• Title/Summary/Keyword: $^1H$-relaxation

Search Result 248, Processing Time 0.022 seconds

Investigation on structural symmetry of CsCoCl3·2H2O crystals by magic-angle spinning 1H and static 133Cs nuclear magnetic resonance

  • Park, Sang Hyeon;Jang, Du Chang;Jeon, Hara;Gyeong, Oh Yi;Lim, Ae Ran
    • Journal of the Korean Magnetic Resonance Society
    • /
    • v.26 no.1
    • /
    • pp.10-16
    • /
    • 2022
  • The phase transition temperatures of CsCoCl3·2H2O crystals are investigated via differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). Three endothermic peaks at temperatures of 370 K (=TC1), 390 K (=TC2), and 416 K (=TC3) were observed for phase transitions from CsCoCl3·2H2O to CsCoCl3·1.5H2O, to CsCoCl3·H2O, and then to CsCoCl3·0.5H2O, respectively. In addition, the spin-lattice relaxation time T in the rotating frame and T1 in the laboratory frame as well as changes in chemical shifts for 1H and 133Cs near TC1 were found to be temperature dependent. Our analyses results indicated that the changes of chemical shifts, T, and T1 are associated with structural phase transitions near temperature TC1. The changes of chemical shifts, T, and T1 near TC1 were associated with structural phase transitions, owing to the changes in the symmetry of the structure formed of H2O and Cs+ ions. Consequently, the structural symmetry in CsCoCl3·2H2O crystals based on temperature is discussed by the environments of their H and Cs nuclei.

Effects of histamine on the ruminal smooth muscle motility of cattle (소(牛)의 제1위 평활근 운동성에 대한 histamine의 효과)

  • Yoon, Byeong-cheol;Han, Ho-jae;Han, Bang-keun
    • Korean Journal of Veterinary Research
    • /
    • v.34 no.3
    • /
    • pp.471-478
    • /
    • 1994
  • Effects of histamine on the ruminal smooth muscle motility of cattle were investigated in the longitudinal and circular smooth muscle strips. In order to these experiments, specimens were obtained from 35 korean native cattles, 3-4 years old, in Kwang-ju area slaughterhouse. Smooth muscle strips of rumen were made from sample, and then measured the isometric contraction with physiograph in $37{^{\circ}C}$ organ bath. The results were as follows : 1. Histamine caused two different types of response(a contraction or a relaxation) on the smooth muscle of cattle rumen. These responses increased in dose dependant manner. 2. Pyrilamine($H_1$-receptor antagonist) completely blocked contraction in all the preparation and converted the response into relaxation. 3. Cimetidine($H_2$-receptor antagonist) completely blocked relaxation in all the preparation and converted the response into contraction. 4. The contraction induced by histamine($10^{-3}M$) was not Mocked by cholinergic, adrenergic blocker or hexamethonium. 5. The contraction induced by histamine($10^{-3}M$) was markedly inhibited in the $Ca^{2+}$ free(or EDTA 2Na) Kreb's solution and by verapamil.

  • PDF

The vortex dynamics in $Bi_2$$Sr_2$Ca$Cu_2$$O_8$single crystals unirradiated and with low-density columnar defect (저밀도 원통형 결함이 $Bi_2Sr_2CaCu_2O_8$ 단결정의 볼텍스 동역학에 미치는 영향)

  • Lee, T.W.;Lee, C.W.;Shim, S.Y.;Ha, D.H.;Kim, D.H.
    • Progress in Superconductivity
    • /
    • v.3 no.1
    • /
    • pp.36-40
    • /
    • 2001
  • We have studied vortex dynamics in$ Bi_2$$Sr_2$$CaCu_2$O$_{8}$single crystals of unirradiated and irradiated samples by using 100 $\times$ $100\mu\textrm{m}^2$Hall sensor. Doses equivalent magnetic fields are 20 G, 100 G and 1 kG. In the magnetization measurement, a second magnetization peak (SMP) was observed in unirradiated, 20 G dose and 100 G dose samples in contrast to 1 kG dose sample. In the unirradiated sample, the SMP was observed in the range of 18 K ~ 35 K and the amplitude of the SMP decreased with increasing temperature. With increase of the irradiation dose, temperature region and sharpness of the SMP were reduced. In the magnetic relaxation measurement, we observed that the normalized relaxation rate S decreased with increasing the irradiation dose. Our results suggest that the vortex dynamics is not greatly affected by low-density columnar defects.s.

