• Title/Summary/Keyword: ${\chi}$-phase

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Charge Transformation of CU-ions in CuxFe3-xO4 (χ=0.1, 0.2)

  • Lee, Choong Sub;Lee, Chan Young;Kwon, Dong Wook
    • Journal of Magnetics
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    • v.7 no.2
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    • pp.25-28
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    • 2002
  • Slowly cooled $Cu_xFe_{3-x}O_4$ ($\chi$=0.1, 0.2) have been investigated over a temperature range from 82 to 700 K using the M$\ddot{o}$ssbauer technique. X-ray diffraction shows that these have a single-phase cubic spinel structure of lattice parameters $\alpha$=8.396 and 8.398${\AA}$, respectively. Since Cu ions prefer B (octahedral) sites to A (tetrahedral) sites, the ionic distribution is $(Fe)_A[Fe_{2-x}Cu_x]_BO_4$. M$\ddot{o}$ssbauer spectra consisted of two sets of 6-line pattern from. A site in ferric state and B site in ferrous-ferric state. Intensity ratio of B to A subspectra is 1.0 at 82 K and increases to 2.0 at 700 K with increasing temperature. After annealing the samples under vacuum at $450^circ{C}$ for a half hour, x-ray diffraction patterns have the peaks of magnetite- and hematite-phase. Lattice constants of magnetite-phase are 8.395 and 8.392 ${\AA}$ smaller than 8.396 and 8.398 ${\AA}$ before annealing, respectively. M$\ddot{o}$ssbauer spectra reveal the conventional magnetite pattern with the additional hematite pattern. Intensity ratios of B to A subspectra fur magnetite-phase become 1.9-2.0 over all temperature ranges and Cu ions are distributed over A and B sites randomly. Ratios of hematite to total intensity in M$\ddot{o}$ssbauer spectra for $\chi$= 0.1 and $\chi$= 0.2 are 10 and 21%, respectively. These hematite ratios may be due to annealing under vacuum at $450^circ{C}$, which transforms $Cu^{2+}$ ionic states into $Cu^{1+}$. Verwey temperatures far $\chi$= 0.1 and $\chi$= 0.2 are $123\pm2$ K and $128\pm2$ K.

Prediction of Gas Phase Sorption Isotherms on The Basis of QSAR Method (QSAR 방법을 이용한 가스 상태의 등온흡착선 예측)

  • Kim, Jong O
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.11 no.3
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    • pp.11-18
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    • 1991
  • Volatile organic compounds(VOC) present in or generated by many sources, can be toxic, mutagenic or even carcinogenic, so that control of such emissions is significant. The 6 chlorinated organic chemicals as VOC were examined in this study. Prediction of the behavior of VOC on activated carbon beds is an important part of control system design. The objective of this study was to predict gas phase sorption isotherms from physical properties and liquid phase isotherms obtained with the same adsorbent and adsorbate. One of the techniques that was investigated was quantitative structure-activity relationships(QSAR) for the predicition procedures. It was possible to estimate sorption isotherms in the gas phase($a_g$) using either connectivity index, $^2{\chi}$, and the Henry's law coefficient ($H_a$) or the solubility and the equilibrium concentration in the gas phase. As a result of study, the predictive equation based on Freundlich model for $a_g$ was ${\log}\;a_g=0.238\;^2{\chi}+0.573\;{\log}\;H_a+4.330(r^2=0.94)$. Finally, this would provide a potentially useful tool to describe and predict sorption capacity without time-consuming tests.

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A Comparison Study between Uniform Testing Effort and Weibull Testing Effort during Software Development (소프트웨어 개발시 일정테스트노력과 웨이불 테스트 노력의 비교 연구)

  • 최규식;장원석;김종기
    • Journal of Information Technology Application
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    • v.3 no.3
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    • pp.91-106
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    • 2001
  • We propose a software-reliability growth model incoporating the amount of uniform and Weibull testing efforts during the software testing phase in this paper. The time-dependent behavior of testing effort is described by uniform and Weibull curves. Assuming that the error detection rate to the amount of testing effort spent during the testing phase is proportional to the current error content, the model is formulated by a nonhomogeneous Poisson process. Using this model the method the data analysis for software reliability measurement is developed. The optimum release time is determined by considering how the initial reliability R($\chi$ 0) would be. The conditions are ($R\chi$ 0)>$R_{o}$ , $P_{o}$ >R($\chi$ 0)> $R_{o}$ $^{d}$ and R($\chi$ 0)<$R_{o}$ $^{d}$ for uniform testing efforts. deal case is $P_{o}$ >($R\chi$ 0)> $R_{o}$ $^{d}$ Likewise, it is ($R\chi$ 0)$\geq$$R_{o}$ , $R_{o}$ >($R\chi$ 0)>R(eqation omitted) and ($R\chi$ 0)<R(eqation omitted)for Weibull testing efforts. Ideal case is $R_{o}$ > R($\chi$ 0)> R(eqation omitted).

