• Title/Summary/Keyword: $\textrm{NO}_3\

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Electrical Property Changes of $\textrm{NO}_X$ Sensitive $\textrm{WO}_3$ Thin Films as Applied DC Voltages on 8YSZ Substrate (8YSZ 기판에 증착한 $\textrm{WO}_3$ 박막의 DC 전압에 따른 $\textrm{NO}_X$ 감지특성)

  • 전춘배;박기철
    • Journal of the Korean Institute of Telematics and Electronics T
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    • v.36T no.1
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    • pp.8-12
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    • 1999
  • $\textrm{WO}_3$ semiconductive film, which is known to have a sensitivity on $\textrm{NO}_X$ gas was prepared on 8YSZ (8% Yttria stabilized $\textrm{ZrO}_2$) ionic conductor substrate that has oxygen ion pumping effect. Microstructure and electrical properity, especially $\textrm{NO}_X$ sensitivity as a function of DC voltage applied to 8YSZ substrate was examined. When the $\textrm{WO}_3$ film was annealed, it showed amorphous structure, while crystallization was occurred at $600^{\circ}$C revealing orthorhombic phase of $\textrm{WO}_3$. As the annealing temperature increases, (111) and (001) peaks of $\textrm{WO}_3$ film was enhanced. At $400^{\circ}C$ when DC voltage was applied, comparing with no DC bias, more stable and large response characteristics was showed, and the best sensitivity was observed at 2V. Recovery characteristics of NO gas was much better that that of $\textrm{NO}_2$ gas.

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Effects of $\textrm{NO}_3$-N:$\textrm{NH}_4$-N Ratio and Elevated $\textrm{CO}_2$ on Growth and Quality of Lactuca sativa L. in Nutrient Film Technique (NFT재배에서 $\textrm{CO}_2$ 시용과 배양액의 $\textrm{NO}_3$:$\textrm{NH}_4$비율이 결구상추의 생육 및 품질에 미치는 영향)

  • 원선이;조영렬;이용범
    • Journal of Bio-Environment Control
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    • v.5 no.2
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    • pp.120-130
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    • 1996
  • Crisphead lettuce(Lactuca sativa L.) was grown in NFT to investigate the effects of NO$_3$-N and NH$_4$-N ratio in nutrient solution and elevated $CO_2$ treatment in the crisphead lettuce growth. This experiment has been conducted under three different ratios of NO$_3$-N:NH$_4$-N(100:0, 75:25, 50:50) with two $CO_2$ concentration (control, 1500ppm ). The results are as follows; 1. In the case of not controlling pH and EC in nutrient solution, pH was gradually increased in NO$_3$-N:NH$_4$-N=100:0 treatment but rapidly decreased in the nutrient solution 2. Daily changes of NO$_3$-N and NH$_4$-N were observed without controlling the nutrient solution. In the treatments of NO$_3$-N:NH$_4$-N ratios were 75:25 and 50:50, NO$_3$-N absorption rates were 27.7% and 26.1%, while NH$_4$-N absorption rates were 87.9% and 71.2%, respectively. 3. There was little differences in total nitrogen of leaves. However phosphorus, potassium, calcium and magnesium contents were highly shown in the treatment of $CO_2$ 1500ppm and 100:0 ratio of NO$_3$-N:NH$_4$-N. 4. Higher $CO_2$ assimilation rate was shown in plants grown under $CO_2$ 1500ppm and 100:0 ratio of NO$_3$-N:NH$_4$-N. It dropped significantly with the increase of NH$_4$- N rates in nutrient solution. 5. Fresh weight, leaf number, root length and root weight of crisphead lettuce were far better in the treatment of $CO_2$ 1500ppm and 100:0 ratio of NO$_3$-N:NH$_4$-N. Growth differences by $CO_2$ elevation were not shown in other NO$_3$-N:NH$_4$-N treatments. 6. The highest nitrate contents of leaves were shown in NO$_3$-N single treatment but shown the lowest vitamin C contents. Nitrate contents of leaves were decreased by $CO_2$ but the effect was slight treatment.

