• Title/Summary/Keyword: ${\Delta}E$

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The Photoluminescence(PL) Spectroscopy and the Photo-Darkening(PD) Effect of the Amorphous SeGe Thin Films (비정질 SeGe 박막의 PL 특성과 광흑화 효과에 관한 연구)

  • 김진우;이현용;정홍배
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.5
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    • pp.435-440
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    • 2002
  • In this study, we have investigated photo-induced changes of optical energy gap( $E_{OP)}$ and photoluminescence (PL) in amorphous ($\alpha$-) S $e_{100-x}$G $e_{x}$ (x=5, 25 and 33) thin films prepared by conventional thermal evaporation method. In the $\alpha$-S $e_{100-x}$G $e_{x}$ thin film, the $E_{OP}$ is obtained by a linear extrapolation of the ($\alpha$hν)$^{\frac{1}{2}}$ versus hν plot to the energy axis using the optical absorption coefficient ($\alpha$) calculated from the extinction coefficient k measured in the wavelength range of 290~900nm. Although the values of $\Delta$ $E_{OP}$ are very different, all films exhibit photo-induced photo-darkening (PD) effect that is a red shift of $E_{OP}$ . In particular, $\Delta$ $E_{OP}$ in $\alpha$-S $e_{75}$ G $e_{25}$ thin film exhibits the largest value (i, e., $\Delta$ $E^{OP}$ ~40meV for $\alpha$-S $e_{95}$ G $e_{5}$ , $\Delta$ $E_{OP}$ ~200meV for $\alpha$-S $e_{75}$ G $e_{25}$ , $\Delta$ $E_{OP}$ ~130meV for $\alpha$-S $e_{67}$ G $e_{33}$ ). PL spectra in $\alpha$-SeGe by hν$_{HeCd}$ have no-Stokes shift (SS) and show a tendency dependent on both composition and illumination time. We explain the energy-induced phenomena such as the PD and thermal bleaching, the native charged-defect generation and the no-SS PL, etc..the PD and thermal bleaching, the native charged-defect generation and the no-SS PL, etc..tc..

Biological Functions of the COOH-Terminal Amino Acids of the $\alpha$-Subunit of Tethered Equine Chorionic Gonadotropin

  • Jeoung, Youn-Hee;Yoon, Jong-Taek;Min, Kwan-Sik
    • Reproductive and Developmental Biology
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    • v.34 no.1
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    • pp.47-53
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    • 2010
  • Glycoprotein hormones have a common $\alpha$-subunit that is involved in the signaling pathway together with G protein, adenylcyclase and cAMP induction; however, it is an unclear how this common structure is related to hormonal action. To determine the biological functions of the COOH-terminal amino acids in the $\alpha$-subunit of these glycoprotein hormones, a tethered-molecule was constructed by fusing the $NH_2$-terminus of the $\alpha$-subunit to the COOH-terminus of the $\beta$-subunit of equine chorionic gonadotropin (eCG). The following deletion mutants were created by PCR; Ile was inserted at position 96 to form ${\Delta}96$, Lys was substituted at position 95 to form ${\Delta}95$, His was inserted at position 93 to form ${\Delta}93$ and Tyr was substituted at position 87 to form ${\Delta}87$. Each mutant was transfected into CHO-K1 cells. Tethered-wt eCG, and ${\Delta}96$, ${\Delta}95$, and ${\Delta}93$ mutants were efficiently secreted into the medium but the ${\Delta}87$ mutant was not secreted. Interestingly, the RT-PCR, real-time PCR, and northern blot analyses confirmed that the RNA was transcribed in the ${\Delta}87$ mutant. However, the ${\Delta}87$ mutant protein was not detected in the medium or the intracellular fraction of the cell lysates. The LH- and FSH-like activities of the recombinant proteins were assayed in terms of cAMP production using rat LH/CG and rat FSH receptors. The metabolic clearance rate (MCR) was determined by injecting rec-eCG (2 IU) into the tail vein. The ${\Delta}95$ and ${\Delta}93$ mutants were completely inactive in both the LH- and FSH-like activity assays. The ${\Delta}96$ mutant showed slight activity in the LH-like activity assay. In comparison to the wild type, the activity of the ${\Delta}96$ mutant in the FSH-like activity assay was the highest among all the mutants. The MCR assay in which rec-eCG was injected showed a peak at 10 min in all the treatment groups, which disappeared 4 h after injection. These results imply a direct interaction between the receptor and the COOH-terminal region of the a-subunit. The data also reveal a significant difference in the mechanism by which the eCG hormone interacts with the rLH and rFSH receptors. The COOH-terminal region of the $\alpha$-subunit is very important for the secretion and functioning of this hormone.

