• Title/Summary/Keyword: $\textrm{Na}^{+}$

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Preparation of A and Y type zeolite film by hydrothermal crystallization (수열결정화법에 의한 A 및 Y형 제올라이트 박막의 제조)

  • 김건중;박노춘;안화승;남세종
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.8 no.1
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    • pp.55-63
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    • 1998
  • A and Y type zeolitic crystal films were synthesized on porous supports from the reaction mixture of 1.9 $SiO_2-1.5\;Na_2O-Al_2O_3-40\;H_2O$ and 10 $SiO_2-7\;Na_2O-Al_2O_3-280\;H_2O$ composition, respectively. The zeolite film was characterized by XRD and SEM. The crystals grown on the porous matrix were very closely bound together and the thickness of membrane was about 8-15$\mu \textrm{m}$. The densely intergrown crystals could be also synthesized by the hydrothermal treatment at $100^{\circ}C$ after pressing the reaction mixture without addition of water. A zeolite membrane crystallized as a thin film showed the selective permeability of water from water and methanol mixture through the molecular sieving activity of micropores.

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Proline Accumulation and P5CS ($\Delta^1$-pyrroline-5-carboxylate synthetase) Gene Expression in Response to Salt Stress in Zoysiagrasses

  • Lee, Dong-Joon;Hwang, Cheol-Ho
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.48 no.1
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    • pp.20-24
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    • 2003
  • Proline is known as an osmotrotectant to enhance tolerance against both salt and dehydration stresses. A P5CS ($\Delta^1$-pyrroline-5-carboxylate synthetase) plays a major role in regulation of synthesis of proline. An overexpression of the mothbean P5CS gene in transgenic tobacco plant increased the levels of proline and osmotolerance. In an attempt to look for the possibility to use content of proline as well as a level of P5CS gene expression as molecular markers for salt tolerance, the amounts of proline and transcript levels of P5CS were measured as functions of either concentration of NaCl or length of treatment period among different species of zoysiagrass. Hybridzoysia showed the highest level of proline ($329\mu\textrm{g}$/g.f.w.) among five different species of zoysiagrass at 250 mM NaCl in 24 hours. The level of P5CS transcript was also the highest in the hybridzoysia at 250 mM NaCl in 24 hours. The transcriptions of P5CS gene were induced at the rates of 1.2, 1.2, 1.8, and 1.8, upon treatment of 250 mM NaCl in Z. japonica, Z. matrella, Z. sinica and hybridzoysia respectively. Based on a correlation between the level of P5CS transcript and the proline content among different species of zoysiagrass, a comparative structural analysis of the gene for P5CS from either Z. sinica or hybridzoysia may lead to an understanding of mechanism for salt tolerance shown differently among zoysiagrasses.

The Synthetic Study of Environmental Contamination at the Seokdae Municipal Waste Landfill in Pusan (부산 석대 생활폐기물 매립장의 환경오염에 대한 종합적 연구)

  • 김병우;정상용;이민희;이병헌
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2001.04a
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    • pp.98-103
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    • 2001
  • In order to understand the characteristics of leachate at the Seokdae municipal waste landfill in the Pusan city, the correlation between leachate pollution loading and volume of gas production. concentration of gas and subsidence of ground, the characteristical methos, geochemical analyses and laboratory column tests using samples of gases, leachate and surface soil of Seokdae waste landfill area. Through the analysis of water balance, leachate flow rate and pollution loading were estimated. Geistatistical analysis of four gas components ( $O_2$, C $H_4$, $H_2$S and CO) shows the possibility of ground subsidence around the group of a site with high concentration of gas. From geochemical analyses of leachate, EC and Total-Alkalinity of ground subsidence around the group of a site with high concentration of gas. From geochemical analysis of leachate, Ec and Total-Alkalinity were increased, and Cl, Cr, Mn, Cu, Zn, Cd and Pb were decreassed comparing to the part, and the type of water quality was Na-HC $O_3$ in trilinear diagram. It shows that biodecomposition of municipal wastes continues actively. From the analysis of water balance, the total leachate flow rate is about 465.11㎥/day and pure pollution loading of Cl, Mn and Fe are estimated to 223.8kg/day, 0.2kg/day, 0.3kg/day, respectively. The laboratory column test of residual soil and landfill soil shows 0.206cm and 0.019cm for linear velocity(equation omitted), 0.234 $\textrm{cm}^2$/min and 0.018$\textrm{cm}^2$/min for diffusion coefficient ( $D_{ι}$), and 1.136cm and 0.095cm longitudinal dispersion index ($\alpha$$_{ι}$), respective]y. It demonstrates that the delay time of contamination for residual soil is shorter than that of landfill soil.

