• Title/Summary/Keyword: $^{36}Cl$

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Genital Organs and Gonad Development of Metapenaeopsis dalei (Penaeidae: Decapoda) in Korean Waters (산모양깔깔새우 (Metapenaeopsis dalei)의 생식기와 생식소 발달)

  • CHOI Jung Hwa;KIM Jae-Won;KIM Jung Nyun;CHA Hyung Kee;HONG Sung Yun
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.36 no.6
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    • pp.619-624
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    • 2003
  • Genital organs and gonad development in kishi velvet shrimp (Metapenaeopsis dalei) were studied based on morphological and histological observations. The samples were collected monthly around the Ochongdo area on the western coast of Korea, from April 1997 to December 1998. Thelycum appear structurally complete after females reach a length of about 12.0 mm CL. Petasma rarely Join after males reach a length of 10.6 mm CL and a fully developed petasma shows up to a length of 12.0 mm CL. The ovaries lie on the dorsal side of the female shrimps thorax. The ovary cavity is located below the heart and above the hepatopancreas. The anterior part of the ovary is round and fused, and the posterior part shows a pair of tubule-like structures. Testes are bilaterally symmetrical, the anterior part shows a convoluted tubule, and the posterior part consists of a pair of tubules. In histological observations, ripe eggs and spermatozoon show when mature females and males reach a length of about 12.0 mm CL.

Metal-Nitrosyl Complexes (I) Synthesis and Characterization of Dinitrosylmolybdenum (O) Complexes (금속-니트로실 착물 (제 1 보) 디니트로실몰리브덴(O) 착물의 합성과 특성)

  • Oh Sang-Oh;Mo Seong-Jong
    • Journal of the Korean Chemical Society
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    • v.36 no.5
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    • pp.661-668
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    • 1992
  • The polymeric compound [{Mo(NO)_2Cl_2}n] was prepared by reductive nitrosylation of NaNO_2 and acidified FeSO_4 with MoCl_5. The reactions of [{Mo(NO)_2Cl_2}n] with unidentate and bidentate ligands afforded neutral monomeric $[Mo(NO)_2Cl_2L_2(or L-L)] in high yield (80∼90%). 3,5-Lutidine, {\gamma}-Cyanopyridine, 1,2-Phenylenediamine, 1,10-Phenanthroline, sym-Diphenylethylenediamine, 9,10-Phenanthrenequinone, 1,3-Bis(diphenylphosphino)propane and 8-Hydroxyquinoline were used as coordinating ligands. The preparation and characterization of these dinitrosylmolybdenum complexes by elemental analysis, 1H NMR, infrared, and UV-Visible spectroscopy are reported. The infrared spectra indicate that in all of the compounds prepared, the NO groups occupy cis-positions in the octahedral group of ligands.

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An ESR Study of Amino Acid and Protein Free Radicals in Solution Part VI. Enzymatic Inactivation of Lysozyme in Aqueous Solution Resulting from Exposure to $Ti-H_2O_2$ System and Gamma-Irradiation

  • Hong, Sun-Joo;Piette, L.H.
    • Journal of the Korean Chemical Society
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    • v.16 no.2
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    • pp.80-83
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    • 1972
  • The activity change of lysozyme resulted from its exposure to $Ti-H_2O_2$system in aqueous liquid at room temperature and to ${\gamma}$-irradiation in ice at $195^{\circ}K$ has been measured at room temperature with a Cary-14 spectrophotometer. The enzymatic activity of lysozyme which had been added to a previously flow-mixed solution of $TiCl_3$ and $H_2O_2$ (System I) was compared with the activity of a lysozyme-$H_2O_2$ solution after flow-mixing with $TiCl_3$ (System II), considering the differences between these two activity changes as the extent of the enzymatic inactivation by the involvement of OH radical reaction. The fraction of lysozyme inactivated by OH radical in the system containing 0.0025 M $TiCl_3-0.1M$ $H_2O_2$ (ph 3.5) was 13%, When the $TiCl_3$ concentration is double (pH 3.0), the fraction of enzyme inactivated increases to 36%. The activity of the system containing 0.025 M $TiCl_3-0.1$ M $H_2O_2$ (pH 1.5) was essentially zero. The results seem to support the previos view that the production of OH radical should be proportional to $TiCl_3$ concentration when $H_2O_2$ is present in excess. Increase in the extent of inactivation found in system I with increasing $TiCl_3$ concentration may be due to a pH effect. $H_2O_2$ seems to be less effective than $TiCl_3$ in the inactivation. 1% lysozyme solution, when ${\gamma}$-irradiated with a total dose of 3M rads, loses about 20% of its activity. Lowering of temperature also was found to yield a reduction in enzymatic activity.

