• Title/Summary/Keyword: $^14 C$

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The Synthesis and Crystal Structure of (${\eta}^5-Cp^*$)(Ir-B3)(1,2-S,S($CH_2SiMe_3$)-o-carborane)($C_{16}H_{35}B_{10}IrS_2Si$) ((${\eta}^5-Cp^*$)(Ir-B3)(1,2-S,S($CH_2SiMe_3$)-o-carborane) ($C_{16}H_{35}B_{10}IrS_2Si$)의 합성 및 결정구조)

  • Cho, Sung-Il
    • Korean Journal of Crystallography
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    • v.18 no.1_2
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    • pp.1-6
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    • 2007
  • An Organometallic compound, $C_{16}H_{35}B_{10}IrS_2Si$, was synthesized from o-carborane, $Cp^*Ir(S_2C_2B{10}H_{10})$, and $Me_3SiCHN_2$. The molecular structure of this complex has been determined by X-ray diffraction. Crystallographic data : monoclinic, space group $P2_1/n$, $a=10.1986(12)\;{\AA}$, $b=14.834(5)\;{\AA}$, $c=17.139\;{\AA}$, ${\beta}=92.24(2)^{\circ}$, Z=4, $V=2591.0(14)\;{\AA}^3$. The structure was solved by direct methods and refined by full-matrix leat-squares methods to give a model with a reliability factor R=0.053 for 5080 reflections.

Effects of the Low Temperature and Low Salt Solution on the Quality Characteristics of Salted Chinese Cabbage (저온-저염 절임기술이 절임배추의 품질 특성에 미치는 영향)

  • Lee, Seog-Won;Cho, Sun-Rae;Han, Sung-Hee;Rhee, Chul
    • The Korean Journal of Food And Nutrition
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    • v.22 no.3
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    • pp.377-386
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    • 2009
  • The principal objective of this study was to evaluate the influence of temperature and salt concentration on the physicochemical properties of salted Chinese cabbage. Salted Chinese cabbage samples were prepared with various concentrations of salt(4, 5, 6 and 7%), and were stored for 10 days at three temperatures(8, 14, and $25^{\circ}C$). The salting ratio of Chinese cabbage evidenced a decreasing trend regardless of the salting temperature and salt concentration, and their decrement appeared relatively high as the salting temperature increased. The period required to achieve a critical salting ratio(85%) decreased with increases in the salt concentration at $25^{\circ}C$, and a similar trend was observed at lower temperatures(8 and $14^{\circ}C$). The salinity of all samples evidenced an increasing trend during the salting period, and at $25^{\circ}C$, in particular, a continuous increment was observed. At salt concentrations of 4%, the critical salinity(2.2%) was not achieved regardless of the temperature and salting period. The pH of salted Chinese cabbage achieved critical pH in 3 days at a salting temperature of $25^{\circ}C$, but the critical pH 5.5 of samples at 8 and $14^{\circ}C$ appeared after a long period of approximately 4 to 10 days. The average hardness values of salted Chinese cabbage at a salting ratio of 85% were approximately 1.49 MPa, 1.87 MPa, and 1.97 MPa, respectively, at three temperatures($25^{\circ}C$, $14^{\circ}C$, and $8^{\circ}C$). The initial reducing sugar content of cabbage juice was 11.8 mg/$m{\ell}$, and this value decreased substantially to 3 to 5 mg/$m{\ell}$ on day 1.

Lifespan Extension of Fermented Zizyphus jujuba Fruits in Caenorhabditis elegans (붉은 덕다리버섯 발효 대조(大棗)의 예쁜꼬마선충 수명연장효과)

