• Title/Summary/Keyword: ${\cdot}OH$ 첨가

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Factors Affecting In Vitro Minimal Growth Conservation of Sedum sarmentosum (돌나물의 기내 활성보존에 영향하는 요인)

  • Lee, Seung Yeob;Kwon, Tae Oh
    • Journal of Bio-Environment Control
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    • v.22 no.3
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    • pp.241-247
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    • 2013
  • For in vitro minimal-growth conservation of S. sarmentosum, the in vitro shoots with 10 mm length were cultured on Murashige and Skoog's media (MS) containing different levels of agar (0.8, 1.2, 1.6, 2%), Gelrite (0.4, 0.6, 0.8, 1%), ABA (0, 5, 10, $20mg{\cdot}L^{-1}$), and sucrose (2, 3, 6, and 9%) without subculture at $4^{\circ}C$ and $25^{\circ}C$. All media were supplemented with $0.2mg{\cdot}L^{-1}$ BA, agar and Gelrite media, with 5% sucrose, sucrose media, with 1.2% agar, and ABA media, with 5% sucrose and 1.2% agar, respectively. In vitro minimal-growth conservation in room-temperature ($25^{\circ}C$) was effective in the media containing with $10mg{\cdot}L^{-1}$ ABA or 1.6% agar, and the healthy plantlets could be preserved for 10 months without subculture. After 12 months at $4^{\circ}C$, survival rate was 100% in all media. The in vitro minimal-growth conservation in low temperature ($4^{\circ}C$) was effective in the media containing with $10mg{\cdot}L^{-1}$ ABA or 6% sucrose, and the healthy plantlets could be preserved over 18 months without subculture. Especially, long-term conservation using minimal growth of S. sarmentosum was much more efficient in the medium containing high level sucrose at $4^{\circ}C$ compared to others.

Effect of Si on the Corrosion Properties of Mg-Li-Al Light Alloy (경량화 Mg-Li-Al합금의 내식성에 미치는 Si의 영향)

  • 김순호
    • Resources Recycling
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    • v.7 no.5
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    • pp.52-57
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    • 1998
  • Effect of Si in the electrochemical corrosion characteristics of Mg-Li-Al light alloy has been investigated by means of potentiodynamic polarization study. The elecrochemical behaviors were evaluated in 003% NaCl solution and the solution buffered with KH$_{2}PO_{5}{\cdot}$NaOH at room temperature. It was found that the addition of very small quantity of Si (0.48 wt%) in Mg-Li-Al light alloy increased corrosion rates and amount of corrosion products and decreated the pitting resistance of the alloy. From the results it was concluded that Si which is added to increase the strength of Mg-Li-Al alloy is harmful to corrosion properties of the alloy.

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The Strength Properties Activated Granulated Ground Blast Furnace Slag with Aluminum Potassium Sulfate and Sodium Hydroxide (칼륨명반과 수산화나트륨으로 활성화된 고로슬래그 미분말의 강도 특성)

  • Kim, Taw-Wan;Hahm, Hyung-Gil
    • Journal of the Korea Concrete Institute
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    • v.27 no.2
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    • pp.95-102
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    • 2015
  • In this paper, the effects of sodium hydroxide (NaOH) and aluminum potassium sulfate ($AlK(SO_4)_2{\cdot}12H_2O$) dosage on strength properties were investigated. For evaluating the property related to the dosage of alkali activator, sodium hydroxide (NaOH) of 4% (N1 series) and 8% (N2 series) was added to 1~5% (K1~K5) dosage of aluminum potassium sulfate ($AlK(SO_4)_2{\cdot}12H_2O$) and 1% (C1) and 2% (C2) dosage of calcium oxide (CaO). W/B ratio was 0.5 and binder/ fine aggregate ratio was 0.5, respectively. Test result clearly showed that the compressive strength development of alkali-activated slag cement (AASC) mortars were significantly dependent on the dosage of NaOH and $AlK(SO_4)_2{\cdot}12H_2O$. The result of XRD analysis indicated that the main hydration product of $NaOH+AlK (SO_4)_2{\cdot}12H_2O$ activated slag was ettringite and CSH. But at early ages, ettringite and sulfate coated the surface of unhydrated slag grains and inhibited the hydration reaction of slag in high dosage of $NaOH+AlK(SO_4)_2{\cdot}12H_2O$. The $SO_4{^{-2}}$ ions from $AlK(SO_4)_2{\cdot}12H_2O$ reacts with CaO in blast furnace slag or added CaO to form gypsum ($CaSO_4{\cdot}2H_2O$), which reacts with CaO and $Al_2O_3$ to from ettringite in $NaOH+AlK(SO_4)_2{\cdot}12H_2O$ activated slag cement system. Therefore, blast furnace slag can be activated by $NaOH+AlK(SO_4)_2{\cdot}12H_2O$.

