• Title/Summary/Keyword: ${\Delta}SR$

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Microstructure and Dielectric Properties of (Sr.Ca)$TiO_3$-based Ceramics on the thermal diffusing time (열확산 시간에 따른 (Sr.Ca)$TiO_3$계 세라믹의 미세구조 및 유전특성)

  • Kang, Jae-Hun;Kim, Chung-Hyeok;Song, Min-Jong;Choi, Woon-Shik
    • Proceedings of the KIEE Conference
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    • 2001.07c
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    • pp.1387-1389
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    • 2001
  • In this paper, the microstructure and the dielectric properties of the $Sr_{1-x}Ca_xTiO_3$($0{\leq}x{\leq}0.2$)-based grain boundary layer ceramics were investigated. The 2nd phase formed by thermal diffusing from the surface lead to a very high apparent dielectric constant, ${\varepsilon}_r$ > 50000, and tan$\delta$ < 0.05, $\Delta$C < ${\pm}$ 10%.

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Voltage-Current Characteristics of (Sr.Ca)$TiO_3$-based Ceramics with contents of Calcite (Ca 변화량에 따른 (Sr.Ca)$TiO_3$계 세라믹의 전압-전류 특성)

  • Choi, Woon-Shik;Kang, Jae-Hun;Seo, Yong-Jin;Lee, Won-Jae
    • Proceedings of the KIEE Conference
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    • 2001.07c
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    • pp.1384-1386
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    • 2001
  • In this paper, the structural and electrical properties of the $Sr_{1-x}Ca_xTiO_3$($0{\leq}x{\leq}0.2$)-based grain boundary layer ceramics were investigated by X-ray, SEM and V-I system. Increasing content of Ca, the average gram size and the lattice constant were decreased. The relative density of all specimens was > 96%. The 2nd phase formed by thermal diffusing from the surface lead to a very excellent electrical properties, that is, ${\varepsilon}_r$ > 50000, tan${\delta}$ < 0.05, $\Delta$C < ${\pm}$ 10%.

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Stabilization and Physical Properties of Ruddlesden-Popper Phase $Sr_3Mn_{2-x}Fe_xO_{7-\delta}(x{\leq}0.3)$ (Ruddlesden-Popper 상 $Sr_3Mn_{2-x}Fe_xO_{7-\delta}(x{\leq}0.3)$의 안정화 및 물성에 관한 연구)

  • Song, Min-Seok;Lee, Jai-Yeoul
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07b
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    • pp.790-793
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    • 2004
  • 이중의 망간 perovskite 블록을 가진 Ruddlesden-Popper 상(R-P phase) $Sr_3Mn_2O_7$ 은 공기중에서 불안정하다. 본 연구에서는 망간 이온 자리에 철 이온을 소량 치환 함으로써 R-P 상을 안정화 시켰으며 이들의 결정구조는 X-선회절 데이터를 이용하여 Rietveld 법으로 정밀화하였다. 안정화에 필요한 Fe 이온의 양은 약 x=0.15로 나타났으며 Fe이온의 양이 증가함에 따라 쉽게 안정화 되었다. 자화율 측정결과 x=0.20 시료는 120K에서 paramgnetic-antiferromagnetic 전이를 나타내었고 이 전이 온도는 치환되는 Fe이온의 양이 증가함에 따라 감소하는 경향을 나타내었다.

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Characterization of Ln0.8Sr0.2CoO3-δ (Ln=Gd, Nd, Pr, Sm, or Yb) as Cathode Materials for Low-Temperature SOFCs

  • Choi, Jung-Woon;Kang, Ju-Hyun;Kim, Han-Ji;Yoo, Kwang-Soo
    • Journal of the Korean Ceramic Society
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    • v.43 no.12 s.295
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    • pp.758-763
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    • 2006
  • Perovskites with nominal compositions $Ln_{0.8}Sr_{0.2}CoO_{3-\delta}$ (Ln=Gd, Nd, Pr, Sm, or Yb) were fabricated as cathode materials using a solid-state reaction method for low-temperature operating Solid-Oxide Fuel Cells (SOFCs). X-ray diffraction analysis and microstructure observation for the sintered samples were performed. The ac complex impedance was measured in the temperature range of $600-900^{\circ}C$ in air and fitted with a Solartron ZView program. The crystal structure, microstructure, electrical conductivity, and polarization resistance of $Ln_{0.8}Sr_{0.2}CoO_{3-\delta}$ were characterized systematically.

