• Title/Summary/Keyword: $^{64}Cu$

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A Study of Optimization of Electrodeposited CuSnZn Alloys Electrolyte and Process

  • Hur, Jin-Young;Lee, Ho-Nyun;Lee, Hong-Kee
    • Journal of the Korean institute of surface engineering
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    • v.43 no.2
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    • pp.64-72
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    • 2010
  • CuSnZn electroplating was investigated as alternative to Ni plating. Evaluation of electrolyte and plating process was performed to control physical characteristics of the film, and to collect practical data for application. Hull-cell test was conducted for basic comparison of two commercialized products and developed product. Based on hull-cell test results, long term test of three electrolytes was performed. Various analysis on long term tested electrolyte and samples have been done. Reliable and practical data was collected using FE-SEM (FEI, Sirion), EDX (ThermoNoran SIX-200E), ICP Spectrometer (GBC Scientifi c, Integra XL), FIB (FEI, Nova600) for anlysis. Physical analysis and reliability test of the long term tested film were also carried out. Through this investigation plating time, plating speed, electrolyte composition, electrolyte metal consumption, hardness and corrosion resistance has been compared. This set of data is used to predict and control the chemical composition of the film and modify the physical characteristics of the CuSnZn alloy.

Microstructure and Toughness of Weld Heat-Affected Zone in Cu-containing HSLA-100 steel (Cu를 함유한 HSLA-100강 용접 열영향부의 미세 조직 및 인성)

  • Park, T.W.;Shim, I.O.;Kim, Y.W.;Kang, C.Y.
    • Journal of the Korean Society for Heat Treatment
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    • v.8 no.1
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    • pp.53-64
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    • 1995
  • A study was made to characterize the microstructures and mechanical properties of the base metal and the heat-affected zone(HAZ) in Cu-bearing HSLA-100 steel. The Gleeble thermal/mechanical simulator was used to simulated the weld HAZ. The relationship between microstructure and toughness of HAZ was studied by impact test, O. M, SEM, TEM, and DSC. The toughness requirement of military specification value was met in all test temperatures for the base metal. The decrease of HAZ toughness comparing to base plate is ascribed to the coarsed-grain and the formation of bainite. Obliquely sectioned Charpy specimens show that secondary crack propagate easily along bainite lath. Improved toughness(240J) at HAZ of $Tp_2=950^{\circ}C$ is due to the fine grain, and reasonable toughness(160~00J) in the intercritical reheated HZA is achieved by the addition of small amount of carbon which affects the formation of "M-A". Cu precipitated during ageing for increasing the strength of base metal is dissolved during single thermal cycle to $1,350^{\circ}C$ and is precipitated little on cooling and heating during subsequent weld thermal cycle. Thus, the decrease of toughness does not occur owing to the precipitation of Cu.

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Retarding Effect of Transferred Graphene Layers on Intermetallic Compound Growth at The Interface between A Substrate and Pb-free Solder (기판과 무연솔더 계면에 전사된 그래핀 층의 금속간화합물 성장 지연 효과)

  • Yong-Ho Ko;Dong-Yurl Yu
    • Journal of the Microelectronics and Packaging Society
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    • v.30 no.3
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    • pp.64-72
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    • 2023
  • In this study, after transferring graphene on a Cu substrate and printing a Sn-3.0Ag-0.5Cu Pb-free solder paste on the Cu substrate, effects of the transferred graphene on formations and growths of intermetallic compound (IMC) at the interface between the Cu substrate and the solder were reported during processes of reflow soldering and isothermal aging for 1000 h with various temperatures (125, 150, and 175 ℃). Thicknesses of Cu6Sn5 and Cu3Sn IMCs at the interfaces with graphene were decreased during the reflow soldering and isothermal aging processes compared to those without graphene. The transferred graphene layers also showed that the growth rate constant and square of growth rate constant which related to the growth mechanisms of Cu6Sn5 and Cu3Sn IMCs with t he t emperature a nd t ime of t he i sothermal aging c ould dramatically decreased.