  • Ji, Byeong-Uk;Park, Sung-Min;Koo, Sungtae;Lim, Byungmook;Yu, Young-Beob
    • Korean Journal of Acupuncture
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    • v.31 no.4
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    • pp.218-224
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    • 2014
  • Objectives : Zizyphus jujuba fruits(ZJF), a traditional Korean medicine has various biological activities such as anti-inflammatory, anti-oxidative and neuro-protective effects. However, it is still unclear whether ZJF has any biological effect on anti-aging. In this study, we examined the effect of ZJF on lifespan and thermal stress in C. elegans. Methods and Results : ZJF water extracts were fermented for 7 days(F7-ZJF) and 14 days(F14-ZJF) by Laetiporus sulphureus to increase secondary metabolites such as aglycone of flavonoids and terpenoids. In the lifespan assay, ZJF water extracts and fermented ZJF were treated on the agar medium plate with age synchronized egg stage of C. elegans. Treatment of F7-ZJF-$200{\mu}g/mL$ with OP-50 E. coli and F14-ZJF-$200{\mu}g/mL$ with OP-50 E. coli significantly increased life span of C. elegans(N2) at thermal stress condition of $25^{\circ}C$. Moreover mRNA levels of lifespan associated HSP 16.1, HSP 70, and HSF-1 were increased at thermal stress condition of $25^{\circ}C$. However, in the equilibration temperature of $20^{\circ}C$ after stress condition of $35^{\circ}C$ for 2 hr, F-14-ZJF-$200{\mu}g/mL$ treatment decreased the levels of heat shock protein in hsp16.2/GFP C. elegans. Conclusions : Our study indicates that prolong role of fermented-ZJF in C. elegans is mediated by control HSPs production.

Effects of Temperature and Salinity on Early Development, Survival and Growth Rate in Seabass, Lateolabrax Japonicus (농어, Lateolabrax Japonicus의 초기 발달, 성장 및 생존율에 미치는 수온과 염분의 영향)

  • 한형균;강덕영;허성범;김성원
    • Journal of Aquaculture
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    • v.14 no.1
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    • pp.17-27
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    • 2001
  • Effects of temperature (10, 12, 14, 16, 18 and 2$0^{\circ}C$) and salinity (22.0, 24.5, 27.0, 29.5, 32.0 and 34.5 ppt) were studied on incubation period, hatching success, survival and growth of alevin and juvenile seabass, L. japonicus. Embryonic development was accelerated with increasing temperature but it was not influenced by salinity. Hatching success was the highest at 14$^{\circ}C$ and 34.5 ppt. Higher temperature also accelerated the development of mouth opening, absorption of yolk and oil globules, and alevin growth. Survival of the 5-day old Juvenile was accelerated in the following order : 14<16<18<20<12$^{\circ}C$. Rearing experiment of the juvenile for 30-day indicated the faster growth at 13, 20 and 27 ppt than at 34 ppt.

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Effects of Aerobic Exercise Program for Obese Elderly Women (비만 여성노인을 위한 유산소 운동프로그램의 적용 효과)

  • Kim, In Hong
    • Korean Journal of Adult Nursing
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    • v.17 no.3
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    • pp.425-434
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    • 2005
  • Purpose: To examine the effects of the aerobic exercise program on changing the body composition, blood lipids and self-esteem of the obese elderly women. Method: A total of 26 obese elderly women(%body fat: over 30%) have been selected for this research[Experimental Group(EG):13, Control Group(CG):13). Walking at a 50% intensity was administered 4 days a week for 14 weeks. The data was analyzed using the SPSS program. Result: The level of % body fat, TC, LDL-C, and %TC/HDL-C in EG was significantly lower than those of the CG after 14 weeks. In addition, the level of HDL-C and self-esteem in EG was significantly higher than those of the CG after 14 weeks. However, TG, body weight between groups didn't appear significant at the end of 14 weeks. Conclusion: The results showed that the aerobic exercise program was effective in changing body composition, blood lipids and self-esteem of the obese elderly women.

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The Clay Mineralogy of some Low Productive Paddy Soils In Kyonggi-Do (경기도(京畿道) 저위생산답(低位生産畓)의 점토광물(粘土鑛物)에 관(關)한 연구(硏究))

