• Title/Summary/Keyword: $\Delta$f

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Effect of Densities on Dielectric Properties of $Ba[Mg_{1/3}(Nb_{0.2}Ta_{0.8})_{2/3}]O_3$Ceramics ($Ba[Mg_{1/3}(Nb_{0.2}Ta_{0.8})_{2/3}]O_3$ 세라믹스의 밀도가 유전특성에 미치는 영향)

  • 김재윤;김부근;김강언;정수태;조상희
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.13 no.6
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    • pp.485-492
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    • 2000
  • The sintering characteristics and the effects of density on dielectric properties in 0.2Ba(Mg$_{1}$3(Nb$_{2}$3/)O$_3$-0.8Ba(Mg$_{1}$3//Ta$_{2}$3/)O$_3$ceramics were investigated. The samples were made by the powder mixing techniques with the two step calcining conditions. When the 1st and the 2nd calcining temperatures were 120$0^{\circ}C$ and the sintering temperature was 155$0^{\circ}C$the density of samples showed the highest value (7.45 g/cm$^3$, 98.5% of theoretical density) among them. The dielectric constant of samples was nearly independent of density but the tan $\delta$ and the temperature coefficient of dielectric constant decreased linearly with increasing of the density. The quality factor(Q$\times$f), the temperature coefficient of resonance frequency and the dielectric constant of Ba[Mg$_{1}$3(Nb$_{0.2}$/Ta$_{0.8}$)sub 2/3/]O$_3$ceramic were 79,548 GHz, +1.5 ppm/$^{\circ}C$ and 26 in the microwave range, respectively.ely.

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Nonstoichiometry of the Tungsten Oxide (산화 텅스텐의 비화학량론)

  • Ryu, Kwang Hyun;Oh, Eung Ju;Kim, Keu Hong;Yo, Chul Hyun
    • Journal of the Korean Chemical Society
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    • v.39 no.3
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    • pp.157-162
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    • 1995
  • The x values and electrical conductivities of the nonstoichiometric compounds $WO_{3-x}$ have been measured in the temperature range from 350 to 700$^{\circ}C$ under oxygen partial pressure of $2{\times}10_{-1}\;to\;1{\times}10_{-5}$ atm. The enthalpy of the defect formation shows an endothermic process, and the oxygen pressure dependence of the defect formation or 1/n varies from -1/5.2 to -1/5.9. The activation energy and 1/n value for the electrical conductivity are 0.24~0.29 eV and -1/4.3~-1/7.6, respectively. The Tungsten Oxide as a n-type semiconductor has predominently defect model of singly charged oxygen vacancy at low temperature, and of doubly charged oxygen vacancy at high temperature.

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Self-Assembly and Electrochemical Properties of Viologen Particles (Viologen 분자의 자기조립과 전기화학적 특성)

  • Lee, Dong-Yun;Park, Sang-Hyun;Shin, Hoon-Kyu;Kwon, Young-Soo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.11a
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    • pp.452-455
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    • 2004
  • In this paper, investigations of the SAMs(self-assembled monolayers) of a thiol-fuctionalized viologen derivatives, $V_8SH$ and $SH_8V_8SH$, where, V is N,N'-dialkylbipyridinium (i.e. a viologen group), have been carried out by elucidate voltammetry date. The redox reactions are highly reversible and can be cycled many times without significant side reaction, which has been known as a nano-gram order mass detector through resonant frequency change self-assembly process of the viologen has been investigated with $QCM({\Delta}F)$. The assembling process of the $V_8SH$ and $SH_8V_8SH$ monolayers can be finished completely in about 1 hour. The measured frequency shift for $V_8SH$ and $SH_8V_8SH$ were about 351 and 172 Hz, respectively. From these values, we calculated that the mass adsorbed $V_8SH$ and $SH_8V_8SH$ were about 375 and 183 ng. We believe that this mass loss is caused by the simultaneous loss of the anions present within the monolayer for charge compensation of the viologen dications and some solvent.

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Quantities and Units in Radiation Dosimetry (방사선량(放射線量) 및 단위(單位))

