• Title/Summary/Keyword: $^{63}Ni$

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Pore Structure and Mechanic:11 Property of Porous TiNi Biomaterial Produced by Self-Propagating High-Temperature Synthesis (고온자전합성법으로 제조된 다공성 TiNi 생체재료의 기공구조 및 기계적 특성)

  • 김지순;강지훈;양석균;정순호;권영순
    • Journal of Powder Materials
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    • v.10 no.1
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    • pp.34-39
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    • 2003
  • Porous TiNi bodies were produced by Self-propagating High-temperature Synthesis (SHS) method from a powder mixture of Ti and Ni. Porosity, pore size and structure, mechanical property, and transformation temperature of TiNi product were investigated. The average porosity and pore size of produced porous TiNi body are 63% and $216\mutextrm{m}$, respectively. XRD analysis showed that the major phase of produced TiNi body is B2 phase. Its average fracture strength and elastic modulus measured under dry condition were $22\pm2$ MPa and $0.18\pm0.01$GPa, respectively. It could be strained up to 7.3 %. The transformation temperatures determined by DSC showed the $M_s$ temperature of $67^{\circ}C$ and $A_f$ temperature of $99^{\circ}C$.

Mineralogy of Garnierite from New Caledonian Ni Lateritic Ore (뉴칼레도니아 니켈 라테라이트 광석 내 가니어라이트의 광물학적 특징)

  • Cho, Hyen-Goo;Kim, Soon-Oh;Kim, Sang-Bae
    • Journal of the Mineralogical Society of Korea
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    • v.24 no.4
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    • pp.253-263
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    • 2011
  • Mineralogical characteristics of garnierite ores from the Nakety, Kouaoua, and Ouaco Ni laterite deposits in New Caledonia are investigated using optical microscopy, powder X-ray diffractometer, and electron proble microanalyzer. Green garnierite ores have colloform, cellular, and boxwork texture, which are formed by precipitation under low temperature surface environment. They are mainly composed of Ni-bearing talc~willemseite series mineral and partly of lizardite. In Ni-bearing talc~willemseite series mineral, NiO contents are Ouaco (average 40.63%), Nakety (average 28.58%), and Kouaoua (average 24.90%), in descending order. Ni atomic percentage replacing Mg in octahedral site are 43.5~85.0%. Dark brown garnierite ores show cellular or boxwork texture, and consist of lizardite~Ni lizardite with some Ni-bearing talc~willemseite series mineral. Ni contents in lizardite~Ni lizardite are 1.14~4.06 wt. % and Ni atomic percentage replacing Mg in octahedral site 1.7~6.8%. Low NiO content in dark brown garnierite attributes to high Fe content replacing Mg in octahedral site.

Study on Thermal Stability of Ni-P-Fe and Ni-P-B Layers Electroplated on Alloy 600 (Alloy 600에 전기 도금한 Ni-P-Fe 및 Ni-P-B 층의 열적 안정성 연구)

  • Kim, Myong-Jin;Kim, Joung-Soo;Kim, Dong-Jin;Kim, Hong-Pyo
    • Journal of the Korean institute of surface engineering
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    • v.43 no.2
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    • pp.57-63
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    • 2010
  • In this study, thermal stability of the mechanical properties of Ni-P-B and Ni-P-Fe layers electroplated on Alloy 600 material was evaluated by measuring their microhardness, tensile strength, and elongation after heat treatment at $325^{\circ}C$ and $400^{\circ}C$. According to the results, there was no noticeable change in microhardness of the two electrodeposits before and after heat treatment at the temperatures for 30 days. In the case of a Ni-P-B electrodeposit, ultimate tensile strength (UTS) slightly increases with heat treatment time, while its elongation decreases, showing good thermal stability in the mechanical properties at high temperature. On the other hand, UTS and elongation of Ni-P-Fe decrease with heat treatment time, which is very unusual observation. This result was attributed to the bad microstructure of Ni-P-Fe having many defects in the deposit formed early stage of an electroplating process and their redistribution to link to become large ones during heat treatment.