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Studies on the Modelling of Controlled Environment in Leaf Vegetable Crops (엽채류의 환경제어 모델 연구 I. 야온 및 양액내 $\textrm{NO}_3\;^-$: $\textrm{NH}_4\;^+$비가 백경채 및 탑채의 생육에 미치는 영향)

  • 박권우;신영주;이용범
    • Journal of Bio-Environment Control
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    • v.1 no.1
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    • pp.21-27
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    • 1992
  • The effects of different night temperatures and NO$_3$$^{[-10]}$ : NH$_4$$^{+}$ ratios in nutrient solution on the growth and quality of Chinese white cabbage(B. chinensis L. var. chinensis) and Chinese flat cabbage(B. chinensis L. var. rosularis) were studied. The results were summarized as follows. 1. Fresh weight was increased higher in night temperature 15$^{\circ}C$ than 5, 1$0^{\circ}C$, but content of vitamin C and dry weight ratio were increased as night temperature was lower. 2, The growth of Chinese white cabbage and Chinese flat cabbage was bad extremely in NO$_3$$^{[-10]}$ : NH$_4$$^{+}$(0 : 8), and the others were little different 3. In nutrient solution, the higher NO$_3$$^{[-10]}$ -N concentration was, the more content of vitamin C, and the higher NH$_4$$^{+}$-N concentration was, the more dry weight ratio.ratio.

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Effect of Tillage and Seeding Methods on Percolation and Irrigation Requirement in Rice Paddy Condition

  • Chae, Je-Cheon
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.43 no.4
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    • pp.264-268
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    • 1998
  • The experiment was conducted to clarify irrigation requirement and percolation rate in rice paddy. The four rice cultural system of no-tin, till, transplanting, and direct seeding condition were treated in the lysimeter filled with sandy loam soil. The amounts of irrigation and soil percolation were measured daily, and irrigation requirement was estimated. The daily percolation was 19.5 l/$\textrm{m}^2$ in no-till direct seeding on flooded paddy surface, 17.4 l/$\textrm{m}^2$ in both of till-direct seeding on flooded surface and no-till transplanting, and 15.2 l/$\textrm{m}^2$ in transplanting plot. This is equivalent to 19.5, 17.4, and 15.2 mm per day, respectively. Highest irrigation requirement was 3,770 l/$\textrm{m}^2$ in no-till direct seeding plots. Others were 3,249, 2,577, and 2,321 l/$\textrm{m}^2$ in till-direct seeding, no-till transplanting and transplanting plot, respectively. The estimated irrigation requirement of no-till transplanting, till-direct seeding and no-till direct seeding was increased by 11, 37, and 59% compared to till-transplanting plot. Percolation rate of no-till transplanting, till direct seeding and no-till direct seeding was increased by 12%, 40%, and 66%, respectively compared to the till-transplanting plot. The percolation rate in paddy soil was increased greatly after reproductive stage of rice.

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Tocotrienol and Tocopherol Content in Various Plant Seeds (몇 가지 작물 종실의 Tocotrienol과 Tocopherol 함량)

  • 박경열;강창성;이용선;이영현;이영상
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.49 no.3
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    • pp.207-210
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    • 2004
  • Vitamin E, consisting of tocotrienols ($\textrm{T}_3$) and tocopherols ($\textrm{T}$) is well-known nutraceutical compound for its antioxidant, anticancer and cholesterol-low-ering activity. The contents of alpha ($\alpha\textrm{-}$), beta ($\beta\textrm{-}$), gamma ($\gamma\textrm{-}$) and delta ($\delta\textrm{-}$) tocotrienols and tocopheyols in some Korean crop seeds were evaluated by using HPLC after saponification. Among tested crops, total 73 contents (mg/110g) were purple perilla 25.06, barley 4.50, corn 3.54, iris 3.04, adlay 2.58, safflower 0.12. Other crops including 5 soybean cultivars, kidneybean, sunflower and perilla contained no tocotrienols. Regarding $\textrm{T}_3$ isomers, $\beta\textrm{-}$$\textrm{T}_3$ were rut observed in adlay and corn, and $\delta$-$\textrm{T}_3$ were not in iris aid purple perilla, while safflower exhibited no detectable $\alpha\textrm{-}$, $\beta\textrm{-}$ and $\delta\textrm{-}$$\textrm{T}_3$. Total T contents (mg/100g) were high in iris (51.82), perilla (40.90), soybean (34.11), sunflower (20.88), and they all contained all $\alpha\textrm{-}$, $\beta\textrm{-}$, $\gamma\textrm{-}$ and $\delta\textrm{-}$ tocopterol isomers. Total Vit E contents (T + $\textrm{T}_3$, mg/100g) were iris 54.86, purple perilla 41.80, perilla 40.90, soybean 34.11, sunflower 20.88, safflower 14.73, corn 11.49, evening-primrose 10.07, barley 7.48, adlay 6.24 and kidneybean 5.27.