  • PDF

Red Ginseng Saponin Fraction A Isolated from Korean Red Ginseng by Ultrafiltration on the Porcine Coronary Artery

  • Jung, Young-Hyun;Park, Kwang-Yeol;Jeon, Jin-Hong;Kwak, Yi-Seong;Song, Yong-Bum;Wee, Jae-Joon;Rhee, Man-Hee;Kim, Tae-Wan
    • Journal of Ginseng Research
    • /
    • v.35 no.3
    • /
    • pp.325-330
    • /
    • 2011
  • Red ginseng saponin fraction-A (RGSF-A) contains a high percentage of panaxadiol saponins that were isolated from Korean red ginseng by ultrafiltration. The aim of this study was to elucidate the effects of RGSF-A on the porcine distal left anterior descending (LAD) coronary artery. The relaxant responses to RGSF-A were examined during contractions induced by 100 nM U46619 (9,11-dideoxy-9a,11a-methanoepoxy-prostaglandin F2a), a stable analogue of thromboxane A2. RGSF-A dose-dependently induced biphasic (fast- and slow-) relaxation in the distal LAD coronary artery in the presence of an intact endothelium. The fast-relaxation was quickly achieved in a minute, and then the slow-relaxation was slowly developed and sustained for more than thirty minutes after the administration of RGSF-A. The slow-relaxation had a tendency to be bigger than the fast-relaxation. Fast relaxation induced by RGSF-A was almost blocked by $N_{\omega}$-Nitro-L-arginine methyl ester (L-NAME), a nitric oxide synthase synthase inhibitor and 1H-[1,2,4]oxadiazolo[4,3-a]quinoxalin-1-one (ODQ), a guanylate cyclase inhibitor. However slow relaxation induced by RGSF-A was only partially inhibited by L-NAME and ODQ. In the endothelium-removed ring, RGSF-A evoked only slowrelaxation to a certain extent. These data suggest that RGSF-A induced both endothelium dependent fast- and slow-relaxation and endothelium independent slow-relaxation in the porcine distal LAD coronary artery. The endothelium dependent fast-relaxation is mediated by the nitric oxide (NO)-cGMP pathway, and the endothelium dependent slow-relaxation is at least partially mediated by the NO-cGMP pathway. However, the endothelium-independent slow-relaxation remains to be elucidated.

Vortex dynamics in YBa$_2Cu_3O_7$ single crystals measured by micro Hall-probe array (Micro Hall probe array를 이용한 YBa$_2Cu_3O_7$ 단결정 내부의 자속 운동 측정)

  • Shim, Seong-Yeop;Hwang, Hyeon-Guk;Lee, Chang-Woo;Lee, Tae-Won;Kim, Dong-Ho
    • 한국초전도학회:학술대회논문집
    • /
    • v.9
    • /
    • pp.189-195
    • /
    • 1999
  • We have studied the vortex dynamics in YBa$_2Cu_3O_7$ single crystals with columnar defects using micro Hall-probe array. The Hall-probe array technique allowed a simultaneous measurement of the time and spatial dependence of the vortex density so that more detailed information on flux dynamics could be obtained. We found that field profiles inside sample were similar to the Bean's critical state model from the magnetic hysteresis measurement. Normalized relaxation rates were maximum near the center and decreased toward the edge if applied field H$_{app}$ is greater than the penetration field H. But applied magnetic field H$_{app}$ is less than H, relaxation rates were minimum near the center and increased toward edge. We found that glassy exponent ${\mu}$ has the value of ${\sim}$ 1 whose corresponding vortex motion is half-loop excitation. However, single vortex creep, ${\mu}$ ${\sim}$ 1/7, was also found at 30 K and H$_{app}$ ${\cong}$ H'. Calculation of activation energy, U, was possible from direct analysis of the local relaxation data using the basic diffusion equation. From these results, we found that U increases logarithmically with time and U around center was lower than that at the edge.