Radical Scavenging Effects and Physicochemical Properties of Seolitae Chungkukjang Added with Green Tea (녹차첨가 서리태청국장의 이화학적 특성 및 유리기 소거능)

  • Park, Hyun-Young;Cho, Eun-Ju
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.37 no.4
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    • pp.401-404
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    • 2008
  • Seolitae Chungkukjang added with different ratios of green tea was prepared to increase the antioxidative activity of Chungkukjang. The physicochemical properties and the radical scavenging effect under in vitro were evaluated. The addition of green tea to Seolitae Chungkukjang (SC) revealed lower pH, green color and decrease in levels of NH3-N. Among the Chungkukjang group with Seolitae or green tea, SC with green tea 5.0% (SCG 5.0) showed the strongest scavenging activity against 1,1-diphenyl-2-picrylhydrazyl with $IC_{50}$ value of $82.1{\mu}g$/mL. In addition, SCG 5.0 exerted the most effective ${\cdot}OH$ scavenging activity. Moreover, SCG 5.0 showed the similar sensory preference to control soybean Chungkukjang. The present study suggests that SC exerts radical scavenging effect, and that the addition of green tea to SC leads to the increase in the antioxidative effect of Chunkukjang.

Effects of NaOH and Na2SiO3·9H2O Addition on Strength Development of Class F Fly Ash-Mortar (F급 플라이 애쉬-모르타르의 강도발현에 대한 NaOH과 Na2SiO3·9H2O 첨가의 영향)

  • Park, Sang-Sook;Kang, Hwa-Young;Han, Sang-Ho;Kang, Hee-Bog
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.9 no.4
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    • pp.261-269
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    • 2005
  • The object of this research is to produce alkali activated fly ash-cement using low calcium fly ash as substitute for portland cement. The experimental program included activation of fly ash by a strong base(NaOH) at different concentration, temperature, and liquid-to-fly ash ratios. To achieve for higher compressive strength of the hardened product, sodium meta silicate is added to the alkaline solution. From the factors considered on strength development, the ratio of liquid/fly ash, the activator concentration and temperature always result to be significative factors. The optimization studied show that the alkaline solution concentration of $NaOH(210g)+Na_2SiO_3{\cdot}9H_2O(30g)+H_2O=1L$ at $50^{\circ}C$ produces the best alkali activation effect for the low calcium fly ash. SEM and XRD patterns showed that the components of alkali-activated fly ash consist mainly of mullite, quartz and amorphous aluminosilicate.

Synthesis of Monodisperse ZnO Nanoparticles Using Semi-batch Reactor and Effects of HPC Affecting Particle Size and Particle Size Distribution (반회분식 반응을 이용한 단분산 ZnO 나노 입자의 제조 및 입자의 크기와 입도 분포에 영향을 미치는 HPC의 작용)