A Study on the Behavior and Deposition of Acid Precipitation-comparison of Chemical Composition of Rain Water between Chunchon and seoul (산성강하물의 침착량과 동태 해명에 관한 연구-춘천과 서울 강우의 화학조성 비교)

  • Kim, Man-Goo;Kang, Mi-Hee;Lim, Yang-Suck;Park, Ki-Jun;Hwang, Hoon;Lee, Bo-Kyung;Hong, Seung-Hee;Lee, Dong-Soo
    • Journal of Korean Society for Atmospheric Environment
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    • v.15 no.2
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    • pp.89-100
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    • 1999
  • The rain water samples were collected at Chunchon and Seoul by using wet only automatic sampler from January 1996 through 1997. The daily base rain water samples collected over than 95% rainy events components, $SO_4^{-2}$, $NO_3^-$, $CI^-$, NH_4^+$, $Ca^{2+}$, $Mg^{2+}$, $Na^+$, and $K^+$, by ion chromatography. In 1996, about 77% of sampled rain water showed below pH 5.6 and the 60% of rain water was lower than pH 5.0. The volume weighted average pH was 4.7 at all sites. In 1997, the volume weighted average pH was 4.6 and 4.9 at Seoul and Chunchon, respectively. Among the rain water samples,, 87% and 55% fo samples showed below than pH 5.6 and 5.0, respectively. The pH value of Chunchon was significantly (p<0.05) lower than Seoul at the rain samples for less than 20mm rainfall. However conductivity of the rain samples were 20.9$\mu$S/cm for 1996 and 27.7$\mu$S/cm for 1997 at Seoul, and 19.1$\mu$S/cm for 1996 and 14.1$\mu$S/cm for 1997 at Chunchon. $H_2SO_4$ and $HNO_3$ contributed 65.9% and 29.6% of free acidity at Seoul, respectively. The ratio of [$NO_3^-$]/[nss-$SO_4^{-2}$] were 0.43 at Seoul and 0.51 at Chunchon for rain samples for less than 20mm rainfall. The annual wet deposition of $CI^-$, $NO_3^-$, $SO_4^{-2}$, $H^+$M, $Na^+$, NH_4^+$, $K^+$, $Mg^{2+}$, and $Ca^{2+}$, respectively, 568.8kg/$ extrm{km}^2$, 1489.3kg/$\textrm{km}^2$, 3184.8kg/$\textrm{km}^2$, 20.9kg/$\textrm{km}^2$, 249.4kg/$\textrm{km}^2$, 1091.2kg/$\textrm{km}^2$, 189.8kg/ $\textrm{km}^2$, 90.2kg/$\textrm{km}^2$ and 702.4kg/$\textrm{km}^2$ at Seoul for 1996; 656.4kg/$\textrm{km}^2$, 2029.7kg/$\textrm{km}^2$, 3280.7kg/$\textrm{km}^2$, 27.2kg /$\textrm{km}^2$, 229.4kg/$\textrm{km}^2$, 1063.9kg/$\textrm{km}^2$, 106.9kg/$\textrm{km}^2$, 78.2kg/$\textrm{km}^2$, 645.3kg/$\textrm{km}^2$ at Seoul for 1997; 116.9kg/ $\textrm{km}^2$, 983.3kg/$\textrm{km}^2$, 1797.0kg/$\textrm{km}^2$, 21.4kg/$\textrm{km}^2$, 83.2kg/$\textrm{km}^2$, 648.1kg/$\textrm{km}^2$, 78.0kg/$\textrm{km}^2$, 22.2kg/$\textrm{km}^2$, 368.8kg/$\textrm{km}^2$ at chunchon for 1996; 100.2kg/$\textrm{km}^2$, 1077.6kg/$\textrm{km}^2$, 1754.0kg/$\textrm{km}^2$, 13.4kg/$\textrm{km}^2$, 146.0kg/$\textrm{km}^2$, 602.3kg/$\textrm{km}^2$, 88.8kg/$\textrm{km}^2$, 16.2kg/$\textrm{km}^2$ and 206.8kg/$\textrm{km}^2$ at chunchon for 1997.