신안동전성분분석에 관한 연구(I)

  • Lee, Chang-Keun;Kang, Dae-III;Hwang, Chae-Geum
    • 보존과학연구
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    • s.6
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    • pp.121-196
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    • 1985
  • Atomic absorption spectrophotometer was used for analyzing each 10elements(Cu, Pb, Sn, Zn, Sb, Fe, Ni, Ag, Co and Mn)on 64 Chinese coinsre covered from Shinan seabed sunken ship. The results show that Cu, Pb and Sn were found to be a major elements consisting of coins and its composition ratio was 6 to 2 to 1.The composition of trace elements on coins was classified 3 levels : Sb, Fe and Zn(0.02%-2.2%), Ag, Ni, and Co(50 ppm-5500 ppm) and Mn(Trace). Theam ount of major elements, Cu and Sn were decreased while increased in Pbby the passage of ages (10th - 13th century) in China. There seems to be no systematic compositional change in major elements but content in trace elements was confirmed to increase with age.

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Effect of Reinforcement Content on Damping Capacities for Castable Aluminum Matrix Composites Reinforced with SiC and Graphite Particles (SiC와 흑연 입자 강화 주조용 Al기지 복합재료의 진동감쇠능에 미치는 강화입자조성의 효과)

  • 최유송
    • Journal of the Korea Institute of Military Science and Technology
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    • v.7 no.1
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    • pp.47-58
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    • 2004
  • Loss factors of A356, Mn-Cu alloy and aluminum matrix composites reinforced with $SiC_p$ and Ni-coated graphite particles at various contents have been investigated using clamped-free cantilever beam method. The loss factors of half-power bandwidth of the specimens were measured over a wide range of frequencies from 50 to 3300Hz. Among the specimens, Al-10%$SiC_p$-10%$C_p$ showed the highest loss factor at the mode I, while Mn-Cu alloy showed the highest loss factors at the modes II and III. Consequently, at the mode I the Al-10%$SiC_p$--10%$C_p$ showed the loss factor of 0.00093, which is 2.64 and 1.58 times higher than those of A356 and Mn-Cu alloy, respectively.

Pb, Cu, Zn Contaminants and Their Correlation of Soil, Leave and Bark of Ginkgo. B and Ambient Air Adjacent to a Heavy Traffic Road Side (교통량 과밀 도로주변의 토양과 가로수, 대기중 Pb, Cu, Zn 중금속 농도와 그 상관성에 관한 연구)

  • 박기학
    • Journal of Environmental Health Sciences
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    • v.18 no.2
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    • pp.19-25
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    • 1992
  • The study was carried out to investigate the correlation between the heavy metals emitted by the motor vehicles with the heavy traffic road side environment (soil, leave, bark, ambient air). The Pb, Cu, Zn contents in road side soil sand leaves, barks from Ginkgo, biloba and ambient air adjacent to the heavy traffic road side from June to August, 1992 Suwon city were analyzed by Atomic absorption spectrometry and Inductively coupled plasma emission spectrophotometry. The results were as follows: 1) The high levels of heavy metals concentration were Pb, at city-terminal in soil (186 $\mu$g/g), Cu, at city-terminal in soil (221 $\mu$g/g), Zn, at city-terminal in ambient air (252 $\mu$g/m$^{3}$). 2) The low leves of heavy metals concentration were Pb, at North-gate in ambient air (1.65$\mu$g/m$^{3}$), Cu, at North-gate in ambient air (4 $\mu$g/m$^{3}$), Zn, at North-gate in ambient air (15.31$\mu$g/m$^{3}$). 3) The regional distribution of Pb, Cu, Zn in road side soils, leaves and barks from Ginkgo, biloba, ambient air show high levels in turn, city4erminal, Guan Sean Dong, South gate, North gate. 4) The concentration of heavy metals (Pb, Cu, Zn) in soils, leaves, barks, ambient air was highly correlated with the traffic volume of the sampling sites (r=0.64~0.96). To conclude that the high levels of Pb, Cu, Zn contaminations were positively related to motor vehicles-borne pollutants and road side soils, trees, ambient air adjacent to a high density building area with low road coverage and heavy traffic volume were reflected strongly by the hazardous pollutants emitted by motor vehicles.