Capacitive-Voltage properties of (Sr.Ca)$TiO_3$ Ceramics ((Sr.Ca)$TiO_3$ 세라믹스의 용량-전압 특성)

  • 강재훈;최운식;김충혁;김진사;박용필;송민종
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11a
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    • pp.34-37
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    • 2001
  • In this study, the capacitance-voltage properties of (Sr$_{1-x}$ .Ca$_{x}$)TiO$_3$(0.05$\leq$x$\leq$0.20)-based grain boundary layer ceramics were investigated. The ceramics were fabricated by the conventional mixed oxide method. The sintering temperature and time were 1480~150$0^{\circ}C$ and 4 hours, respectively. The 2nd phase formed by the thermal diffusion of CuO from the surface leads to very excellent dielectric properties, that is, $\varepsilon$$_{r}$>50000, tan$\delta$<0.05, $\Delta$C<$\pm$10%. The capacitance is almost unchanged below about 20[V] but it decreases slowly about 20[V]. The results of the capacitance-voltage properties indicated that the grain boundary was composed of the continuous insulating layers.ulating layers.s.

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Electrical Conductivity of ${La_{2-x}}{Sr_x}{Mo_{2-y}}{Cr_y}{O_{9-\delta}}$Ionic Conductors (${La_{2-x}}{Sr_x}{Mo_{2-y}}{Cr_y}{O_{9-\delta}}$ 이온전도체의 전기전도도)

  • ;;Allan J. Jacobson
    • Journal of the Korean Ceramic Society
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    • v.38 no.8
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    • pp.693-697
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    • 2001
  • 고상반응법으로 이론 밀도의 약 92%의 소결 밀도를 갖는 입방정계의 새로운 이온전도체 L $a_{2-x}$S $r_{x}$M $o_{2-y}$C $r_{y}$ $O_{9-{\delta}}$(x=0, 0.05, y=0, 0.1)를 제조하였다. 교류 복소임피던스는 3$50^{\circ}C$~90$0^{\circ}C$의 온도범위에서 공기중에서 측정하여, EQUIVCRT 모델링 소프트웨어로 해석하였다. 상 전이온도인 58$0^{\circ}C$ 전.후로 임피던스 스펙트럼에 큰 차이가 있었으며, 전기전도도는 L $a_2$M $o_2$ $O_{9}$ 시편의 경우 7$50^{\circ}C$에서 3$\times$$10^{-2}$ S$cm^{-1}$ /로 우수하였으며, 활성화 에너지는 고온 상 영역에서는 0.89 eV, 저온 상 영역에서는 1.12 eV이었다. 순수한 L $a_2$M $o_2$ $O_{9}$과 비교하여 Cr 치환효과는 크지 않았으나, Sr 치환 시에는 상 전이온도의 감소와 전기전도도의 증가 현상을 보였으며, 전이온도 부근에서의 전기전도도 변화 폭은 작았다.다.

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[ $Bi_2Sr_2CaCu_2O{8+\delta}$ ] Intrinsic Josephson Junctions in a Parallel Magnetic Field

  • Lee, J.H.;Chong, Yon-Uk;Lee, Su-Youn;Khim, Z.G.
    • Progress in Superconductivity
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    • v.1 no.2
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    • pp.110-114
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    • 2000
  • We have investigated the Josephson vortex dynamics in $Bi_2Sr_2CaCu_2O{8+\delta}$ intrinsic Josephson junctions subjected to a magnetic field parallel to $CuO_2$ planes. We investigated mesas with $40\times40{\mu}m^2$ in size and containing 6 and 20. intrinsic junctions. The zero field I-V characteristics exhibited a typical hysteretic, multi-branched nature of the intrinsic Josephson effect. At high magnetic fields (H>1.5 T), I-V characteristics showed flux flow steps. The Swihart velocity obtained from this observation was about $4.2\times10^5$ m/s, which was the lowest mode electromagnetic wave velocity of N coupled stack. The experimental I-V curves fitted well into the simple model of Cherenkov radiation including Ohmic and non-linear dissipation terms. This suggests that the dissipation mechanism of Josephson vortex be due to both Cherenkov radiation and quasiparticle tunneling current.

