• Applied Chemistry for Engineering
• /
• v.21 no.3
• /
• pp.337-342
• /
• 2010

The interaction of monochlorophenol isomers with the micellar system of TTAB (tetradecyltrimethylammonium bromide) was studied by the UV/Vis spectrophotometric method. The solubilization constants ($K_s$) of monochlorophenol isomers into this micellar system have been measured with the change of temperature. Various thermodynamic parameters (${\Delta}G^{\circ}_s$, ${\Delta}H^{\circ}_s$, and ${\Delta}S^{\circ}_s$) have been calculated and analyzed from the dependence of $K_s$ values on the temperature. The results show that the values of ${\Delta}G^{\circ}_s$ and ${\Delta}H^{\circ}_s$ are all negative but the values of ${\Delta}S^{\circ}_s$ are all positive for the solubilizations of all isomers within the measured temperature range. The effects of additives (n-butanol and NaCl) on the solubilization of monochlorophenol isomers by the same surfactant system have been also measured. There was a great change on the values of $K_s$ and CMC simultaneously with these additives. From these changes we can postulate the solubilization sites of each isomer in the micellar system of TTAB.

• Korean Journal of Optics and Photonics
• /
• v.28 no.1
• /
• pp.33-38
• /
• 2017

The universality of the quasi-linear relation between the order parameter S and the normalized birefringence ${\Delta}n_{rel}$, $S=(1+a){\Delta}n_{rel}-a{\Delta}n^2_{rel}$ is confirmed. It is verified that the refractive index of liquid crystals distributed with regular polyhedral symmetry is isotropic and it is given as $\frac{1}{n^2_{av}}=\frac{1}{3}\(\frac{1}{n^2_e}+\frac{2}{n^2_o}\){\cdot}S$ and ${\Delta}n_{rel}$ of angular weighted liquid crystals that are initially distributed with regular polyhedral symmetry, are numerically calculated. Also ${\Delta}n_{rel}$ and S of liquid crystals that are conically distributed, keeping the rotational symmetry about z-axis are calculated as the apex angle of the cone is varied. Based on these calculated results, it is confirmed that the quasi-linear relation between S and ${\Delta}n_{rel}$ is universal, independent of the details of the distribution function.

• The Korean Journal of Pain
• /
• v.22 no.2
• /
• pp.146-150
• /
• 2009

Background: A skin temperature difference is one of the variables used in the diagnosis of complex regional pain syndrome. However, there have been no reports as to whether the real (${\Delta}T$) or absolute value ($|{\Delta}T|$) of skin temperature differences should be used in the diagnosis of complex regional pain syndrome. This study was conducted to compare the diagnostic validity of ${\Delta}T$ with $|{\Delta}T|$ for complex regional pain syndrome using receiver operating characteristic curves (ROC). Methods: Infrared thermographic images were obtained from the 144 patients who were suspected to have CRPS in a unilateral limb. After ${\Delta}T$ and $|{\Delta}T|$ calculation from the thermographic image, ROCs of ${\Delta}T$ and $|{\Delta}T|$ were developed, and the areas under the curve (AUC) for the ROC curves were compared. Results: AUCs of ${\Delta}T$ and $|{\Delta}T|$ were 0.520 and 0.746 respectively, this difference was statistically significant (P < 0.001). Conclusions: Absolute skin temperature difference shows greater validity in the diagnosis of CRPS than ${\Delta}T$. Therefore, $|{\Delta}T|$ is more useful when comparing the skin temperature of CRPS patients.

• International Union of Geodesy and Geophysics Korean Journal of Geophysical Research
• /
• v.21 no.1
• /
• pp.17-30
• /
• 1993

The basic processes responsible for the generation of oceanic fronts were reviewed. In particular the process of a shelf sea front produced by tidal stirring was identified from the one dimensional model of the water column in the coastal area, which incorporates the microscale process for the formation of a tidal front. Also a new criterion to predict its location was suggested. The time evolutions of the distributions of density and turbulent kinetic energy calculated from the model show that the criterion for the formation of a thermocline can be predicted as $R{\delta}^4$~ constant for large $\delta$ ($\delta$＞0.5), but the dependence on $\delta$ decreases as $\delta$ goes to O, where $R=H^4Q/{K_b}^3$,{\;}{\delta}=1-Do/H$, Q is the buoyancy flux at the surface, $K_b$ is the eddy diffusivity maintained at the bottom and Do is the depth of a thermocline in the absence of bottom mixing. The depth of a thermocline was found to decrease as the bottom mixing increases for a given value of Do. The results were interpreted in comparison with the previous studies.

