• Bulletin of the Korean Chemical Society
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• v.15 no.9
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• pp.732-739
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• 1994

Asymmetric [2,3]-Wittig rearrangements of allyl propargyl ethers in hexane were performed in the presence of s-butyllithium and (-)-${\alpha}$-isosparteine which is a $C_2$-symmetric chiral ligand for the alkyllithium reagent. The reactions of (Z)-or (E)-allyl 3-trimethylsilylpropargyl ethers at -78$^{\circ}C$ showed good diastereoselectivities (74-100%) and moderate enantioselectivities (29-71%). The absolute configurations of the rearrangement products were determined by the corresponding Mosher's esters. It was found that (-)-${\alpha}$ -isosparteine induced (R) configuration at the hydroxy carbon and syn stereochemistry more favorably. The possible transition state is discussed.

• Asian-Australasian Journal of Animal Sciences
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• v.21 no.4
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• pp.532-537
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• 2008

In order to investigate the factors affecting the culture of mouse preantral follicles in vitro, we examined the effect of culture media, protein supplements, and culture period on their growth. The oocyte diameter (initial size: $55.6{\pm}2.5{\mu}m$) was progressively increased during culture, and the maximum size ($72.0{\pm}2.4{\mu}m$) was reached on day 10 of the in vitro culture. The chromatin configuration in the germinal vesicle (GV) oocyte progressively shifted from a non-surrounded nucleolus (NSN) to a surrounded nucleolus (SN). On day 10 of the culture, most of the oocytes progressed to the SN pattern. The survival and metaphase II rates of the oocytes in alpha-minimal essential medium (alpha-MEM) were significantly higher (p<0.05) than those in Waymouth and tissue culture medium (TCM)-199. As a protein source, fetal bovine serum (FBS) was more suitable for the culture of mouse preantral follicles as compared to human follicular fluid (hFF) and bovine serum albumin (BSA); the optimal concentration of FBS was 5%. These results suggest that in a culture of mouse preantral follicles, alpha-MEM and 5% FBS are an optimal medium and a protein source, respectively; further, the 10 days of culture is required for the complete growth of oocytes in this culture system.

• Composites Research
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• v.13 no.2
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• pp.30-39
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• 2000

It is difficult for civil engineer to apply composite materials of laminated type to structure for civil construction because of complicated theory although those have much merit. A simple method by which one can predict "exact" values of the natural frequency of vibration of laminated plates is presented. Many laminates with particular orientations have negligible values of $B_{16}$ and $B_{26}$ as the number of plies increases. Such laminates, with $D_{16}$ = $D_{26}$ ->0 can be solved by the same equation as for the special orthotropic laminates(1991,1995). If the quasi-isotrpic constants are used, It is possible to simplify analysis procedure since the equations for isotropic plates can be used. Use of some coefficients can produce "exact" values for laminates with such configuration. This coefficient, in fact, represents the effect of the anisotropy of the laminate. D. H. Kim proposed to use a correction factor, he developed, to produce "exact" solution out of the approximate solution obtained by using the quasi-isotropic constants(1995). In this paper, the fiber orienation studied is [$\alpha$/$\beta$/$\beta$/$\gamma$/$\alpha$/$\alpha$/$\beta$]r, with $\alpha$=-$\beta$, and $\gamma$${\gamma}$=$0^{\circ}$ or $90^{\circ}$ and the above-mentioned method is used to obtain the natural frequencies of plates with such orientations, and detailed result is presented for the use of engineers.nted for the use of engineers.

• Journal of The Korean Astronomical Society
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• v.32 no.2
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• pp.127-136
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• 1999

In this study we present the study of solar active regions based on BOAO vector magnetograms and H$\alpha$ filtergrams. With the new calibration method we analyzed BOAO vector magnetograms taken from the SOFT observational system to compare with those of other observing systems. In this study it has been demonstrated that (1) our longitudinal magnetogram matches very well the corresponding Mitaka's magnetogram to the extent that the maximum correlation yields r=0.962 between our re-scaled longitudinal magnetogram and the Mitaka's magnetogram; (2) according to a comparison of our magnetograms of AR 8422 with those taken at Mitaka solar observatory their longitudinal fields are very similar to each other while transverse fields are a little different possibly due to large noise level; (3) main features seen by our longitudinal magnetograms of AR 8422 and AR 8419 and the corresponding Kitt Peak magnetograms are very similar to each other; (4) time series of our vector magnetograms and H-alpha observations of AR 8419 during its flaring (M3.1/1B) activity show that the filament eruption followed the sheared inversion line of the quadrupolar configuration of sunspots, indicating that the flare should be associated with the quadrupolar field configuration and its interaction with new filament eruption. Finally, it may be concluded that the Solar Flare Telescope at BOAO works normally and it is ready to do numerous observational and theoretical works associated with solar activities such as flares.

• Current Optics and Photonics
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• v.1 no.4
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• pp.389-395
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• 2017

This paper investigates a method to improve the lighting performance of white light-emitting diodes (WLEDs), which are packaged using two separate remote phosphor layers, a yellow-emitting YAG:Ce phosphor layer and a red-emitting ${\alpha}-SrO{\cdot}3B_2O_3:Sm^{2+}$ phosphor layer. The thicknesses of these two layers are $800{\mu}m$ and $200{\mu}m$, respectively. Both of them are examined in conditions where the average correlated color temperatures (CCT) are 7700 K and 8500 K. For this two-layer model, the concentration of red phosphor is varied from 2% to 30% in the upper layer, while in the lower layer the yellow phosphor concentration is kept at 15%. It was found interestingly that the lighting properties such as color rendering index (CRI) and luminous flux are enhanced significantly, while the color uniformity is maintained in a relatively close range to the one of one-layer configuration (measured at the same correlated color temperature). Besides, the transmitted and reflected light of each phosphor layer are revised by combining Kubelka-Munk and Mie-Lorenz theories. Through analysis, it is demonstrated that the packaging configuration of two-layer remote phosphor that employs red-emitting ${\alpha}-SrO{\cdot}3B_2O_3:Sm^{2+}$ phosphor particles provides a practical solution for general WLEDs lighting.