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Effect of $\textrm{NO}_3$:$\textrm{NH}_4$ Ratio on the $\textrm{NO}_3$ Content in Leaf Lettuce Cultured by a Deep Flow Technique (잎상추의 수경재배시 $\textrm{NO}_3$-N과 $\textrm{NH}_4$-N의 비율이 엽중 nitrate 함량에 미치는 효과)

  • 김혜진;김영식
    • Journal of Bio-Environment Control
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    • v.10 no.1
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    • pp.50-54
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    • 2001
  • Effect of NO$_3$:NH$_4$ratio and pH of nutrient solution on nitrate content of leaves was investigated for leaf lettuce(Lactuca sativa L.) grown by a deep flow technique. Ratios(in me.L$^{-1}$ ) of NO$_3$:NH$_4$tested were 12:1, 10:3 and 8:5. The treatment of 8:5 NO$_3$:NH$_4$ratio had two solutions, one with uncontrolled pH and the other with automatically controlled pH. Solution pH continuously increased in 12:1 NO$_3$:NH$_4$treatment. Solution pH decreased gradually more as NH$_4$ratio increased. Treatment of 8:5 NO$_3$:NH$_4$with automatic pH control satisfactorily maintained the solution pH in the range of pH 5.5-6.0. Nitrate content in leaves was the greatest in treatment of 12:1 NO$_3$:NH$_4$ and the least in treatment of 8:5 NO$_3$:NH$_4$with automatic pH control. Fresh weight decreased in treatments of 10:3 and 8:5 NO$_3$:NH$_4$, whereas it increased in treatments of 12:1 and 8:5 NO$_3$:NH$_4$with pH control. It was concluded that the growth and leaf nitrate content were the greatest in high NH$_4$treatment with automatic pH control.

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Growth and Ion Content of Korean Ginseng under Saline Condition

  • Cho, Jin-Woong;Seong, Bong-Jae;Kim, Hyun-Ho;Kim, Choong-Soo
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.49 no.2
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    • pp.94-99
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    • 2004
  • This study was conducted to determine the effect of salinity on the growth and development of Korean ginseng (Panax ginseng C.A.Meyer) and to evaluate the inorganic ion content in Korean ginseng with different general complete fertilizer (GCF) and NaCI concentrations at two growth stages. The stem height of Korean ginseng treated with different GCF and NaCI concentrations decreased at the higher EC (2.0 dS m$^{-1}$ ), but there were no significant difference in the stem diameter, the leaf length, and the leaf width among different treatments. The root growth increased with the supply of GCF. Especially, the root growth was facilitated two times at 3.0 dS $\textrm{m}^{-1}$ as compared to control. But the root growth more sharply decreased with NaCI treatment than GCF. The $\textrm{K}^{+}$ and $\textrm{Mg}^{2+}$ content in leaves and roots increased with GCF at the early growth stage. At the late growth stage, the $\textrm{K}^{+}$ content in leaves decreased but the $\textrm{Ca}^{2+}$ and $\textrm{Mg}^{2+}$ content increased. The $\textrm{Ca}^{2+}$ and $\textrm{Mg}^{2+}$ content in roots increased but the $\textrm{K}^{+}$ content decreased. The $\textrm{Na}^{+}$ content in Korean ginseng increased sharply with NaCl treatment. The $\textrm{NO}_3^{-}$ content in leaves and $\textrm{NH}_4^{+}$ content in leaves and roots increased as GCF concentration increased. The $\textrm{NO}_3^{-}$ content in leaves, stems, and roots at the late growth stage decreased as NaCl concentration increased. The $\textrm{NH}_4^{+}$ content in leaves and roots decreased significantly at the early growth stage, but it decreased significantly in leaves and stems at the late growth stage. The root activity of Korean ginseng increased with GCF, but decreased as the EC increased with NaCl. The water potential of leaves with GCF showed no significant difference compare to control, but the water potential of leaves treated with NaCl decreased as EC increased.