Formation Process of Barium Ferrite Crystallites in Molten Salts and its Magnetic properties (용융염내에서의 Ba-ferrite 결정의 생성과정 및 그 자기적 특성)

  • 정지형;김창곤;윤석영;신학기;김태옥
    • Journal of the Korean Ceramic Society
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    • v.38 no.11
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    • pp.1015-1022
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    • 2001
  • In this study, formation process of Ba-ferrite by using molten salt synthesis and its magnetic properties were investigated. Among starting materials, BaC $O_3$was only soluble in the molten salts, but other starting material such as $\delta$-FeOOH or F $e_2$ $O_3$was not soluble even at 105$0^{\circ}C$. It implies that the dissolved $Ba^{2+}$ diffused on surfaces of F $e_2$ $O_3$(or $\delta$-FeOOH), therefore, Ba-ferrtites were formed through surface reaction. However, the magnetic properties of Ba-ferrite prepared by two starting materials (F $e_2$ $O_3$and $\delta$-FeOOH) were not different. On the other hand, compared $\delta$-FeOOH with F $e_2$ $O_3$m, morphologies and dispersibility of Ba-ferrites prepared by using $\delta$-FeOOH were good and Ba-ferrites were obtaioned at lower temperature.

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Clamping Voltage Characteristics and Accelerated Aging Behavior of CoCrTb-doped Zn/Pr-based Varistors with Sintering Temperature

  • Nahm, Ghoon-Woo
    • Transactions on Electrical and Electronic Materials
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    • v.10 no.4
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    • pp.125-130
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    • 2009
  • The clamping voltage characteristics and accelerated aging behavior of CoCrTb-doped Zn/Pr-based varistors were investigated for different sintering temperatures. The best clamping voltage characteristics were obtained for the varistors sintered at $1330^{\circ}C$, with a clamping voltage ratio (K) of 1.63 at a surge current of 5 A and 1.75 at a surge current of 10 A. The varistors sintered at $1330^{\circ}C$ exhibited the highest stability, with -0.1% in $%{\Delta}E_{1\;mA}$, -0.2% in $%{\Delta}{\alpha}$, and +15.5% in $%{\Delta}J_L$ for E-J characteristics under a stress state of 0.90 $E_{1\;mA/120^{\circ}C$ /24 h. Furthermore, it exhibited $%{\Delta}{\varepsilon}_{APP}$' of -0.7% and $%{\Delta}tan{\delta}$ of +5.7% for dielectric characteristics under the same stress state.

SEARCH FOR PHOTOMETRIC ABUNDANCE INDICES FOR M DWARF STARS

  • Lee, Sang-Gak
    • Journal of The Korean Astronomical Society
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    • v.15 no.2
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    • pp.49-58
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    • 1982
  • The UBVRIHKL magnitudes on Johnson system and space motions of M dwarf stars have been collected. This sample of M stars have been distinguished on a purely kinematical basis; the one with e<0.15, young disk population, with 0.150.3 halo population. On the color-color diagrams and the color excess-orbital eccentricity diagrams, there is no distinction between the old disk stars and the young disk stars. However (I-H) color could be used to distinguish halo stars from young and old disk stars and the color excesses, ${\Delta}(U-B),\;{\Delta}(B-V),\;{\Delta}(V-R),\;{\Delta}(H-K),\;{\Delta}(K-L),\;and\;{\Delta}(B-R)$ can be used as abundance indicators only for the halo stars. But these color excesses which are measures of blue excesses, are positive for the halo stars with smaller eccentricities and become negative for those with larger eccentricities.

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Design of fuzzy control system based on PID control scheme (PID 제어방식에 근거한 퍼지 제어 시스템의 설계)

  • 김관준;이철희;남현도
    • 제어로봇시스템학회:학술대회논문집
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    • 1993.10a
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    • pp.404-407
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    • 1993
  • In this paper, a new PID fuzzy controller(FC) is presented. The linguistic control rules of PID FC is separated into two parts : one is e-.DELTA.e part, and the other is .DELTA.$^{2}$e - .DELTA.e part. And then two FCs employing these rule base individually are synthesized. The control input to the process is decided by taking weighted mean of the outputs of two FCs. The proposed PID FC improve the transient response of the system and gives better performance than the conventional PI FC.