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Study on the Fabrication Step-edges on $\textrm{SrTiO}_3$ Substrates and the Characterization of $\textrm{YBa}_{2}\textrm{Cu}_{3}\textrm{O}_{7-\delta}$ Step-edge Junctions ($\textrm{SrTiO}_3$ 기판 위에 계단형 모서리 제작 및 $\textrm{YBa}_{2}\textrm{Cu}_{3}\textrm{O}_{7-\delta}$계단형 모서리 접합의 특성 연구)

  • Nam, Byeong-Chang;Kim, In-Seon;Lee, Sun-Geol;Park, Jong-Cheol;Park, Yong-Gi
    • Korean Journal of Materials Research
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    • v.8 no.10
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    • pp.950-955
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    • 1998
  • Ar 이온 식각법을 이용하여 (001) SrTiO3(STO) 단결정 기판 위에 200nm 높이의 계단형 모서리를 제작하였다. 계단식은 입사하는 Ar 이온 빔에 대한 Ar 이온 입사각과 마스크 회전각을 조절함으로써 38$^{\circ}$-70$^{\circ}$의 넓은 범위로 제어할 수 있었다. 초전도 YBa2Cu3O7-$\delta$박막은 계단이 있는 STO 기판 위에 펄스레이저 증착법을 이용하여 증착하였으며, 박막의 두께는 계단 높이에 대한 박막의 두께비가 0.5-1.2가 되도록 하였다. 계단형 모서리 조셉슨 접합의 임계전류밀도와 IcRn값은 77K에서 각각 104A/$\textrm{cm}^2$, 70-200$\mu$V이었다.

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Preparation of Epitaxial $LaSrCoO_3/SrTiO_3(100)$ Structures by The Chemical Solution Process (화학적 용액법에 의한 에피탁샬 $LaSrCoO_3/SrTiO_3(100)$ 구조의 제조)

  • 이형민;황규석;송종은;류현욱;강보안;윤연흠;김병훈
    • Journal of the Korean Ceramic Society
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    • v.36 no.10
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    • pp.1075-1079
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    • 1999
  • LaSrCoO3 thin films were spin-coated onto the SrTiO3(100) substrates by the chemical solution process. X-ray diffraction $\theta$-2$\theta$ scans and X-ray diffraction $\beta$ scans were used to determine the crystallinity and in -plane alignment behavior of the films. The X-ray diffraction pattern showed the film obtained by annealing at 80$0^{\circ}C$ was highly oriented. The X-ray diffraction pole-figure analysis and reciprocal-space mapping (2$\theta$-$\Delta$$\omega$ scans) of the resulting film showed that the film comprising the pseduocubic phase had an epitaxial relationship with the SriO3 substrate.

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Bacterial Stringent Signal Directs Virulence and Survival in Vibrio cholerae.

  • Oh, Young Taek;Kim, Hwa Young;Yoon, Sang Sun
    • Proceedings of the Plant Resources Society of Korea Conference
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    • 2019.10a
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    • pp.8-8
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    • 2019
  • The stringent response (SR) is characterized as a bacterial defense mechanism in response to various growth-inhibiting stresses. It is activated by accumulation of a small nucleotide regulator, (p)ppGpp, and induces global changes in bacterial transcription and translation. Recent work from our group has shown that (p)ppGpp plays a critical role in virulence and survival in Vibrio cholerae. The genes, relA and relV, are involved in the production of (p)ppGpp, while the spoT gene encodes an enzyme that hydrolyzes it in V. cholerae. A mutant strain defective in (p)ppGpp production (i.e. ${\Delta}relA{\Delta}relV{\Delta}spoT$ mutant) lost the ability to produce cholera toxin (CT) and lost their viability due to uncontrolled production of organic acids, when grown with extra glucose. In contrast, the ${\Delta}relA{\Delta}spoT$ mutant, a (p)ppGpp overproducer strain, produced enhanced level of CT and exhibited better growth in glucose supplemented media via glucose metabolic switch from organic fermentation to acetoin, a neutral fermentation end product, fermentation. These findings indicates that (p)ppGpp, in addition to its well-known role as a SR mediator, positively regulates CT production and maintenance of growth fitness in V. cholerae. This implicates SR as a promising drug target, inhibition of which may possibly downregulate V. cholerae virulence and survival fitness. Therefore, we screened a chemical library and identified a compound that induces medium acidification (termed iMAC) and thereby loss of wild type V. cholerae viability under glucose-rich conditions. Further, we present a potential mechanism by which the compound inhibits (p)ppGpp accumulation. Together, these results indicate that iMAC treatment causes V. cholerae cells to produce significantly less (p)ppGpp, an important regulator of the bacterial virulence and survival response, and further suggesting that it has a therapeutic potential to be developed as a novel antibacterial agent against cholera.

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