  • Rho, Seung Yun;Kim, Ki Do;Song, Gun Yong;Kim, Hee Taik
    • Applied Chemistry for Engineering
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    • v.17 no.3
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    • pp.274-279
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    • 2006
  • To synthesize ZnO colloidal solution by a sol-gel process, zinc acetate ($C_{4}H_{6}O_{4}Zn{\cdot}2H_{2}O{\cdot}0.2\;mol$) and lithium hydroxide ($LiOH{\cdot}H_{2}O{\cdot}0.14\;mol$) in the ethanol were added to the solution containing a dispersing agent, hydroxypropyl cellulose (HPC). The nanosize and physical shape of the synthesized ZnO particles were determined by HPC acting as the dispersing agent. Nanosized ZnO particles were also obtained by a precipitation method based on zinc-2-ethylhexagonate. The precipitates were characterized by DLS, XRD, FE-SEM, and UV-vis. As the results, the ZnO colloids tend to self-assemble into a well-ordered hexagonal close-packed structure. The ZnO nanoparticles have an average diameter of nearly 40 nm with a narrow size distribution.

Partial oxidation of methane over ceria-promoted catalysts derived from Ni-substituted hydrotalcite (세리아가 첨가된 니켈 치환 하이드로탈사이트로부터 유도된 촉매에 의한 메탄의 부분산화)

  • Lee, Seung-Hwan;Kim, Mi-So;Kwak, Jung-Hun;Lim, Tae-Hoon;Nam, Suk-Woo;Hong, Seong-Ahn;Yoon, Ki-June
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.05a
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    • pp.499-502
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    • 2008
  • 고정층반응기에서 니켈이 치환된 하이드로탈사이트($Ni_3Mg_3Al_2(CO_3)(OH)_{{16}{\cdot}n}H_2O$ ; n=3$\sim$5)를 합성하고 여기에 세리아를 첨가 후 소성하여 얻은 촉매를 사용하여($Ce_xNi_3$-HTlc ; x=0.3$\sim$1.2) 메탄의 부분산화 반응실험을 수행하였다. 세리아가 첨가되지 않은 촉매는 반응 초기 활성이 세리가가 소량 첨가된 ($Ce_{0.3}Ni_3$-HTlc) 촉매보다 우수하였으나 장시간 반응에서는 차차 활성이 저하되었으나, $Ce_{0.3}Ni_3$-HTlc의 활성은 30시간까지 일정하게 유지 되었다. 세리아 함량이 많아 질수록 촉매 활성은 점차 저하되었으며, $Ce_{1.2}Ni_3$-HTlc 는 촉매활성이 매우 낮았다.

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A Study on the Characteristics and Utilization of Ash from ASR Incinerator (ASR 소각재의 이화학적 물성 및 재활용(再活用)을 위한 기초연구(基礎硏究))

  • Lee, Hwa-Young
    • Resources Recycling
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    • v.16 no.2 s.76
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    • pp.32-39
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    • 2007
  • The measurement of physicochemical properties of ASR incineration ash has been carried dot and the preparation of light-weight material has also been performed using ASR ash for recycling point of view as building or construction materials. For this aim, chemical composition, particle size distribution, and heavy metal leachability were examined for 2 bottom ashes and 4 fly ashes obtained from the domestic ASR incinerator. In the present work, attempt has been made to prepare the lightweight material using boiler ash as a raw material, which is prepared by forming the mixture of boiler ash, lightweisht filler and inorganic binder and followed by calcination at elevated temperature. As a result, the content of Cu in bottom ash was as high as about 3wt% so that the recovery of Cu from ash was required. The major compound of SDR #5 and Bag filter #6 was found to be $CaCl_2{\cdot}Ca(OH)_2{\cdot}H_2O\;and\;CaCl_2{\cdot}4H_2O$, respectively. It is thought that heavy metal teachability of lightweight material prepared with boiler ash was significantly decreased due to the encapsulation or stabilization of heavy metal compounds.