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Exploring Critical Risk Factors of Office Building Projects

  • NGUYEN, Phong Thanh;PHAM, Cuong Phu;PHAN, Phuong Thanh;VU, Ngoc Bich;DUONG, My Tien Ha;NGUYEN, Quyen Le Hoang Thuy To
    • The Journal of Asian Finance, Economics and Business
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    • v.8 no.2
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    • pp.309-315
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    • 2021
  • Risks and uncertainty are unavoidable problems in management of projects. Therefore, project managers should not only prevent risks, but also have to respond and manage them. Risk management has become a critical interest subject in the construction industry for both practitioners and researchers. This paper presents critical risk factors of office building projects in the construction phase in Ho Chi Minh City, Vietnam. Data was collected through a questionnaire survey based on the likelihood and consequence level of risk factors. These factors fell into five groups: (i) financial risk factors; (ii) management risk factors; (iii) schedule risk factors; (iv) construction risk factors; and (v) environment risk factors. The research results showed that critical factors affecting office building projects are natural (i.e., prolonged rain, storms, climate effects) and human-made issues (i.e., soil instability, safety behaviors, owner's design change) and the schedule-related risk factors contributed to the most significant risks for office buildings projects in the construction phase in Ho Chi Minh City. They give construction management and project management practitioners a new perspective on risks and risk management of office buildings projects in Ho Chi Minh City and are proactive in the awareness, response, and management of risk factors comprehensively.

High Temperature Precipitation Behavior of High-Nitrogen Duplex Stainless Steel (고질소 2상 스테인리스강의 고온 석출거동)

  • Bae, Jong-In;Kim, Sung-Tae;Lee, Tae-Ho;Ha, Heon-Young;Kim, Sung-Joon;Park, Yong-Ho
    • Korean Journal of Metals and Materials
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    • v.49 no.2
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    • pp.93-103
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    • 2011
  • Precipitation behavior of high-nitrogen duplex Fe-24Cr-7Mn-4Ni-4Mo-0.43N stainless steel aged at $850^{\circ}C$ was investigated using scanning transmission electron microscopy. Based on the analyses of selected area diffraction patterns, four kinds of precipitates (intermetallic sigma (${\sigma}$) and chi (${\chi}$), $Cr_2N$ and secondary austenite) were identified. At the ferrite/austenite phase boundary, the ${\sigma}$ phase and secondary austenite were formed via ${\alpha}{\rightarrow}{\gamma}+{\sigma}$ eutectoid reaction. The precipitation of $Cr_2N$ occurred at the austenite grain boundary as well as the interior of the ferrite. The intermetallic ${\chi}$ phase also formed within the ferrite and showed a cube-cube orientation relationship with the ferrite. Further aging produced a lamellar structure composed of $Cr_2N$ and austenite along the ferrite/austenite boundary and enhanced the precipitation of the ${\chi}$ phase. The crystallographic features of the precipitates were also examined in terms of the orientation relationship with the austenite or ferrite matrix.

Power extraction efficiency and lasing wavelength distribution of complex-coupled DFB lasers for various facet reflectivity combinations and coupling coefficient ratios (양 단면 반사율 조합과 결합 계수 비에 따른 Complex-Coupled DFB 레이저 다이오드의 파워 추출 효율과 발진 파장 분포)

  • 김상택;김부균
    • Korean Journal of Optics and Photonics
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    • v.15 no.2
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    • pp.149-157
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    • 2004
  • We have calculated the power extraction efficiency and the lasing wavelength distribution of complex-coupled(CC) DFB lasers above threshold for various|$\chi$L| and facet reflectivity combinations, and we have compared the results with those at threshold. Also, we have investigated the effect of coupling coefficient ratio(CR) and the reflectivity of AR facet on the power extraction efficiency and the lasing wavelength distribution. At threshold, the single mode yield as a function of power extraction efficiency of in-phase(IP) CC DFB lasers is the same as that of anti-phase(AP) CC DFB lasers. Above threshold, however, the single mode yield as a function of power extraction efficiency of IP CC DFB lasers is much larger than that of AP CC DFB lasers. For IP CC DFB lasers, AR-HR combination has high single mode yield and large power extraction efficiency compared to other facet combinations. IP CC DFB laser with AR-HR combination for |$\chi$L|of 0.8 has the highest single mode yield and largest power extraction efficiency above threshold among the cases considered. For AR-HR combination, as CR increases and the reflectivity of AR facet decreases, both single mode yield and power extraction efficiency increase due to the reduction of the spatial hole burning effect. For AR-HR combination, the lasing wavelength of CC DFB laser has distributed over the stopband of DFB. As CR increases, the lasing wavelength concentrates on the long wavelength side for IP CC DFB laser, while on the short wavelength side for AP CC DFB laser. As |$\chi$L| increases, the width of the wavelength distribution decreases and the lasing wavelength moves to the long wavelength side.