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Physicochemical Properties on Shinsun (Waxy) and Black Rice Starch (신선찰벼와 찰흑미 전분의 이화학적 특성)

  • Choi, Gyeong-Cheol;Na, Hwan-Sik;Oh, Geum-Soon;Kim, Sung-Kon;Kim, Kwan
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.32 no.7
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    • pp.953-959
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    • 2003
  • This study examined physicochemical properties of two waxy rice starches, shinsun and black rice starches. Proximate compositions of both samples were similar. The major minerals in the shinsun rice starches were Ca, Mg, P and Na, whereas those in black rice starches were Ca, P, Fe and Mg. The major particle size of shinsun rice starch was 6.97 micron and that of black rice starch was 6.27 micron. In iodine reaction, maximum absorbance wavelength (λmax) and absorbance at 625nm of black rice starch were higher than those of shinsun rice starch. Intrinsic viscosity of black rice starch (183mL/g) was higher than that of shinsun rice starch (178 mL/g). Water binding capacity was similar in both samples. Swelling power and solubility of black rice starch were lower than those of shinsun rice starch. X-ray diffraction patterns of all samples showed traditional A type of cereals as shown peaks at 15.2 (15.0), 17.2 (17.15), 18.05 (17.95), 23.25 (23.15)$^{\circ}$. The common shape of SEM was observed in both waxy rice starches.

Isolation and Characterization of an Extremely Thermophilic Sulfur-metabolizing Bacterium from a Deep-sea Hydrothermal Vent System

  • Kwak, Yi-Seong;Kobayashi, Tetsuo;Akiba, Teruhiko;Horikoshi, Koki;Kim, Young-Bae
    • Journal of Microbiology and Biotechnology
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    • v.4 no.1
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    • pp.36-40
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    • 1994
  • A water sample was taken from a black smoker chimney of a deep-sea hydrothermal vent by using an unmanned submersible "Dolphin 3K". The temperature of the hydrothermal fluid from the black smoker was $276^{\circ}C$. After isolation by repeated serial dilutions, An extremely thermophilic bacterial strain was selected. The strain designated as DT1331, was an anaerobic, non-motile, coccoid shaped bacterium with about 0.5 to $1.0\;\mu\textrm{m}$ in diameter. The strain DT1331 could grow up to $93^{\circ}C$, but the optimum temperature of this strain was $80^{\circ}C$. The growth occurred in the pH range of 4.5 to 8.5 and the optimum pH was 6.0. The strain DT1331 required 1% to 5% NaCl for growth and cell lysis was observed below 1% NaCl concentration. The bacterium could grow on polypeptides such as tryptone, peptone, soytone and on proteins such as casein or gelatin. However, no growth was observed on single amino acids, sugar and organic acids. Hydrogen gas was detected slightly during growth. This bacterium obligately required elemental sulfur and hydrogen sulfide gas was produced during growth.

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Performance Evaluation of Domestic -made DOC for the Heavy-duty Diesel Engine (국내 제작된 대형 디젤산화촉매의 배출가스 성능평가)

  • 정일록;엄명도;김종춘;김태승;류정호;임철수
    • Transactions of the Korean Society of Automotive Engineers
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    • v.7 no.7
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    • pp.15-23
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    • 1999
  • In recent years, environmental damage to urban area becomes serious problem due to the exhaust emissions by increasing the number of vehicle . Especially, diesel particulate matters(DPM) are hazardous air pollutant s to human health and environment. The reduction technologies of exhaust emissions from diesel engines are improvement of engine combustion, fuel quality and development of diesel exhaust aftertreatment. In this study, a diesel oxidation catalyst(DOC) that is one of diesel exhaust aftertreatments was made for performance evaluation . It was tested for NA and turbocharged engine by D-13 mode that currently be used for regulation driving test mode in Korea Scanning mobility particle sizer (SMPS) was used for the analysis of the particle size distribution with and w/o DOC. As the results , for NA and tubochartged engine, CO, THC, DPM was respectively reduced 85.7, 40.7,3.3% and 79.1, 53.1, 11.6% by DOC. Test results of particle size distribution was showed that particle number is 107 ~108per ㎤ , 2 $\times$105 ~5$\times$105$\mu\textrm{g}$/㎥ for weight concentration and 100~200nm for particle mean size in diesel engine and there is no effect to reduce the particle concentration by the DOC.

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Geochemistry and Mineralogy of Precipitates from Oseag Hot Spring (오색온천수의 지화학적 및 침전물에 대한 광물학적 특성)

  • 김정진;김수진;김윤영
    • Journal of the Mineralogical Society of Korea
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    • v.17 no.2
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    • pp.169-176
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    • 2004
  • The Osaeg hotspring (long. $128^{\circ}$ 56'E, tat. $37^{\circ}$ 06'N) located in the northester part of Kangwon-do, Korea. The pH value of the hot spring water is 8.31, and the EC, $SO_4$, F and Na are 196 ${\mu}\textrm{s}$/cm, 10.88 mg/L, 8.19 mg/L, and 37.07 mg/L, respectively. The ocherous precipitates are precipitated on the stream bottom of Osaeg hot spring drainage. X-ray diffraction analysis (XRD), scanning electron microscopy (SEM) and stereo-microscope were used to analyze the precipitates. X-ray diffraction analysis shows that the precipitates consist mainly of poorly crystalline materials and messelite. Many spherical and rod-shaped bacteria-like forms were observed in the precipitates.