• Bulletin of the Korean Chemical Society
• /
• v.26 no.8
• /
• pp.1246-1250
• /
• 2005

We have evaluated the hydroxyl group-solvent specific interactions by using a Lichrosorb RP18 stationary phase and by measuring the retention data of carefully selected solutes in 50/50, 60/40, 70/30, 80/20, and 90/10(v/v%) methanol/water eluents at 25, 30, 35, 40, 45, and 50 ${^{\circ}C}$. The selected solutes are 3 positional isomers of phenylpropanol, that is, 1-phenyl-1-propanol, 1-phenyl-2-propanol, and 3-phenyl-1-propanol. There exist clear discrepancies in ${\Delta}H^o$ (solute transfer enthalpy from the mobile to the stationary phase) and $T{\Delta}S^o$ (solute transfer entropy) among positional isomers. The difference in ${\Delta}H^o$ and $T{\Delta}S^o$ between secondary alcohols (1-phenyl-1-propanol and 1-phenyl-2-propanol)is negligible compared to the difference between the primary alcohol (1-phenyl-3-propanol) and secondary alcohols. The $T{\Delta}S^o$ values of 3-phenyl-1-propanol are close to those of butylbenzene while the $T{\Delta}S^o$ values of secondary alcohols are close to those of propylbenzene. The difference in ${\Delta}{\Delta}H^o$ (specific solute-mobile phase interaction enthalpy) between the primary alcohol and the secondary alcohol decreases with increase of methanol content in the mobile phase. A unique observation is an extremum for 1-phenyl-3-propanol in the plot of $T{\Delta}{\Delta}S^o$ vs. methanol volume %. The positive sign of $T{\Delta}{\Delta}S^o$ of 3-phenyl-1-propanol implies that the entropy of 3-phenyl-1-propanol is greater than that of the hypothetical alkylbenzene (the same size and shape as phenylpropanol) in the mobile phase.

• Journal of the Korean Chemical Society
• /
• v.57 no.6
• /
• pp.665-671
• /
• 2013

The solubilization of p-bromophenol by the micellar system of TTAB(tetradecyltrimethylammonium bromide) and the micellization of TTAB were studied by the UV-vis spectrophotometric method simultaneously. And the effects of temperature on these properties have been measured for the thermodynamic study. The results show that the ${\Delta}G_s{^o}$ and ${\Delta}H_s{^o}$ values are negative and the ${\Delta}S_s{^o}$ values are positive for the solubilization of p-bromophenol within the measured range. On the other hand, the ${\Delta}G_m{^o}$ values are negative and the ${\Delta}H_m{^o}$ and ${\Delta}S_m{^o}$ values are positive for the micellization of TTAB. The effects of additives such as n-butanol and NaCl have been studied also for both properties and the relationship between these two properties has been also studied. From the results, we can postulate the solubilization site of p-bromophenol in the micelle.

• 한국해양학회지
• /
• v.29 no.2
• /
• pp.183-187
• /
• 1994

The oxygen and carbon isotopic compositions of the foraminiferal species, Elphidirm dtigoense and Ammonia beccarii tepida, of the tidal flat in the Gomso Bay of the western coast of Korea have been measured. This work was intended to study the relationship between oxygen and carbon isotopic compositions of the foraminifera and present oceanographic environments, and also the difference between two foraminiferal species. The values of $\delta$/SUP 18/O and $\delta$/SUP 13/C of E. dtigoense varied from - 3.20% to + 0.58% and from - 5.26% to - 0.93%, respectively. The values of $\delta$/SUP 18/O and $\delta$/SUP 13/C of A. beccarii tepida varied from - 1.11% to + 0.61% and from - 2.04% to - 1.40%, respectively. Mo significant variations in these values occur from the samples among the upper, middle and lower tidal zones except for the one from the upper tidal zone that has extremely low value. The difference between the two foraminiferal species was 0.20% and 1.63% in the average values of $\delta$/SUP 18/O and $\delta$/SUP 13/C, respectively. The relationship between $\delta$/SUP 18/O and $\delta$/SUP 13/C values was positive in interspecies of two species.