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Studies on Chromatographic Behaviors of the Metal Complexes by Various Eluents (용리제의 종류에 따른 금속착물의 크로마토그래피적인 거동에 관한 연구)

  • Chang Eon Oh;Doo Cheon Yoon
    • Journal of the Korean Chemical Society
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    • v.31 no.1
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    • pp.31-36
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    • 1987
  • We examined eluting behaviors for cationic complexes with the eluting cations. Retention volumes of hydrophilic complexes when eluted by the high concentration of aqueous KCl, NaCl and $NH_4Cl solutions, have been increased in the order NH_4^+ > Na^+ > K^+$, but in the low concentration, retention volumes of hydrophilic complexes bave been increased in the order $Na^+ > NH4^+ > K^+$. On the order hand, retention volumes of hydrophobic complexes when eluted by aqueous KCl, NaCl and $NH_4Cl solutions, have been increased in the order NH_4^+ > Na^+ > K^+$ in the whole concentration range. And we examined eluting behaviors for cationic complexes with the eluting anions. Hydrophilic complexes were associated more strongly with chloride ion among halide ions. However, hydrophobic complexes were associated more strongly with iodide ion. Sulfate ion, a highly hydrated anion, was associated more strongly with hydrophilic complexes than with hydrophobic complexes.

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Preparation of Nano-sized Pt Powders by Solution-phase Reduction (액상환원법(液相還元法)에 의한 백금(白金) 나노분말(粉末) 제조(製造))

  • Kim, Chul-Joo;Yoon, Ho-Sung;Cho, Sung-Wook;Sohn, Jung-Soo
    • Resources Recycling
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    • v.16 no.5
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    • pp.36-40
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    • 2007
  • Platinum plays an important role in many applications because of its extraordinary physical and chemical properties. All these applications require the use of platinum in the finely divided state. Therefore the preparation of platinum nanoparticles by reducing platinum-surfactant salt with reducing agent in the solution was investigated in this study. The net interaction between C14TABr and $H_2[PtCl_6]$ in aqueous solution results in the formation of $[C14TA]_2[PtCl_6]$. The concentration of C14TABr and the concentration of $H_2[PtCl_6]$ has to be above cmc and 0.32 mM, respectively in order to obtain complex-micelle aggregation for mono dispersed Pt particles. Pt particle size increases with increasing $H_2[PtCl_6]$ and C14TABr concentration. And the shape of Pt particles was well controlled with increasing surfactant concentration.

Condition of Processing and Change of Chemical Composition on the Salted-dried Sardine during the Storage (정어리 염건품의 제조 조건과 저장중의 성분변화)

  • JEONG Hae-Kyung;PARK Yeung-Ho
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.16 no.3
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    • pp.231-238
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    • 1983
  • An investigation on optimum condition for processing of salted-dried sardine and quality change of the product during the storage was carried out. The fillets of sardine were salted in 5, 10 and $15\%$ NaCl solution for 12, 24 and 36 hours at $9-10^{\circ}C$, respectively and air-blast dried at $24-25^{\circ}C$ with a velocity of 3 m/sec and then stored at room temperature for 30 days. The results were as follows : The optimum condition for the product was salting in $15\%$ NaCl solution for 36 hours as VBN and histamine contents were 27.5 mg/100g and 42.5 mg/100g, respectively, and also showed a good result in sensory evaluation. Histamine, VBN and TMA-N content of the dried fillets immediately after salting in $15\%$ NaCl solution for 36 hours increased to 47.8 mg, 29.5 mg and 5.4mg per 100g of the sample, respectively and increased slowly during the storage. The peroxide value and acid value of the lipid extracted from the product increased from 15.9 meq/kg to 114.0 meq/kg, and 12.6 to 30.5 during the storage. In the fatty acid composition, $C_{22:6}\;and\;C_{20:5}$ acids were decreased during the storage period.

