Formation Process of Barium Ferrite Crystallites in Molten Salts and its Magnetic properties

용융염내에서의 Ba-ferrite 결정의 생성과정 및 그 자기적 특성

  • 정지형 (부산대학교 무기재료공학과) ;
  • 김창곤 (부산대학교 무기재료공학과) ;
  • 윤석영 (부산대학교 무기재료공학과) ;
  • 신학기 (경남정보대학 식품화공학부) ;
  • 김태옥 (부산대학교 무기재료공학과)
  • Published : 2001.11.01

Abstract

In this study, formation process of Ba-ferrite by using molten salt synthesis and its magnetic properties were investigated. Among starting materials, BaC $O_3$was only soluble in the molten salts, but other starting material such as $\delta$-FeOOH or F $e_2$ $O_3$was not soluble even at 105$0^{\circ}C$. It implies that the dissolved $Ba^{2+}$ diffused on surfaces of F $e_2$ $O_3$(or $\delta$-FeOOH), therefore, Ba-ferrtites were formed through surface reaction. However, the magnetic properties of Ba-ferrite prepared by two starting materials (F $e_2$ $O_3$and $\delta$-FeOOH) were not different. On the other hand, compared $\delta$-FeOOH with F $e_2$ $O_3$m, morphologies and dispersibility of Ba-ferrites prepared by using $\delta$-FeOOH were good and Ba-ferrites were obtaioned at lower temperature.

본 연구에서는 용융염법에 의한 Ba-ferrite의 생성기구와 그 자기적특성에 대해 조사하였다. 출발원료 중 BaC $O_3$만이 용융염내에서 용해도를 가졌으며, 이는 용융염내에서는 Ba-ferrite의 생성이 용해된 $Ba^{2+}$가 F $e_2$ $O_3$$\delta$-FeOOH의 표면으로 확산하여 표면반응을 통해 일어나는 것으로 보인다. 한편, 출발물질($\delta$-FeOOH와 F $e_2$ $O_3$)에 따라 생성된 Ba-ferrite가 합성되는 온도는 더 낮은 온도에서 생성됨을 알 수 있었다.

Keywords

References

  1. IEEE Trans. Magn v.MAG-13 no.5 An Analysis for the Magnetization Mode for High Density Magnetic Recording S. Iwasaki;T. Nakamura
  2. ibid v.MAG-22 no.5 Pigment-to-Binder Loading Effects in Ba-ferrite Coating D. E. Speliotis
  3. ibid v.MAG-22 no.5 Temperature Effects in Barium Ferrite Particles D. E. Speliotis
  4. ibid v.MAG-21 no.5 Barium Ferrite Media Perpendicular Recording T. Fujiwara
  5. Ibid v.MAG-21 no.5 Relations Between Coercivity and Recording Performances for Ba-ferrite Particulate Perpendicular Media M. Isshiki;T. Suzuki;T. Ito;T. Ido;T. Fujiwara
  6. ibid v.MAG-22 no.5 Coercivity for Ba-frttite Superfine Particles T. Ido;O. Kubo;H. Yokoyama
  7. ibid v.MAG-18 no.6 Properties of Ba Ferrite Particles for Perpendicular Magnetic Recording Media O. Kubo;T. Ido;H. Yokoyama
  8. J. Appl. Phys. v.44 no.8 Magnetization Reversal Process in Chemically Precipitated and Ordinary Prepared Ba$Fe_12$$O_19$ K. Haneda;H. Kojima
  9. J. Kor. Ceram. Soc. v.26 no.6 Effects Heat Treatment on the Composition and Magnetic Properties of the Hydrothermal-synthesized Ba-ferrite Powder S. H. Lee;J. H. Kim;T. O. Kim
  10. Bull. Chem. Soc. Jpn. v.49 no.7 Conditions for the Formation of BaO and Fe₂O₃from Aqueous Suspension M. Kiyama
  11. J. Kor. Ceram. Soc. v.34 no.10 Crystal Structures of Ba-Ferrite Synthesize by Coprecipitation-oxididation Method H. S. Shin
  12. Ferrite:Proc. ICFI. The Preparation of Ferrite with the Aid of Fused Salts D. G. Wickham
  13. Ferrite:Proc. ICF3 Preparation of Ferrite Powder by Flux Method T. Kimura;T. Takahashi;T. Yamaguchi
  14. Adv. in Ceram. v.21 Morphology Control of Electronic Ceramic Powder by Molten Salt Synthesis T. Kimura;T. Yamaguchi
  15. Tranl. Int. Geol.Rev. v.19 Feroxyhite, a New Modification of FeOOH F. V. Chukhrov;B. B. Zvyagin;A. I. Gorshkov;L. P. Yermilova;V. V. Korovushkin;Y. S. Rudnitskaya;N. Y. Yakubovskaya
  16. Clay. Miner. Bull. v.4 Structure Transformations of Effected by thr Dehydration of Diaspore, Geothite and Delta Ferrie Oxide M. H. Francombe;H. P. Rooksby
  17. Clay Mineral v.28 Structure of Feroxyhite as Determined by Simulation of X-ray Diffraction Curves V. A. Drits;B. A. Sakharov;A. Manceau
  18. IEEE Trans. Magn. v.MAG-20 no.5 Magnetic Structure and Supermagnetic Properties of δ-FeOOH M. Pernet;X. Obradors;J. Fontcuberta;J. C. Jonbert;J. Tejada
  19. J. Chem. Soc. Faraday Trans. v.88 no.8 Chracterization of the Thermal Decomposition Product of δ-FeOOH by Fourier-transform Infrared Spectroscopy and N₂Adsorption T. Ishikawa;W. Y. Cai;K. Kandori
  20. J. Chem. Soc. Faraday Tranas. v.90 no.17 Textures of Tetradecahedron σ-FeOOH Particles and Their Thermal Decomposition Products T. Ishikawa;A. Tasukawa;K. Kandoril
  21. J. Kor. Ceram. Soc. v.31 no.12 The Thermal Decomposition Precess of δ-FeOOH Prepared by Rapid Oxidation Method Y. D. Park;H. H. Lee;T. O. Kim
  22. Magnetism:Principles and Applications D. Craik
  23. IEEE Trans. Mag. v.MAG-22 no.5 Coercivity for Ba-ferrite Superfine Particles T. Ido;O. kubo;H. Yokoyama
  24. J. Colloid and Interface Sci. v.122 no.2 Textural Evolution of α-Fe₂O₃Obtained by Thermal and Mechanochemical Decomposition of δ-FeOOH J. M. Jimenez-Mateos;J. Morales;J. L. Tirado