• Journal of the Korean Society of Propulsion Engineers
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• v.9 no.3
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• pp.49-59
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• 2005

Turbulent heat transfer over a fully-developed wavy channel is investigated by a turbulence model. The nonlinear k- f - f$_{ model of Park et at.[1] is slightly modified and their explicit algebraic heat flux model is employed. The Reynolds number is fixed at Re$_{b}$=6760 and the wave configuration is varied in the range of 0 $\leq$ $\alpha$/$\lambda$$\leq$0.15 and 0.25 $\leq$A/H$\leq$4.0. In order to verify model performances, a large eddy simulation is performed for the selected cases. The model performance is shown to be generally satisfactory. By using k- $\varepsilon$ - f$_{ model, the enhancement of heat transfer and the characteristics of turbulent flow in wavy wall are investigated. Finally, the influence of wavy configuration on heat transfer is scrutinized.

• Bulletin of the Korean Chemical Society
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• v.23 no.11
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• pp.1527-1530
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• 2002

1,12-diazacyclodocosane-2,11-dione was first isolated from a plant Phyllanthus niruri Linn. Its structure has been determined by means of spectroscopy methods and X-ray crystallography. Two peptide groups in the big ring (lactam) are the main factors influencing intermolecular contacts. The hydrogen-bond interaction of these hydrophilic groups is observed in the crystal structure. Meanwhile, C-H···O hydrogen bonds in molecules contribute to the formation of the whole crystal. These two kinds of hydrogen-bond form six- member rings among molecules. This compound crystallizes in the triclinic space group P-1 with a= 9.588(1) $\AA$, b= $9.850(1)\AA$, c = $11.810(1)\AA$, $\alpha=$ 68.18(1)$^{\circ}C$ , $\beta=$ 84.98(1), $\gamma$ = 86.03(1)$^{\circ}C$ , V = $1030.66(17)\AA3$ , Z = 2. A disorder of five-member carbon chain in the whole ring is observed in the title compound. The bond angle 105.8(4) is determined for a extreme configuration C(14)-C(15)-C(16), and 117.7(10) for another extreme configuration C(14')-C(15')-C(16'). In this crystal, two molecules are tied each other by short intermolecular hydrogen bonds, the oxygen atom being tied by hydrogen bond to nitrogen atom of another two molecules. The NMR and IR spectral data coincides to the structure of the compound.

• Archives of Pharmacal Research
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• v.25 no.3
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• pp.275-279
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• 2002

The crystal structure of byakangelicin, one of furanocoumarin aldose reductase inhibitors, was determined by X-ray diffraction method. The crystal is triclinic, with a=8.114(1), b=10.194(1), $c=11.428(1)\AA,{\;}{\alpha}=111.50(1),{\}{\beta}=95.57(1),{\}{\gamma}=112.52(1)^{circ},{\;}D_x=1.41,{\;}D_m=1.39{\;}g/cm^3$, space group P1 and Z=2. The intensity data were collected by ${\omega}-2{\theta}$ scan method with $CuK_{a}$ radiations. The structure was solved by direct method and refined by full matrix least-squares procedure to the final R-value of 0.056. There are two molecules with different conformations in an asymmetric unit. The molecules are kept by two intermolecular O-HO type hydrogen bonds and van der Waal's forces in the crystal. The absolute configuration of the molecules was estimated to S-form by the 'Eta refinement' procedure.

• Journal of the Korean Chemical Society
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• v.30 no.1
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• pp.84-89
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• 1986

A newflexible $N_2O_2$-type tetradentate ligand. Ethylenediamine-N,N'-di-${\alpha}$-isobutyric acid(eddib), has been synthesized, and dichloro cobalt(III) complex of eddib has been prepared via the air-oxidation technique. Only S-cis isomer has been yielded during the preparation of complex. Ring strain and steric hinderance are cited as the cause for the preference for the S-cis geometric configuration. On series of cobalt(III) complexes of eddib, $[Co(eddib)L]^{n+}$ $(L = Cl{\cdot}(H_2O),\;CO_3^{2-},\;(H_2O)_2)$have been prepared in situ. In their electronic absorption spectra, the absorption maxima and their intensities of the above series of complexes are on the ordinary line of the spectrochemical and hyperchromic series. Elemental analysis, IR, NMR and electronic absorption spectra have been used to characterize the complex and geometries of the complex.

• Journal of the Institute of Electronics and Information Engineers
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• v.53 no.2
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• pp.70-75
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• 2016

This paper proposes the constructing method of effective multiplier based on the finite fields in case of P=2. The proposed multiplier is constructed by polynomial arithmetic part, mod F(${\alpha}$) part and modular arithmetic part. Also, each arithmetic parts can extend according to m because of it have modular structure, and it is adopted VLSI because of use AND gate and XOR gate only. The proposed multiplier is more compact, regularity, normalization and extensibility compare with earlier multiplier. Also, it is able to apply several fields in recent hot issue IoT configuration.