Improvement on the Corrosion Resistance and Stress Corrosion Cracking of Ultra-high Strenght AISI 4340 Steel (초강인 AISI 4340 강의 부식 저항성 향상 및 응력부식균열)

  • Hong, Won-Sik;Park, Gyeong-Sun;Lee, Sang-Yul;Kim, Gwang-Bae
    • Korean Journal of Materials Research
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    • v.6 no.9
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    • pp.885-899
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    • 1996
  • 초강인 AISI 4340강을 85$0^{\circ}C$에서 2시간 동안 오스테나이징 처리 후 수냉하고, 250, 400, $600^{\circ}C$에서 각각 2시간 동안 템퍼링 처리를 하였다. AISI 4340강의 인장 특성은 상온에서 측정되었다. AISI 4340강 위에 니켈 전해도금된 것과 도금되지 않은 시편의 분극 특성이 3.5wt%NaCI 수용액과 인공해수에서 측정되었다. AISI 4340강위에 니켈 전해도금된 시편은 500mV(vs. Ag/AgCI)이하의 전위에서 부식 저항이 크게 향상되었다. 그러나 1A/$\textrm{cm}^2$의 전류밀도에서 30분 이상 니켈 전해도금된 시편은 도금층에 불순물과 기공이 형성되었기 때문에 AISI 4340강의 부식 저항은 감소되었다. AISI 4340강의 수소취화형 응력부식균열을 여러 작용 응력과 음극인가전력에서 U-bend 시편을 이용하여 IN 3.5 wt% NaCI 수용액에서 조사되었고, 수소취화형 응력부식균열 거동은 주사전자현미경으로 조사되었다.

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A Study on the Wear Characteristics of Austempered Ductile Cast Iron in Corrosive Environments (오스템퍼링한 구상점연주철의 부식환경중의 마멸특성에 관한 연구)

  • Kang, Myug-Soon;Jun, Tae-Ok;Park, Heung-Sik;Jin, Dong-Gyu
    • Journal of Ocean Engineering and Technology
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    • v.2 no.2
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    • pp.87-95
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    • 1988
  • This paper is studied to know corrowive wear characteristics of austempered ductile cast ironin corrosive environments against mating SM45C hardened two test pieces in distilled water and NaCl aqueous solution. The corrosive wear mechanism was investigated by scanning electron microscopy and retained austenite volume fraction was investigated by X-ray diffractometer. The experimental result show that the corrosive wear characteristics depend largely on the $\textrm{Fe(OH)}_{3}$which is influenced by the critical sliding distance $L_{cr}$ and $L_{cr}$ shorted with increasing NaCl concentration. It was found that the carbides in matrix have a significant effect on their corrosive wear resisance and the fine acicular bainite showed corrosive wear resistance stronger than that of the coarse acicular and platelet bainite. From above results the model of corrosive wear mechanism in corrosive environments is proposed.

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Pre-sowing Treatments to Improve Germination of Intact Seeds in Burcucumber (Sicyos angulatus L.) (가종피가 부착된 안동대목 종자의 발아율 향상을 위한 파종전 종자처리)

  • 강진호;전병삼;윤수영;이상우;정종일
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.48 no.3
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    • pp.169-172
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    • 2003
  • Intact seeds of burcucumber (Sicyos angulatus L.) are not nearly germinated so that the farmers remove their arils before sowing. The study was carried out to measure the effort of aging, chilling, washing, chemical treatment, drying, and their sequential treatments on the germination of ones with arils and the seedling emergence. The seeds extruding over 1mm of their radicles and the seedlings with fully expanded cotyledons were counted daily for calculating the germination and the seedling emergence rates. Seedcoat softening using 10% NaOH solution somewhat enhanced their germination rate of the intact seeds harvested in the current year, but aging treatment done on 6 days at $45^{\circ}C$ after NaOH treatment increased the germination rate more than only NaOH treatment. A day washing after the NaOH treatment and a day chilling after the washing increasingly elevated the rates as well. Irrigation of 0.2% $\textrm{KNO}_3$ solution, moreover, showed the greatest germination rate of the priming treatments done during all the 7 day chilling. Drying the seeds after the combined treatment of chilling and priming more inclined the germination rate than nondrying ones, but red light treated during 24 hour desiccation was more effective in the germination rate increment than dark condition. The seeds done the sequential treatments of aging, NaOH, washing, combining chilling and priming and drying under red light illumination were germinated up to 80% but seedlings were emerged to 60%, lower than ones removed their arils.