Antigenicity of CFC-101(Pseudomonas vaccine) in Guinea Pigs and Mice (기니픽과 마우스에서 CFC-101(녹농균 백신)의 항원성시험)

  • 백남진;김달현;이동억;선우연;한형미;정승태;김필선;김현수
    • Biomolecules & Therapeutics
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    • v.2 no.4
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    • pp.331-335
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    • 1994
  • As a part of the safety evaluation of Pseudomonas vaccine(CFC-101), antigenicity tests were carried out in guinea pigs and mice. In active systemic anaphylaxis(ASA) test, guinea pigs showed no sign or only moderate sign(1/5) when sensitized and challenged with up to 200 $\mu\textrm{g}$/kg. In homologous passive cutaneous anaphylaxis(PCA) test using guinea pigs, inoculation of CFC-101 alone did not produce CFC-101-specific antibody. When inoculated with 200 $\mu\textrm{g}$/kg plus adjuvant, challenge of 200 $\mu\textrm{g}$/kg produced PCA titer of 32(5/5) but challenge of 20 $\mu\textrm{g}$/kg did not produce CFC-101-specific antibody. In heterologous PCA test using mice, CFC-101-specific antibody was not detected when sensitized with CFC-101 alone. Some animals(3/12) showed positive PCA response when inoculated with 200 $\mu\textrm{g}$/kg plus alum. In passive hemagglutination (PHA) test, although no antibody was detected at 20 $\mu\textrm{g}$/kg, inoculation of 200 $\mu\textrm{g}$/kg alone or with alum produced positive response in all animals. This result has already been predicted because CFC-101 is a vaccine developed for the purpose of immunization. From the above results, it can be concluded that there is no adverse antigenic potential up to 10 times clinical dose of 200 $\mu\textrm{g}$/kg.

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Effect of White Ginseng on the Proliferation of Mouse Peritoneal Macrophages and Their Nitric Oxide Synthesis (백삼성분이 마우스 복강 탐식세포의 증식 및 Nitric Oxide 생성에 미치는 영향)

  • 김주원;배지현
    • Journal of the East Asian Society of Dietary Life
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    • v.7 no.4
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    • pp.484-490
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    • 1997
  • In an attempt to investigate the effects of white ginseng on the proliferation and the nitric oxide(NO) secretion of mouse peritoneal macrophages, which are the first mai or defense phagocytes in the immune system, the studies have been carried out. In the macrophage proliferation assay using the $^3$H-thymidine incorporation, the total saponin or Ginsenoside Rb$_2$ were added to the medium at the concentration of 0 to 256$\mu\textrm{g}$/$m\ell$. DNA synthesis of the macrophage was increased at 64$\mu\textrm{g}$/$m\ell$ of total saponin and either 16$\mu\textrm{g}$/$m\ell$ or 64$\mu\textrm{g}$/$m\ell$ of Ginsenoside Rb$_2$, respectively. Also, the effect o(white ginseng on the nitric oxide secretion of the macrophages was investigated. The addition of either total saponin or Ginsenoside Rb$_2$ at the concentration of 20$\mu\textrm{g}$/$m\ell$ significantly increased the secretion of NO from the macrophages. The nitric oxide synthase (NOS) gene expression which is responsible for the synthesis of the nitric oxide has been studied using reverse transcription polymerase chain reaction. In RT-PCR, the $\beta$-actin and nos gene expression have been analyzed. 20$\mu\textrm{g}$/$m\ell$ of either total saponin or Ginsenoside Rb$_2$ increased nos gene expression of the macrophages.

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