moisture permeation barriers is dependent upon density of films and initial state of polymer surface. A significant reduction of WVTR was achieved by increasing density of films and by applying low plasma induced interlayer on the PES substrate. In order to minimize damage of polymer surface, a 10 nm thick $TiO_2$ was deposited on PES prior to a $Al_2O_3$ ECR-ALD process. High quality barriers were developed from $Al_2O_3$ barriers on the $TiO_2$ interlayer. WVTR of $Al_2O_3$ by introducing $TiO_2$ interlayer was recorded in the range of $10^{-3}g/m^2.day$ at $38^{\circ}C$ and 100% relative humidity using a MOCON instrument. The WVTR was two orders of magnitude smaller than $Al_2O_3$ barriers directly grown on PES substrate without the $TiO_2$ interlayer. Thus, we can consider that the $Al_2O_3/TiO_2$ multi-layer passivation can be one of the most suitable F-OLEDs passivation films.

  • PDF

ZnO:Al 투명전도막을 이용한 높은 개방전압을 갖는 비정질 실리콘 박막 태양전지 제조 (Amorphous silicon thin-film solar cells with high open circuit voltage by using textured ZnO:Al front TCO)

  • 이정철;안세진;윤재호;송진수;윤경훈
    • 신재생에너지
    • /
    • 제2권3호
    • /
    • pp.31-36
    • /
    • 2006
  • Superstrate pin amorphous silicon thin-film(a-Si:H) solar cells are prepared on $SnO_2:F$ and ZnO:Al transparent conducting oxides(TCO) in order to see the effect of TCO/p-layers on a-Si:H solar cell operation. The solar cells prepared on textured ZnO:Al have higher open circuit voltage VOC than cells prepared on $SnO_2:F$. Presence of thin microcrystalline p-type silicon layer(${\mu}c-Si:H$) between ZnO:Al and p a-SiC:H plays a major role by causing improvement in fill factor as well as $V_{OC}$ of a-Si:H solar cells prepared on ZnO:Al TCO. Without any treatment of pi interface, we could obtain high $V_{OC}$ of 994mV while keeping fill factor(72.7%) and short circuit current density $J_{SC}$ at the same level as for the cells on $SnO_2:F$ TCO. This high $V_{OC}$ value can be attributed to modification in the current transport in this region due to creation of a potential barrier.

  • PDF

Creep of Al and $Al-Al_4C_3$ Materials

  • Besterci, Michal;Spitas, Vasilios;Michelis, Paul;Spitas, Christos;Sulleiova, Katarna;Ballokova, Beata;Kvackaj, Tibor
    • 한국분말야금학회:학술대회논문집
    • /
    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
    • /
    • pp.1050-1051
    • /
    • 2006
  • PDF

용융 55%Al-Zn 중에서 세라믹 용사 피막의 침식 거동에 관한 연구 (A Study on the Erosion Behavior of the Ceramic Sprayed Coating Layer in the Molten 55% Al-Zn)

  • 강태영;임병문;최장현;김영식
    • Journal of Welding and Joining
    • /
    • 제18권3호
    • /
    • pp.51-59
    • /
    • 2000
  • Sink roll has been used in molten 55%Al-Zn alloy bath of continuous galvanizing line for sinking and stabilizing working steel strip in molten metal bath. In the process, the sink roll body inevitably build up dross compounds and pitting on the sink roll surface during 55%Al-Zn alloy coated strip production, and the life time of the sink roll is shorten by build up dross compounds and pitting. The present study examined the application of thermally sprayed ceramic coatings method on sink roll body for improving erosion resistance at molten 55% Al-Zn pool. In this experiment, the stainless steels such as STS 316L and STS 430F were used as the substrate materials. The CoNiCr and WE-Co powder were selected as bond coating materials. Moreover $Al_2O_3-ZrO_2-SiO_2 and ZrO_2-SiO_2$ powders selected as the top coating materials. Appearances of the specimens before and after dipping to molten 55%Al-Zn pool were compared and analyzed. As a result of this study, STS430F of substrate, WC-Co of bond spray coatings, $ZrO_2-SiO_2$ power of top spray coatings is the best quality in erosion resistance test at molten 55%Al-Zn pool

  • PDF