• Title/Summary/Keyword: ${\zeta}$-potential

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Novel route of enhancing the metal loading in highly active Pt/C electro-catalyst by polyol process (Polyol process를 통한 고비율 백금 담지 촉매 합성)

  • Oh, Hyung-Suk;Kim, Han-Sung
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.05a
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    • pp.560-563
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    • 2008
  • A modified polyol process is developed to enhance Pt loading during the preparation of Pt/C catalysts. With the help of the zeta potential, the effect of pH on the electrostatic forces between the support and the Pt colloid is investigated. It is shown experimentally that the surface charge on the carbon support becomes more electropositive when the solution pH is changed from alkaline to acidic. However, this change does not affect the electronegative surface charge of Pt colloids already attained and stabilized by glycolate anions. This new behavior caused by the change in the solution pH accounts for the enhanced yield of the process and does not affect the Pt particle size. All our experimental results reveal that this simple modification is a cost effective method for the synthesis of highly Pt loaded Pt/C catalysts for fuel cells.

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Rheological Properties of Cement Paste Added Inorganic Fine Powders and Superplasticizer (무기미분체와 고유동화제가 첨가된 시멘트 페이스트의 유변학적 특성)

  • 김재호;김도수;노재성
    • Proceedings of the Korea Concrete Institute Conference
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    • 1998.10c
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    • pp.191-196
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    • 1998
  • Under concentrational paste and dilute suspension systems, we have been tested the effects in the dosage of two superplasticizers [naphtalenic(NSF) and polycarboxylic(NT-2)] which has been varied from 0 to 2.0 wt%, in both one case of cement Ⅱ-anhydrite and fly ash itself and the other case that cement has been substituted 10wt% to Ⅱ-anhydrite and fly ash. The result of tested zeta potential tells that zeta potential values increase in addition to increasing of the NSF dosage. And it's effect was high in case of fly ash. We has confirmed the 10wt% substitution of Ⅱ -anhydrite and fly ash would be more effective than the cement itself in initial fluidity and stable fluidity. And in case of NT-2 and NSF, addition of 1.0wt% NT-2 improved the fluidity of paste cement more than that for NSF.

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Study on the Adsorption Behavior of FeS in Anaerobic Conditions (혐기성 조건에서 FeS의 흡착 거동 연구)

  • 김정배
    • Journal of Environmental Science International
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    • v.6 no.5
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    • pp.505-512
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    • 1997
  • The Interfacial characteristics between various heavy metals and hydrous FeS were investigated. Heavy metals which have lower sulfide solubilities than FeS undergoes the lecttice exchange reaction when these metal tons contact FeS In the aqueous phase. For heavy metals which have higher suede solubilities than FeS, these metal ions adsorb on the surface of FeS. Such characteristic reactions were interpreted by the soled solution formation theory. The presence of ligand such as EDTA reduced largely metal removal efficiency due to formation of metal-ligand complex In the solution. In an attempt to elucidate the Interfacial characteristics, zeta potential of the hydrous FeS In the absence and In the presence of various metal loons were measured and analyzed.

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Effect of Electrolytic Concentration on Frictional Behavior of Single Crystal Silicon (전해질 용액의 농도가 단결정 Si의 마찰거동에 미치는 영향)

  • 임대순
    • Tribology and Lubricants
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    • v.7 no.2
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    • pp.46-50
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    • 1991
  • The Frictional behavior in single crystal (111) p-type silicon as influenced by electolytic solutions have been studied. Linear scratching by diamond indentor was carried out to show the variation of friction between silicon and diamond indentor immersed in electrolytic solutions. The results indicate that concentration of the solutions influence the fricational coefficient. In addition there is a correlation between measured zeta-potential and frictional coefficients. The zeta-potential in various concentrations was measured to estimate the variation of the Peierls energy. The proposed model predicts a minimum frictional coefficient near a concentration of $10^{-3}$ M/l NaOH in deionized water and explains the chemomechanical effect observed in this study.

Morphological features of thermophilic activated sludge treating food industry wastewater in MBR

  • Ince, Mahir;Topaloglu, Alikemal;Ince, Elif
    • Membrane and Water Treatment
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    • v.9 no.1
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    • pp.33-42
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    • 2018
  • Microscopic examination of the activated sludge and morphological characterization of the flocs provides detailed information about the treatment process. The aim of this study is to investigate the morphological parameters of flocs obtained from a thermophilic jet loop membrane bioreactor (JLMBR) in different sludge retention times (SRTs), considering EPS and SMP concentration, hydrophobicity, zeta potential. The results showed that irregularity decreased with the increasing SRT. The compactness value was calculated to be less than 1 for all SRTs. However, the sludge had a more compact structure when the SRT increased. Zeta potential increased whereas hydrophobicity and floc size reduced, with increasing SRT. Furthermore, 2-D porosity calculated using the hole ratio was higher at greater SRTs. Hence, there was a significant correlation between the results obtained using the imaging technique and operation conditions of thermophilic JLMBR.