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Differences of Nutrient Input by Throughfall, Stemflow and Litterfall between Deciduous Forest and Larix kaempferi Plantation in Mt. Joonwang, Kangwon-do (강원도 중왕산 지역 낙엽활엽수림과 낙엽송 조림지에서 수관통과우와 수간류 및 낙엽낙지에 의한 양분 유입의 차이)

  • Jung, Mun-Ho;Lee, Don-Koo;Um, Tae-Won
    • Korean Journal of Soil Science and Fertilizer
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    • v.40 no.2
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    • pp.136-144
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    • 2007
  • The objectives of this study were to compare nutrient input by throughfall, stemflow and litterfall and concentration of nutrient in soil water between deciduous forest stand and Larix kaempferi plantation at Mt. Joongwang, Pyongchang-gun, Gangwon-do. The amount of rainfall interception during study period in deciduous forest stand and L. kaempferi plantation was 12% and 36%, respectively. Concentrations of cation ($Na^+$, $Mg^{2+}$, $K^+$ and $Ca^{2+}$) in throughfall were not different, while concentration of $Cl^-$ in stemflow was higher in L. kaempferi plantation. The results indicated that annual nutrient inputs by rainfall with the exception of $Cl^-$ were significantly greater in deciduous forest stand. In soil water, concentrations of anion ($Cl^-$, $NO_3{^-}$ and $SO{_4}^{2-}$) in A-layer, and $Ca^{2+}$ and $Cl^-$ in B-layer were higher in L. kaempferi plantation. Litterfall input during study period was $2,589kg\;ha^{-1}$ in deciduous forest stand and $1,046kg\;ha^{-1}$ in L. kaempferi plantation. Concentration of N was higher in L. kaempferi plantation, while N input from litterfall was greater in the deciduous forest stand ($36.81kg\;ha^{-1}yr^{-1}$) than L. kaempferi plantation ($16.16kg\;ha^{-1}yr^{-1}$). $Na^+$, $Mg^{2+}$, $K^+$ and $Ca^{2+}$ in litterfall collected from deciduous forest stand were found to be higher than those from the L. kaempferi plantation. Also, input of those were greater in deciduous forest stand. Thus, total nutrient input by throughfall, stemflow and litterfall was greater in deciduous forest stand than L. kaempferi plantation, significantly.

Increased Alcohol Decomposition Efficacy of Hoveina dulcis Extract by Carbohydrate-Hydrolyzing Enzymes (당 분해 효소를 이용한 헛개나무 열매 추출물이 알코올 분해에 미치는 영향)

  • Lee, Kyung-Seok;Kim, Ae-Jung;Lee, Ki-Young
    • Journal of the East Asian Society of Dietary Life
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    • v.22 no.4
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    • pp.473-479
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    • 2012
  • In this study, increased alcohol decomposition efficacy (ADH) of Hoveina dulcis extract by Carbohydrate-Hydrolyzing Enzymes was investigated. Carbohydrate decomposition enzymes such as Maxinvert (Invertase), Optidex L-400 (Glucoamylase) and Rohament CL (Cellulase & Pectinase) were added to Hoveina dulcis extract at different concentrations (0.01, 0.05, 0.1, 0.5 and 1%) for 48 hrs, after which samples were taken every 6 hrs for determination of ADH activity. As the enzyme concentration became higher, ADH activity also increased. Especially, the addition of 1% Rohament CL increased enzyme activity to 76% at 30 hrs incubation, after which the increase in activity stopped. In the rat and human body experiment, enzymatic decomposition of Hovenia dulcis extract by addition of 1% Rohament CL was also effective in decreasing serum alcohol concentration and respiration. Especially, in the early stage after alcohol consumption, the efficacy of enzyme treatment of Hovenia dulcis extract was more effective. These results show that if the glycoside forms of active compounds such as flavonols in Hovenia dulcis extract are converted into aglycone forms, alcohol decomposition capability can be enhanced.