Chemical Speciation of Heavy Metals in Soils of Jeju Island, Korea (제주도 토양 중 중금속의 화학적 형태)

  • Hyun, Sung-Su;Kim, Se-Ra;Lee, Min-Gyu;Kam, Sang-Kyu
    • Journal of Environmental Science International
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    • v.26 no.7
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    • pp.847-858
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    • 2017
  • For 26 soil series distributed more than 1% among 63 soil series in Jeju Island, natural uncultivated soil samples were collected. For these soils, the chemical speciation of eight heavy metals (Cd, Cr, Cu, Mn, Ni, Pb, V, and Zn) was examined. Further, the Plant Bioavailability (PB) and Mobility Factor (MF) of these heavy metals were evaluated using Tessier's 5-step sequential extraction method (exchangeable, carbonate, reducible (bound to Fe/Mn oxides), oxidizable (bound to organic matter), and residual fraction). The main form present was residual fraction for Cd and Zn; residual and oxidizable fractions for Cr, Cu, Ni, and Pb; reducible fraction for Mn; and carbonate fraction for V. The average plant availability and average mobility factor were found to be V (57.37%) > Zn (12.49%) > Cd (11.76%) > Cu (11.19%) > Pb (9.37%) > Cr (9.09%) > Mn (3.13%) > Ni (2.63%), and Mn (61.04%) > V (59.94%) > Zn (31.54%) > Cd (17.65%) > Cr (15.66%) > Ni (13.89%) > Pb (13.80%) > Cu (13.53%), respectively.

A Numerical Study on the Effectiveness Factor of Ni Catalyst Pellets for Steam-Methane Reforming (수증기-메탄개질용 Ni 촉매의 유용도에 관한 수치적 연구)

  • Choi, Chong-Gun;Nam, Jin-Hyun;Shin, Dong-Hoon;Jung, Tae-Yong;Kim, Young-Gyu
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.11a
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    • pp.63-66
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    • 2007
  • Reformers which produce hydrogen from natural gas are essential for the operation of residential PEM fuel cells. For this purpose, steam-methane reforming reactions with Ni catalysts is primarily utilized. Commercial Ni catalysts are generally made to have porous pellet shapes in which Ni catalyst particles are uniformly dispersed over Alumina support structures. This study numerically investigates the reduction of catalyst effectiveness due to the mass transport resistances posed by porous structures of spherical catalyst pellets. The multi-component diffusion through porous media and the accurate kinetics of reforming reaction is fully considered in the numerical model. The preliminary results on the variation of the effectiveness factor according to different operation conditions are presented, which is planned to be used to develop correlations in future studies.

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Electroforming of Nickel-iron alloy and Iron (Ni-Fe 및 Fe 정밀 전주성형에 관한 연구)

  • Lee, Heung-Ryeol;Park, Jae-Yeong;Kim, Gyun-Tak;Kim, Ho-Hyeong;Hwang, Tae-Jin
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2011.05a
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    • pp.63-64
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    • 2011
  • 니켈 알러지를 일으키지 않는 전주 부품 개발을 위해 Ni을 대체할 수 있는 전주 소재로 Ni-Fe 합금과 Fe에 대한 전주 공정을 개발하였다. Ni-Fe 합금 전주의 경우 전주품의 표면 내식성 강화를 위해 Cr 나노입자를 이용한 복합전주를 실시하여, Ni 전주품과 내부식성, 니켈 용출 비교 분석 실험을 하였다. 또한 Ni을 완전히 배제하기 위해 새로운 시도로서 순 Fe 전주 공정 기술을 개발하였다. 제조된 Fe 전주품의 내식성 향상을 위한 실리카 코팅 등의 표면처리에 대한 효과도 분석하였다.

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