  • Shim, Sang Chil;Kim, Tai Soon;Lee, Hyung Koo;Song, Ki Joon;Valencia, I.G.
    • Korean Journal of Soil Science and Fertilizer
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    • v.7 no.3
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    • pp.127-135
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    • 1974
  • The samples were taken from the following localities previously classified as "Akiochi" area: Yangpyung, Puchun, and Pyungtaik, all of Kyonggi-do province. Five soil profiles were described in the field, and taken to the laboratory for physical and chemical analysis and mineralogical analysis by X-ray diffraction. The predominant clay minerals consist mainly of illite, vermiculite, chlorites and intergrade with vermiculite, and kaolinite. Illite or mica was found present in all samples and in all horizons. This was identified by the 9.83 to $10{\AA}$ (0.01) and $3.32{\AA}$ (003) basal reflections, Interhorizontal variations in mineral content and crystallinity are illustrated in their respective Xray diffractogram. Comparing the peak intensity, of the $14{\AA}$, $10{\AA}$ and $7{\AA}$ indicated the degree of weathering from the surface to the lower horizons. In general, the weathering of illite on the surface produced less pronounced $10{\AA}$ and $14{\AA}$ peak as compared to the lower horizons. The same may be said with kaolinite. On K-saturation, the $14{\AA}$ peak broadening on the low angle side was observed. This is interpreted to be due to chlorization. Heat treament from $100^{\circ}C$, $200^{\circ}C$, $400^{\circ}C$, $600^{\circ}C$, and $800^{\circ}C$. caused significant changes in the different diffractograms. Heating caused collasped of the $14{\AA}$ to $10{\AA}$ and the appearance of scattered peaks between $10-14{\AA}$. This is interpreted to the presence of vermiculite chlorite intergradient. The complete collapse of the $14{\AA}$ at $800^{\circ}C$ to $10{\AA}$ with increased intensity was attributed to the preservce of vermiculite. The principal difference among the clay minerals in each horizon is the concomitant increase and decrease in intensity with depth of the $14{\AA}$, $10{\AA}$ and $7{\AA}$ diffraction spacings. Apparently the weathering of illite ($10{\AA}$) is resulting in the formation of vermiculite ($14{\AA}$) and the interstratified material being an intermediate stage and the beginning of the formation of vermiculite. Some broadening- in the 17 to $18{\AA}$ was observed in Puchun-1 Pyungtaik-1 and Pyungtaik-2 specially so in the lower horizon in the Ca or Mg-saturated sample. Heated treatment tend to shift this peak to $14{\AA}$ indicating the presence of regular layering of the interstratified complex. The high amount of extractable aluminum and iron coupled with low exchange capacity indicate that iron and aluminum plays an important role in the weathering of these soils and is responsible to the low exchange capacity, high acidity and high phosphate absorptive capacity. The results presented substantiated the weathering sequence of Jackson in that mica ${\rightarrow}$ vermiculite ${\rightarrow}$ chloritezed vermiculite ${\rightarrow}$ kaolinite.

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Spawning Inducement of Flounder, Paralichthys olivaceus by the Control of Water Temperature and Photoperiod (수온과 광주기 조절에 의한 넙치(Paralichthys olivaceus)의 산란유도)

  • Kim, Yoon;Hur, Sung-Bum
    • Journal of Aquaculture
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    • v.4 no.2
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    • pp.85-95
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    • 1991
  • Spawning inducement of flounder, Paralichthys olivaceus, was attemped by the control of water temperature and photoperiod from June 1, 1989 through January 5, 1990 (189 days) Water temperature was gradually decreased from $21.7^{\circ}C$ to $10.6^{\circ}C$ which was the minim biological temperature for spawning of flounder. Water temperature was increased asain to $15^{\circ}C$ gradually, and then maintained at this level through the end of spawning. Photoperiod was also changed gradually from 10L/14D in June 1, 1989 to 14L/10D in July 25, 1989. Spawning of the fish occurred from October 4, 1989 through January 5, 1990 (93 days). The average number of eggs spawned during the spawning season per female were 2.67 billion. The first spawning occurred on the 60th day after the time of minimun water temperature $10.6^{\circ}C$. The water temperature and photoperiod at the first spawning were $13^{\circ}C$ and 14L/10D respectively It took 71 days to spawn since the photoperiod had changed from 10L/14D to 14L/10D. Spawning period can be devided into three terms. The first term was continued for 30 days from the beginning of the spawning. The second term for 41 days was the major spawning period followed by the third term, the final period of the spawning, for 22 days. The percentage of average fertilization rate of the eggs in the first, second and third spawning terms were $37.4{\%},\;54.1\%\;and\;19.6\%$, respectively. Feeding rate was increased in the maturing period but, decreased in the spawing period. During the final spawning period, the abrubt decreasing of the feeding occurred again.