Mathematical Model for Predicting the Growth Probability of Staphylococcus aureus in Combinations of NaCl and NaNO2 under Aerobic or Evacuated Storage Conditions

  • Lee, Jeeyeon;Gwak, Eunji;Ha, Jimyeong;Kim, Sejeong;Lee, Soomin;Lee, Heeyoung;Oh, Mi-Hwa;Park, Beom-Young;Oh, Nam Su;Choi, Kyoung-Hee;Yoon, Yohan
    • Food Science of Animal Resources
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    • v.36 no.6
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    • pp.752-759
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    • 2016
  • The objective of this study was to describe the growth patterns of Staphylococcus aureus in combinations of NaCl and $NaNO_2$, using a probabilistic model. A mixture of S. aureus strains (NCCP10826, ATCC13565, ATCC14458, ATCC23235, and ATCC27664) was inoculated into nutrient broth plus NaCl (0, 0.25, 0.5, 0.75, 1, 1.25, 1.5, and 1.75%) and $NaNO_2$ (0, 15, 30, 45, 60, 75, 90, 105, and 120 ppm). The samples were then incubated at 4, 7, 10, 12 and $15^{\circ}C$ for up to 60 d under aerobic or vacuum conditions. Growth responses [growth (1) or no growth (0)] were then determined every 24 h by turbidity, and analyzed to select significant parameters (p<0.05) by a stepwise selection method, resulting in a probabilistic model. The developed models were then validated with observed growth responses. S. aureus growth was observed only under aerobic storage at $10-15^{\circ}C$. At $10-15^{\circ}C$, NaCl and $NaNO_2$ did not inhibit S. aureus growth at less than 1.25% NaCl. Concentration dependency was observed for NaCl at more than 1.25%, but not for $NaNO_2$. The concordance percentage between observed and predicted growth data was approximately 93.86%. This result indicates that S. aureus growth can be inhibited in vacuum packaging and even aerobic storage below $10^{\circ}C$. Furthermore, $NaNO_2$ does not effectively inhibit S. aureus growth.

Preparation and Luminescent Properties of YNbO$_4$ : Bi Phosphors by Flux Technique with B$_2$O$_3$ (Boron Oxide Flux를 이용한 YNbO$_4$ : Bi 청색 형광체의 제조 및 발광 특성)

  • 한정화;김현정;박희동
    • Journal of the Korean Ceramic Society
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    • v.36 no.3
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    • pp.319-324
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    • 1999
  • 기존의 고상 반응법에 의해 합성된 YNbO4 : Bi 형광체의 발광특성을 개선하기 위하여 B2O3 융체 첨가법으로 형광체를 합성하고, 빛발광(PL) 및 저전압 음극선발광(CL)을 측정하였다. PL 및 CL 모두 415~440 nm 영역에서 강한 청색 발광 스펙트럼을 나타냈으며, 고상 반응의 경우와 마찬가지로 Y/Nb 비율이 화학 양론상의 1:1인 경우보다 결함구조를 인위적으로 조절한 51/49나 54/46에서 최대의 발광강도를 보였다. 한편, 고상 반응에서는 125$0^{\circ}C$에서 4시간 열처리하는 것이 최대의 발광효과를 나타냈으나, B2O3융제를 첨가하고 110$0^{\circ}C$에서 열처리한 시료가 결정성이 좋고 입자의 크기 및 형태가 균일하여 PL뿐만 아니라 CL에서도 우수한 발광특성을 보였다. B2O3융제를 첨가하는 방법으로 열처리 온도를 낮추고 입자크기와 형태를 조절하여 형광체의 휘도를 개선할 수 있었다.

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