Effect of sulfuric acid hydrolysis condition on yield, particle size and surface charge of cellulose nanocrystals (황산 가수분해 조건이 셀룰로오스 나노크리스탈의 수율, 입도 및 전기화학적 특성에 미치는 영향)

  • Ryu, Jae-Ho;Youn, Hye-Jung
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.43 no.4
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    • pp.67-75
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    • 2011
  • Sulfuric acid hydrolysis is a typical approach for producing cellulose nanocrystals. The method has been widely used, but it has a disadvantage of low yield of cellulose nanocrystals compared to mechanical method. To expand the application of cellulose nanocrystals in practical, we should be able to produce them with higher yield and the controlled properties. In this study, therefore, we intended to investigate the effect of sulfuric acid hydrolysis condition on the characteristics of the prepared cellulose nanocrystals. The concentration of sulfuric acid, temperature and hydrolysis time were varied, and the yield as well as diverse properties including the morphology, size and zeta potential were examined. We could obtain cellulose nanocrystals up to 70% of yield and found that the properties were dependent on the reaction condition. It would be helpful to select an appropriate condition for producing cellulose nanocrystals.

Preparation of Smart Probiotic Solid Lipid Nanoparticles (SLN) for Target Controlled Nanofood

  • Kim, Dong-Myung
    • Journal of Dairy Science and Biotechnology
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    • v.25 no.2
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    • pp.5-10
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    • 2007
  • Ultrasonication was employed to prepare solid lipid nanoparticles (SLN) for smart probiotic nanoparticles as a nanofood. The model probiotic material, lactocin from Lactobacillus plantarum (CBT-LP2), was incorporated into SLN. The CBT-LP2 loaded SLN (CBT-LP2-SLN) were spherical in the photograph of scanning electron microscope (SEM). The particle size measured by laser diffraction (LD) was found to be $97.3{\pm}8.2nm$. Zeta potential analyzer suggested the zeta potential of LP-SLN was $-29.36{\pm}3.68$ mV in distilled water. The entrapment efficiency (EE%) was determined with the sephadex gel chromatogram and high-performance liquid chromatogram (HPLC), and up to 90.59% of nanofood was incorporated. Stability evaluation showed relatively long-term stability with only slight particle growth (P>0.05) after storage at room temperature for 4 weeks. Therefore, ultrasonication is demonstrated to be a simple, available and effective method to prepare high quality SLN loaded probiotic material.

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Characterizations of Membrane for Water Treatment: Surface Charge Analysis by Electrophoresis and Acidity Measurements

  • Yongki Shim;Lee, Sangyoup;Moon, Seung-Hyeon;Jaeweon Cho
    • Korean Membrane Journal
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    • v.2 no.1
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    • pp.56-59
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    • 2000
  • The surface charge properties of a polymeric NF and a ceramic UF membranes were characterized in terms of zeta potential and acidity. Both the negative zeta potential and acidity values increased as pH increases due to ionizable acidic functional groups. Increased ionic strength reduced the acidity of the negatively-charged membrane surface as anticipated. Through these results, it can be envisioned are used to reject solutes with ionizable functional groups. Fouling of the negatively-charged membrane with natural organic matter (NOM) having a negative charge density was also investigated with respect to the surface charge. The surface charge of the NF membrane increased negatively when greater NOM adsorption onto the membrane surface occured.

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Synthesis and Characterization of Glold Nanofluid Prepared by the Solution Plasma Processing (용액 플라즈마 공정을 이용하여 제조된 금 나노유체의 특성평가)

  • Heo, Yong-Kang;Lee, Sang-Yul
    • Journal of Powder Materials
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    • v.17 no.4
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    • pp.342-346
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    • 2010
  • In the present work, water-based gold nanofluids were synthesized by the solution plasma processing (SPP). The size distribution and the shape of gold nanoparticles in the nanofluids were investigated using high resolution transmission electron microscopy (HR-TEM). The dispersion stability of gold nanofluids was characterized using zeta potential, as well. The thermal properties of gold nanofluids were measured by utilizing lambda measurement device. Nanofluids containing nanoparticles with $64.0{\pm}42.1\;nm{\sim}18.10{\pm}5.0\;nm$ in diameter were successfully synthesized. As diameter of nanoparticles decreased, dispersion stability of nanofluids increased and the enhanced ratio of thermal conductivity increased. The nanofluid with nanoparticles of $18.10\;{\pm}\;5.0\;nm$ in diameter showed approximately 3% improvement in thermal conductivity measurement and this could be due to the enhanced Brownian movement.

Factors related to Performance of Reverse Osmosis Membrane in Seawater Desalination Process (해수담수화 공정에서 역삼투막의 거동에 영향을 주는 요인)

  • Park, Jun-Young;Hong, Sung-Ho;Kim, Ji-Hoon;Jeong, Woo-Won;Nam, Jong-Woo;Kim, Young-Hoon;Lee, Chang-Ha;Kim, Hyung-Soo
    • Journal of Korean Society of Water and Wastewater
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    • v.25 no.2
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    • pp.171-176
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    • 2011
  • Organic matters that comprise a tiny part of seawater generally occur over 50% of membrane fouling in Reverse Osmosis Process. This study evaluates Foundation efficiency of reverse osmosis membranes under brackish and seawater conditions and resistance of organic fouling. Moreover, analyzing the membrane surface through roughness, contact angle and zeta potential results in roughness and contact angle are proportional to flux decline rate (FDR), yet FDR has high value when zeta potential is low level. Furthermore, with various membrane fouling of different raw water conditions, the flux tends to improve when pH value is high and raw water which is complex with organic and cation pollutes membrane faster than organic separated raw water condition.