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Fuzzy PID control System by Parallel PI and PD Control (PI와 PD의 병렬 구성에 의한 퍼지 PID제어 시스템)

  • Lee, Chul-Heu
    • Journal of Industrial Technology
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    • v.13
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    • pp.43-48
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    • 1993
  • In this paper, a new PID fuzzy controller (FC) is presented. The linguistic control rules of PID FC is separated into two parts : one is $e-{\Delta}e$ part, and the other is ${\Delta}^2e-{\Delta}e$ part. And then two FCs employing these rule base indivisually are synthesized. The control input to the process is decided by taking weighted mean of the outputs of two FCs. The proposed PID FC improve the transient response of the system and gives better performance than the conventional PI FC.

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SOME PROPERTIES ON f-EDGE COVERED CRITICAL GRAPHS

  • Wang, Jihui;Hou, Jianfeng;Liu, Guizhen
    • Journal of applied mathematics & informatics
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    • v.24 no.1_2
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    • pp.357-366
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    • 2007
  • Let G(V, E) be a simple graph, and let f be an integer function on V with $1{\leq}f(v){\leq}d(v)$ to each vertex $v{\in}V$. An f-edge cover-coloring of a graph G is a coloring of edge set E such that each color appears at each vertex $v{\in}V$ at least f(v) times. The f-edge cover chromatic index of G, denoted by ${\chi}'_{fc}(G)$, is the maximum number of colors such that an f-edge cover-coloring of G exists. Any simple graph G has an f-edge cover chromatic index equal to ${\delta}_f\;or\;{\delta}_f-1,\;where\;{\delta}_f{=}^{min}_{v{\in}V}\{\lfloor\frac{d(v)}{f(v)}\rfloor\}$. Let G be a connected and not complete graph with ${\chi}'_{fc}(G)={\delta}_f-1$, if for each $u,\;v{\in}V\;and\;e=uv{\nin}E$, we have ${\chi}'_{fc}(G+e)>{\chi}'_{fc}(G)$, then G is called an f-edge covered critical graph. In this paper, some properties on f-edge covered critical graph are discussed. It is proved that if G is an f-edge covered critical graph, then for each $u,\;v{\in}V\;and\;e=uv{\nin}E$ there exists $w{\in}\{u,v\}\;with\;d(w)\leq{\delta}_f(f(w)+1)-2$ such that w is adjacent to at least $d(w)-{\delta}_f+1$ vertices which are all ${\delta}_f-vertex$ in G.

The Effect of Pressure on the Electrophilic Substitution Reaction of Tetramethyltin with Iodine (Tetramethyltin과 Iodine의 친전자 치환반응에 대한 압력의 영향)

  • Kwun Oh Cheun;Lee Young Hoon
    • Journal of the Korean Chemical Society
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    • v.37 no.6
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    • pp.555-561
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    • 1993
  • Ultraviolet spectrophotometric investigation has been carried out on the system of iododestannylation iodine and tetramethyltin in methanol. The transient CT absorption spectrum can be observed and the subsequent disappearance of CT absorption spectrum was accompained by the cleavage of tetramethyltin with iodine. From there, the rate constants for the iododestannylation were determined at 10, 25 and 35$^{\circ}C$ up to 1600 bar and the reaction rates were increased with increasing temperature and pressure. From these rate constants, the values of the activation parameters (${\Delta}V^\neq,\;{\Delta}{\beta}^{\neq},\;{\Delta}H^{\neq},\;{\Delta}S^{\neq}\;and\;{\Delta}G^{\neq}$) were obtained. The activation volumes and activation compressibility coefficients were both negativity. The activation enthalpies were positive and activation entropies had large negative values. From these values discussed in terms of solvent structure variation of transition state and mechanism. From these results, it was found that the reaction is followed with $S_E2$ mechaenism and weakened $S_E2$ mechanism nature by increasing pressure.

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Studies on the Light Fastness of Dyeings. (II) Fading Rate Curve (染色物의 日光에 對한 堅牟性에 關한 硏究 (第2報) 褪色速度 曲線에 對하여)

  • Ha, Wan-Shik
    • Journal of the Korean Chemical Society
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    • v.8 no.4
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    • pp.142-146
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    • 1964
  • The author proposed an equation of fading rate, expressed as ${\Delta}E$=${\Delta}E_{1{\infty}}({{1-e^{-k}}_1}^t)+k_2t$, where ${\Delta}E$=fading of dye (colour difference of N.B.S. unit), ${\Delta}E_{1{\infty}}$=extremity value of fading of molecularly dispersed dye, $k_1$, $k_2$=constants, t=exposure (hours). The validity of above equation, which is connected with the state of dye in fibre, was confirmed by experimental in a range of 2-3 colour fading in grey scale value for assessing change in colour visually, except the case of increasing the fading rate with the time resulted from the break-down of dye particles through the heat effect of light; it was also discussed about possiblity of evaluating of fastness to light of dye in early stage.

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