Phase identification and degree of orientation measurements far fine-grained rock forming minerals using micro-area X-ray diffractometer -$Al_{2}SiO_{5}$ Polymorphs- (미소부 X-선 회절분석기를 이용한 미립조암광물의 상동정 및 배향도 측정 -$Al_{2}SiO_{5}$ 3상다형-)

  • 박찬수;김형식
    • The Journal of the Petrological Society of Korea
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    • v.9 no.4
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    • pp.205-210
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    • 2000
  • Measurements of phase identification and degree of orientation for fine-grained (about 0.3 mm in diameter) minerals in rock samples performed by micro-area X-ray diffractometer.$Al_{2}SiO_{5}$ polymorphs (andalusite, kyanite and sillimanite) were chosen for the measurements and target minerals were existed on thin sections. Micro-area X-ray diffractometer is composed of 3(${\omega}\;{\chi}\;{\phi}$)-circle oscillating goniometer and position sensitive proportional counter (PSPC). $CuK_{\alpha}$ radiation was used as X-ray source and a pin hole ($50\;\mu\textrm{m}$$ in diameter) collimator was selected to focus radiation X-ray onto the target minerals. Phase identification and diffracted X-ray peak indexing were carried out by 3(${\omega}\;{\chi}\;{\phi}$)-circle oscillation measurement. Then, 2(${\omega}\;{\phi}$)-circle oscillation measurement was made for the purpose of searching the prevailing lattice plane of the minerals on thin section surface. Finally, for a selected peak by 2-circle oscillation measurement, X-ray pole figure measurement was executed for the purpose of check the degree of orientation of the single lattice direction and examine its pole distribution. As a result of 3-circle oscillation measurement, it was possible that phase identification among $Al_{2}SiO_{5}$ polymorphs. And from the results of 2-circle oscillation measurement and X-ray pole figure measurement, we recognized that poles of andalusite (122), kyanite (200) and sillimanite (310) lattice plances were well developed with direction normal to each mineral surface plane respectively. Therfore, the measurements used with micro-area X-ray diffractometer in this study will be a useful tool of phase identification and degree of orientation measurement for fine-grained rock forming minerals.

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The Efficacy of Community-Based Rehabilitation Exercise to Improve Physical Function in Old Women with Knee Arthritis (지역사회중심재활운동이 여성 슬관절염 환자의 신체기능에 미치는 효과)

  • Kim, Su-Min;Song, Ju-Min
    • The Journal of Korean Physical Therapy
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    • v.22 no.1
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    • pp.9-17
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    • 2010
  • Purpose: The purpose of this study was to compare the effects of Tai-Chi exercise (TCE) and resistance exercise (RE) when used as part of a community-based exercise program on improvement of physical function in elderly women with knee arthritis. Methods: Forty-seven women with knee arthritis participated in this study. They were assigned to one of two groups: the TCE group (n=22) or the RE group (n=25). Tai-Chi exercise and resistance exercise sessions were held for 1 hour per session, twice per week, for 8 consecutive weeks. At pre-treatment and post-treatment, subjects were tested using the following measurements: one-legged stand test (sec), a functional reach test (cm), a test of the strength of the knee extensor and flexor muscles, determination of the pathway of center of foot pressure and vertical ground reaction force for stance phase at pre and post treatment time points. An independent t-test and a ${\chi}^2$ were used to determine the significance of differences between group means using SPSS 12.0. Results: After 8 weeks of participation in the exercise programs, there were significant improvements for both groups in joint pain, difficulty of performing activity, muscle strength of knee extensor and flexor. Also, vertical ground reaction force increased at the loading response phase for both groups. The RE group was significantly different from TC group on the eyes-closed one-legged stand test (sec). Conclusion: Tai-Chi exercise and resistance exercise programs improve physical functioning and reduce pain and locomotion difficulties.

New Charge-Recycling Structure and Driving Scheme for TFT-LCD Source-Driver IC Application

  • Lu, Chih-Wen;Hsu, Kuo-Jen;Liao, Hsueh-Chih;Chen, Chun-Hung
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07a
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    • pp.653-656
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    • 2005
  • New charge-recycling structure and driving scheme for TFT-LCD source-driver IC application are proposed. The number of additional switches for the charge recycling is greatly reduced. An experimental prototype 6-bit source driver with five-level seven-phase charge recycling implemented in a $0.35-{\mu}m$ CMOS technology demonstrates that the quiescent current is only 3.1 mA, dynamic power saving is 75 %, and the settling time, which includes the charge-recycling and data driving, is within 25 $25{\mu}s$.

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