  • PDF

Regularized Iterative Image Restoration with Relaxation Parameter (이완변수를 고려한 영상의 정칙화 반복 복원)

  • 홍성용;이태홍
    • The Journal of Korean Institute of Communications and Information Sciences
    • /
    • v.19 no.1
    • /
    • pp.91-99
    • /
    • 1994
  • We proposed the regularized iterative restoration method considering relaxation parameter and regularization paramenter in order to restore the noisy motion-blurred images. We used (i-H) as a regularization operator and these two kinds of constraints were applied while conventional regularization iterative restoration method proposed by Jan Biemond et al used the 2-D Laplacian filter and a predetermined regularization parameter value and relaxation parameter to 1. Through the experimental results, we showed better results compared with those by a conventional method and or regularized iterative restoration method just considering only a regularization parameter. These two kinds of constratints have good effects when applied into the regularized iterative restoration method for noisy motion-blurred images.

  • PDF

NMR Relaxometry of Water in Set Yogurt During Fermentation

  • Mok, Chul-Kyoon;Qi, Jinning;Chen, Paul;Ruan, Roger
    • Food Science and Biotechnology
    • /
    • v.17 no.5
    • /
    • pp.895-898
    • /
    • 2008
  • The mobility of water in set yogurt during fermentation was studied using nuclear magnetic resonance (NMR) relaxometry. The spin-spin relaxation was analyzed using a 2-fraction model, resulting in 2 spin-spin relaxation time constants $T_{21}$ and $T_{22}$. Both $T_{21}$ and $T_{22}$ exhibited rapid changes between 2 and 4 hr of fermentation, coinciding with the drop in pH and the rise in lactic acid bacteria count. The spin-lattice relaxation time $T_1$ increased over the fermentation period. Both $T_1$ and $T_2$ showed an increase in the mobility of water upon gel formation during fermentation. Water redistribution within the gel matrix due to casein aggregation and structure forming may be responsible for the changes in mobility.

A Novel Optimization-Based Approach for Minimum Power Multicast in Wireless Networks

  • Yen, Hong-Hsu;Lee, Steven S.W.;Yap, Florence G.H.
    • Journal of Communications and Networks
    • /
    • v.13 no.1
    • /
    • pp.26-31
    • /
    • 2011
  • In this paper, we formulate the minimum power multicast problem in wireless networks as a mixed integer linear programming problem and then propose a Lagrangean relaxation based algorithm to solve this problem. By leveraging on the information from the Lagrangean multiplier, we could construct more power efficient routing paths. Numerical results demonstrate that the proposed approach outperforms the existing approaches for broadcast, multicast, and unicast communications.

Magnetic Properties of Helicobacter Pylori Ferritins Genetically Prepared Under Different Biomineralization Conditions

  • Son, K.;Park, J.N.;Yoon, Sungwon;Suh, B.J.;Cho, K.J.;Kim, K.H.;Jang, Z.H.
    • Journal of Magnetics
    • /
    • v.21 no.1
    • /
    • pp.20-24
    • /
    • 2016
  • Magnetic properties of bio-magnetic molecule ferritin have been investigated. Two ferritin samples were synthesized under different magnetic fields, 0 and 9.4 T, respectively. This work is focused on the influence of magnetic field on biomineralization process. While magnetization vs. temperature (M-T) data of both samples measured at 1000 Oe are almost identical except for low temperature region (T < 6 K), magnetization vs. field (M-H) data show noticeable difference. From an analysis of M-H data by using a modified Langevin function, we could extract the saturation magnetization $m_0$(T), the effective magnetic moment ${\mu}_{eff}$(T) and the linear susceptibility x(T). The difference between the samples is most prominent in the x(T), whereby the x(T) of the sample prepared at 9.4 T is 1.7 times bigger than that of the other. In addition, from hysteresis and relaxation measurements, we found the sample prepared at 9.4 T showed strikingly smaller coercivity and slower relaxation.