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Physiological Response of the Pearl Oyster, Pinctada fucata martensii, to Low Water Temperature: a Preliminary Study for Indoor Overwintering (진주조개 Pinctada fucata martensii의 실내월동을 위한 저온노출에 따른 생리적 변화)

  • Lee, Jeong-Mee;Lee, Sang-Won;Cho, Sang-Man
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.43 no.1
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    • pp.54-62
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    • 2010
  • With the aim of developing and indoor overwintering technique for Pearl oyster, Pinctada fucata martensii, the metabolic rates of young oysters (52.4-83.0 mm in shell length) were measured for 2 weeks at water temperatures of 8, 10, 12, and $14^{\circ}C$. The filtration rate (FR) ranged 0 to $4.84\;L\;h^{-1}gDW^{-1}$ (mean, $0.02{\pm}0.06 $ to $3.12{\pm}1.45$), with significant changes observed over thme except for the case of a water temperature of $14^{\circ}C$. Respiration rate (R) ranged from 0 to $2.370\;mgO2\;h^{-1}gDW^{-1}$ (mean, 0 to $1.77{\pm}0.37$), with significant respiratory disorders observed at temperatures below $12^{\circ}C$; in contrast, the rate increased on the $14^th$ day of the experiment in the case of a temperature of 14$^{\circ}C$. No significant difference was observed among the different water temperatures in terms of excretion rate (E) or absorption efficiency (Abs.eff), except for a significant decrease in aerobic metabolism in the case of water temperature of $8^{\circ}C$. The estimated scope for growth (SFG) ranged from -9.1 to $126.9\;J\;h^{-1}gDW^{-1}$ (mean. $-4.1{\pm}2.6$ to $82.85{\pm}42.6$). A significant energy Joss was found at $8^{\circ}C$, with negative SFG observed throughout the experiment and a gradual energy decrease observed over time at water temperatures of $10^{\circ}C$ and 120C. However. SFG remained positive throughout the experiment in the case of $14^{\circ}C$. The estimated minimum energy requirement, assessed from energy expenditure, is $8.00-34.24\;J\;h^{-1}gDW^{-1}$ (mean, $17.67{\pm}6.17$). In conclusion, the lowest temperature suitable for indoor overwintering is above $14^{\circ}C$.

Effect of Night Minimum Temperature During Winter Season on Growth and Flowerng in Chrysanthemum 'Baekma' (국화 '백마'의 겨울철 재배시 야간최저온도가 생장과 개화에 미치는 영향)

  • Choi, Seong Youl;Hur, Eun Joo;Kwon, Oh Geun;Lim, Jin Hee
    • FLOWER RESEARCH JOURNAL
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    • v.17 no.4
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    • pp.226-230
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    • 2009
  • To investigate the effect of night minimum temperature on growth and flower development in standard type chrysanthemum 'Baekina' during winter season, morphological characteristics and physiological disorders were compared with standard chrysanthemum 'Jinba'. Although the flower budding of 'Baekma' was delayed about 2 to the days compared with 'Jinba', the days to flowering of 54 to 59 showed no difference between the two cultivars. Flowering was delayed as minimum temperature decreased at night. The length and weight of cut flower decreased in the two cultivars as minimum temperature increased at night. In 'Baekina', the number of petals at 16 showed the highest values among other temperatures. Whereas there was no significant difference among the temperature treatments in 'Jinba'. Rosette occured only in 'Baekma', and the ratio was 11.1% at 14, 55.6% at 16, and 56.1% at 18. The inhibition of flower budding appeared only at 14 in the ratio of 17.3% in 'Baekma' and 4.0% in 'Jinba'.

Synthesis of SiC Nanotube by CNT-confined Reaction (CNT-confined reaction에 의한 탄화규소 나노튜브의 합성)

  • Rho Dae-Ho;Kim Jae-Soo;Byun Dong-Jin;Yang Jae-Woong;Kim Na-Ri
    • Korean Journal of Materials Research
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    • v.14 no.3
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    • pp.175-180
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    • 2004
  • SiC nanotubes were synthesized by CNT-confined reaction. Evaporated SiO gas reacted with carbon nanotubes by VS growth mechanism. By confineded reaction, carbon nanotube was changed to SiC nanotube, and synthesized SiC nanotube was filled partly by the gas reaction in the nanotubes. SiC nanotube's mean diameters were not changed than carbon nanotubes because of means ratio of $CO_2$ and SiO gas was maintained evenly during the process. This result was same of data of simulation. By TEM observastion, SiC nanotube was filled by reaction of inner wall of CNT and SiO gas through the VS reactions. Converted SiC nanotube's compositions were revealed Si and C of 1: 1 ratios at all sites of nanotube by EDS.