Organic Wastewater Treatment Using Modified Fenton's Oxidation (변형 펜턴산화법을 이용한 유기폐수의 처리)

  • Kim, Ji Yeon;Yoon, Tai Il;Park, Se Jin
    • Clean Technology
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    • v.5 no.1
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    • pp.49-61
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    • 1999
  • Fenton's oxidation can improve the biodegradability of refractory organic wastewater by generating $OH{\cdot}$ which is one of the most reactive species. Fenton's reagent is used to treat a variety of industrial waste containing a range of toxic organic compounds. But this process cannot be economical because of high chemical cost of $H_2O_2$, ferrous ion solution and high sludge disposal cost. In this study, we proposed a modified Fenton's oxidation process which can reduce the reagent cost and obtain better removal efficiencies with less Fenton's reagents, and have a good potential of sludge recycling. In modified Fenton reaction, ferrous ion solution is adjusted to optimal pH with NaOH. Then it added to the sample and reacted to $H_2O_2$. For the experiment, synthetic wastewater made of phenol, which is one of the typical water pollutants, was used and the ionic strength of this wastewater was controlled by adding $NaHCO_3$. The effects of DO, ionic strength, and $H_2O_2$ dosing methods were investigated. As a result, modified Fenton's treatment efficiencies are better than conventional Fenton's reaction treating leachate and dyeing wastewater. And modified Fenton's treatment efficiencies combined to the sludge recycling for a half of Iron dosage are as good as the conventional Fenton's for a normal Iron dosage.

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Taxonomic Study of the Genus Lespedeza by Means for Colour Reactions (정색반응(呈色反應)에 의(依)한 싸리속(屬)의 분류학적(分類學的) 연구(硏究))

  • Park, Chong Yawl;Lee, Tchang Bok
    • Journal of Korean Society of Forest Science
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    • v.14 no.1
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    • pp.21-31
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    • 1972
  • It has intended to identify the members of the Genus Lespedeza in Korea by a chemical colour reaction, and the following five species of the Genus Lespedeza grown in the garden have been used in this experiment. 1. Lespedeza bicolor Turcz 2. Lespedeza bicolor var. melanantha (Nak.) T. Lee 3. Lespedeza cyrtobotrya Miq. 4. Lespedeza japonica var. intermedia Nakai 5. Lespedeza maritima Nakai 6. Lespedeza maximowiczii Schneider 7. Lespedeza maximowiczii var. tomentella Nakai A few drops of each solution of $K_2Cr_2O_7$. $FeSO_4{\cdot}7H_2O$, $FeCl_3$, $KH_2PO_4$, $KMnO_4$, $NH_4OH$, and HCl was added to the methanol extracts of wood dust to get the specific colour reaction. HCl-infused wood was also used for the identification of L. bicolor var. melanantha and L. bicolor. The results can be summarized as the following key; 1. Chrome lemon by $K_2Cr_2O_7$ ${\cdots}{\cdots}$2 1. Sun flower yellow by $K_2Cr_2O_7$ ${\cdots}{\cdots}$Lespedeza maximowiczii var. tomentella Nakai 2. $KH_2PO_4$ Oystem white by $KH_2PO_4$; golden yellow by $FeCl_3$ ${\cdots}{\cdots}$=3 2. Cream colour by $KH_2PO_4$=6 3. Oyster white by $NH_4OH$; corn colour by $FeSO_4{\cdot}7H_2O$ ${\cdots}{\cdots}$4 3. Cream colcur by $NH_4OH$ ${\cdots}{\cdots}$5 4. Van dyke brown by $KMnO_4$ ${\cdots}{\cdots}$; sea shell pink by HCl injection under heating ${\cdots}{\cdots}$Lespedeza japonica var. intermedia Nakai 4. Sepia colour by $KMnO_4$; honey colour by HCl injection under heating ${\cdots}{\cdots}$Lespedeza maritima Nakai 5. Golden red by $FeSO_4{\cdot}7H_2O$; andover green by HCl-infused wood dust ${\cdots}{\cdots}$Lespedeza bicolor var. melanantha (Nak.) T. Lee 5. Yellow ochre by $FeSO_4{\cdot}7H_2O$; sand warm gray by HCl-infused wood dust ${\cdots}{\cdots}$Lespedeza bicolor Turcz 6. Amber green by $FeCl_3$ ${\cdots}{\cdots}$Lespedeza cyrtobotrya Miq. 6. Leather brown by $FeCl_3$ ${\cdots}{\cdots}$Lespedeza maximowiczii Schneider.

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