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Microstructure and Tensile Strength Property of Arc Brazed DP steel using Cu-Sn Insert Metal (Cu-Sn 삽입금속을 이용한 DP강의 아크 브레이징 접합부의 미세조직과 인장특성)

  • Cho, Wook-Je;Cho, Young-Ho;Yun, Jung-Gil;Kang, Chung-Yun
    • Journal of Welding and Joining
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    • v.31 no.1
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    • pp.58-64
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    • 2013
  • The following results were obtained, microstructures and tensile properties in arc brazed joints of DP(dual phase) steel using Cu-5.3wt%Sn insert metal was investigated as function of brazing current. 1) The Fusion Zone was composed of ${\alpha}Fe+{\gamma}Cu$ and Cu23Sn2. The reason for the formation of these solid solutions. Despite, Fe & Cu were impossible to solid solution at room temperature. It's melting & reaction to something of insert metal & Base Metal (DP Steel) by Arc. Brazing Process has faster cooling rate then Cast Process, Supersaturated solid solution at room temperature. 2) The increase Hardness of Fusion Zone was directly proportional to the rise of welding current. Because, ${\alpha}Fe+{\gamma}Cu$ phase (higher hardness than the Cu23Sn2.(104.1Hv < 271.9Hv)) Volume fraction was Growth, due to increasing the amount of base metal melting by High current. 3) The results of tensile shear test by Brazing, All specimens happen to fracture in Fusion Zone. On the other hand, when Brazing Current increasing tend to rise tensile load. but it was very small, about 26-30% of the base metal. 4) The result of fracture analysis, The crack initiate at Triple Point for meet to Upper B.M/Under B.M/Fusion Zone. This Crack propagated to Fusion zone. So ruptured by tensile strength. The Reason to in the fusion zone fracture, Fusion zone by Brazing of hardness (strength) was very lower then the base metal (DP steel). In addition the Fusion Zone's thickness in triple point was thin than the base metal's thickness in triple point.

Preparation and Gas Permeation Performance of Pd-Ag-Cu Hydrogen Separation Membrane Using α-Al2O3 Support (α-Al2O3 지지체를 이용한 Pd-Ag-Cu 수소 분리막의 제조 및 기체투과 성능)

  • Sung Woo Han;Min Chang Shin;Xuelong Zhuang;Jae Yeon Hwang;Min Young Ko;Si Eun Kim;Chang Hoon Jung;Jung Hoon Park
    • Membrane Journal
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    • v.34 no.1
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    • pp.50-57
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    • 2024
  • In this experiment, Pd-Ag-Cu membrane was manufactured using electroless plating on an α-Al2O3 support. Pd, Ag and Cu were each coated on the surface of the support through electroless plating and heat treatment was performed for 18 h at 500℃ in H2 in the middle of electroless plating to form Pd alloy. The surface of the Pd-Ag-Cu membrane was observed through Scanning Electron Microscopy (SEM), and the thickness of the Pd membrane was measured to be 7.82 ㎛ and the thickness of the Pd-Ag-Cu membrane was measured to be 3.54 ㎛. Energy dispersive X-ray spectroscopy and X-ray diffraction analysis confirmed the formation of a Pd-Ag-Cu alloy with a composition of Pd-78wt%, Ag-8.81wt% and Cu-13.19wt%. The gas permeation experiment was conducted under the conditions of 350~450℃ and 1~4 bar in H2 single gas and H2/N2 mixed gas. The maximum H2 flux of the hydrogen separation membrane measured in H2 single gas is 74.16 ml/cm2·min at 450℃ and 4 bar for the Pd membrane and 113.64 ml/cm2·min at 450℃ and 4 bar for the Pd-Ag-Cu membrane. In the case of the separation factor measured in H2/N2 mixed gas, separation factors of 2437 and 11032 were measured at 450℃ and 4 bar.

동전선의 열열화에 의한 특성변화 분석

  • 최충석;김향곤;김혁수
    • Proceedings of the Korean Institute of Industrial Safety Conference
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    • 2000.11a
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    • pp.64-67
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    • 2000
  • 옥내전선의 도체재료로 주로 동(CU)이 사용되고 있으며, 절연재료로는 염소(Cl)를 주성분으로 한 콤파운드가 사용되고 있다. 전선을 장시간 사용하게 되면 전기적, 열적, 기계적, 환경적 요인 등에 의해 열화가 진행되며, 도체 및 절연물의 열분해, 산화, 뒤틀림 등에 의한 특상저하로 전기설비 및 전기기기에 재해를 유발하게 된다.(중략)

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