• The korean journal of orthodontics
• /
• v.33 no.6 s.101
• /
• pp.475-483
• /
• 2003

The purpose of this study is to evaluate hard and soft tissue changes following the subapical osteotomy in bimaxillary dentoalveolar protrusion patients requiring maximal retraction adult female patients was selected. Surgical procedures were performed by the same surgeon, anterior subapical osteotomy techniques were employed on the maxilla and cephalometric radiograms were traced and superimposed using the best-fit method and two reference The results were as follows 1. The bodily movement of the maxillary anterior segment was achieved in a posterior moved posteriorly with a slight correction of the lower incisors. 2. The horizontal soft tissue measurements changed significantly after treatment, but Nt and Sn vertical soft tissue measurements indicated that Ls moved inferiorly and Li superiorly. 3. The correlation between hard and soft tissue changes indicated that ${\Delta}HId/{\Delta}HLi,\;{\Delta}HId/{\Delta}LL-Eline,\;{\Delta}Hpt.B/{\Delta}HILS,\;and\;{\Delta}UI-FH/{\Delta}NL$ were significant. 4. More lower lip relative to upper lip retraction was demonstrated in relation to Rickett's E-line. The ratio between upper lip displacement was $50\%$, and between the lower incisor and lower lip displacement was $60\%$. We conclude from the results that the anterior subapical osteotomy is an efficient treatment severe dentoalveolar protrusion and desire rapid results.

• Journal of Soil and Groundwater Environment
• /
• v.10 no.6
• /
• pp.45-55
• /
• 2005

The geothermal research has been carried out on the Heunghae, Pohang geothermal area know as having geo-heat-flow area in the Korean peninsula. This study results so far indicate that geothermal water in the area is in peripheral waters of hydrothermal area and is not in equilibrium with the reservoir rock. The average oxygen and hydrogen stable isotope values are as follows: deep groundwater $(average:\;{\delta}^{18}O=-10.1\%_{\circ},\;{\delta}D=-65.8\%_{\circ})$, intermediate groundwater (average: $(average:\;{\delta}^{18}O=-8.9\%_{\circ},\;{\delta}D=-59.6\%_{\circ})$, shallow groundwater $(average:\;{\delta}^{18}O=-8.0\%_{\circ},\;{\delta}D=-53.6\%_{\circ})$, surface water $(average:\;{\delta}^{18}O=-7.9\%_{\circ},\;{\delta}D=-53.3\%_{\circ})$ respectively. Deep groundwaters was originated from a local meteoric water recharged from distant, topographically high mountain region and not affected by the sea water. High temperature zone inferred from water geothermometers is around D-1, D-5, D-6, 1-04 well zones. The estimated enthalpy from Silica-enthalpy mixing model is near 410 kJ/kg, which corresponds to the temperature of $98^{\circ}C$, and in consistent with the result of Na-K and K-Mg geothermometer.

• Maxillofacial Plastic and Reconstructive Surgery
• /
• v.34 no.5
• /
• pp.311-319
• /
• 2012

Purpose: The aim of this study is to evaluate the vertical changes of the lip and perioral soft tissue, following orthognathic surgery in skeletal class III patients by a cephalometric analysis of a cone beam computed tomography (CBCT). Methods: A total of 20 skeletal class III patients, who had bimaxillary surgery with Le Fort 1 osteotomy and bilateral sagittal split ramus osteotomy, were included in this study. The surgical plan for maxilla was posterosuperior impaction with the anterior nasal spine, as the rotation center. Further, the surgical plan for mandible was also posterosuperior movement. The soft tissue changes between lateral cephalogram and CBCT were compared. And the correlations between independent variables and dependent variables were evaluated. Results: There were no significant differences of the soft tissues changes between lateral cephalogram and CBCT. Upper lip philtrum length (SnLs), nasolabial angle increased and upper lip vermilion length (LsStms), lower lip length (StmiB'), lower lip vermilion length (StmiLi), lower lip philtrum length (LiB') and soft tissue lower facial height (SnMe') decreased after surgery. Change of SnLs (${\Delta}$SnLs) was influenced by vertical change of menton (${\Delta}$MeV), and change of LsStms (${\Delta}$LsStms) was influenced by upper lip thickness (ULT). Change of StmiLi' (${\Delta}$StmiLi') were influenced by preoperative overjet. Change of StmiB' (${\Delta}$StmiB') were influenced by preoperative overjet, vertical change of lower incisor (${\Delta}$L1V) and horizontal change of posterior nasal spine (${\Delta}$PNSH). Change of LiB' (${\Delta}$LiB') was influenced by ${\Delta}$L1V and ${\Delta}$PNSH. Change of SnMe' (${\Delta}$SnMe') was influenced by ${\Delta}$MeV, horizontal change of upper incisor (${\Delta}$U1H) and horizontal change of lower incisor (${\Delta}$L1H). ${\Delta}$Nasolabial angle was influenced by change of ULT (${\Delta}$ULT). Conclusion: Both soft tissues and hard tissues can be evaluated by CBCT. Posterosuperior rotation of maxillomandibular complex resulted in increase of upper lip philtrum length and nasolabial angle, while the upper lip vermilion length, lower lip philtrum length, lower lip vermilion length, and soft tissue lower facial height showed a decrease.