  • Hwang, Sun-Tae
    • Journal of Radiation Protection and Research
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    • v.2 no.1
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    • pp.38-46
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    • 1977
  • 오늘날 에너지 공급(供給)을 위한 새로운 해결책(解決策)의 하나로서 등장(登場)한 원자력발전소(原子力發電所), 재래(在來)의 X선(線) 진료(診療) 이외(以外)에 의학계(醫學界)에 도입(導入)된 방사선원(放射線源), 그리고 각종(各種) 전자생산품(電子生産品) 등(等)의 증가현상(增加現象)은 방사선(放射線) 방어(防禦) 문제(問題)와 관련(關聯)하여 보건의학분야(保健醫學分野)에서 종사(從事)하는 사람들에게 지대(至大)한 관심(關心)거리가 되고있다. 그래서, 우선(于先) 방사선(放射線)에 관(關)한 사항(事項)중에서 가장 기초(基礎)가되는 방사선량계측(放射線量計測)에 있어서 그 양(量)과 단위(單位) 문제(問題)가 체계적(體系的)으로 서술(敍述)되었다. 즉(卽) 방사선(放射線)이 인체(人體)에 끼칠 수 있는 해(害)로운 영향(影響)에 그 주안점(主眼點)을 두어 조사선량(照射線量), 흡수선량(吸收線量), 선량당량(線量當量), 그리고 그들의 관계(關係) 및 방사능등(放射能等)에 관(關)하여 토론(討論)되었다. 특(特)히 조사선량률(放射線量率), X는 비(比)감마선선상수(線常數), ($\Gamma$)를 포함(包含)하는 함수(函數)로 표현(表現)되었고, 끝으로 인체(人體) 내부(內部)에 축적(蓄積)된 방사능(放射能)으로부터의 영향(影響)에 의(依)한 이른바 생물학적효과(生物學的效果) (Somatic or Genetic Effects)와 관련(關聯)되는 내부흡수선량율(內部吸收線量率)은 평형흡수선량상수(平衡吸收線量常數)($\Delta_i$)와 흡수율($F_i$)를 포함(包含)하는 수학적(數學的) 모델로 소개(紹介)되었다. 한편 방사능(放射能)은 방사선원(放射線源) 물질(物質)의 자연붕괴율(自然崩壞率)이므로 다른 방사선량(放射線量)들 즉(卽) 조사선량(照射線量), 흡수선량(吸收線量)그리고 선량당량(線量當量)과는 별도(別途)로 취급(取扱)하였음을 부언(附言)한다.

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Fatigue Design of Spot Welded Lap Joint Considered Residual Stress (잔류응력을 고려한 점용접이음재의 피로설계)

  • Son, Il-Seon;Bae, Dong-Ho;Hong, Jeong-Gyun;Lee, Beom-No
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.24 no.3 s.174
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    • pp.743-751
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    • 2000
  • Because welding residual stress is formidable result in electric resistance spot welding process, and it detrimentally affect to fatigue crack initiation and growth at nugget edge of spot welded la p joints, it should be considered in fatigue analysis. Thus, accurate prediction of residual stress is very important. In this study, nonlinear finite element analysis on welding residual stress generated in process of the spot welding was conducted, and their results were compared with experimental data measured by X-ray diffraction method. By using their results, the maximum principal stress considered welding residual stress at nugget edge of the spot welded lap joint subjected to tension-shear load was calculated by superposition method. And, the $\Delta$P- $N_f$ relations obtained through fatigue, tests on the IB-type spot welded lap joints was systematically rearranged with the maximum principal stress considered welding residual stress. From the results, it was found th2at fatigue strength of the IB-type spot welded lap joints could be systematically and more reasonably rearranged by the maximum principal stress($\sigma$1max-res considered welding residual stress at nugget edge of the spot welding point.

Nonstoichiometry of the Yttrium Oxide and the Holmium Oxide (산화이트륨 및 산화홀뮴의 비화학양론)

  • Chang, Soon-Ho;Yo, Chul-Hyun;Choi, Jae-Shi;Pyun, Mu-Sil
    • Journal of the Korean Chemical Society
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    • v.28 no.4
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    • pp.231-237
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    • 1984
  • The x-values in the nonstoichiometric chemical formulas $YO_{1.5+x}\;and\;HoO_{1.5+x}$, have been measured in the temperature range from 700$^{\circ}$C to 1000$^{\circ}$C under oxygen pressures from $2{\times}l0^{-1}\;to\;1{\times}10^{-6}$ atm by gravimetric method. The observed x-values increase with increasing temperature and oxygen pressure. The enthalpies of formation of excess oxygen in yttrium oxide and holmium oxide decrease with decreasing oxygen pressure and are all positive values representing an endothermic process. The 1/n values calculated from the slopes of the plots of log x vs. log $P_{O2}$ increase with temperature and are positive values which means the higher oxygen pressure dependence at higher temperature. We have examined the nonstoichiometric defect and conduction mechanism from x-values and thermodynamic data.

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A FINITE ELEMENT ANALYSIS OF THE CENTER OF RESISTANCE OF A MAXILLARY FIRST MOLAR (상악 제일대구치의 저항중심에 관한 유한요소법적 분석)

  • Cho, Jeong-Hyeon;Lee, Ki-Soo;Park, Young-Guk
    • The korean journal of orthodontics
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    • v.23 no.2 s.41
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    • pp.263-273
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    • 1993
  • The purpose of this study was to analyse the center of resistance of the maxillary first molar using the 3-dimension finite element method. An extracted maxillary first molar of normal shape and average root length was selected and sectioned every 1.5mm parallel to the cementoenamel junction. Each section was traced and digitized to construct 3-D finite element model of the maxillary first molar. After a certain magnitude of counterbalancing moment(M) was applied to the tooth, a varying single force(F) of distomesial direction was applied to a certain point of th tooth until the tooth was translated. The force producing translation(Ft) was substituted to the equation ${\Delta}d=M/Ft$ to calculate the center of resistance of the maxillary first molar. And reducing the alveolar bone level 1.68mm, and 3.36mm below to the cementoenamel junction, the tooth movement was analysed to see the effect of reducing the alveolar bone level to the location of the center of resistance. The results were as follows ; 1. The center of resistance of the maxillary first molar was 3.72mm apical, 1.10mm buccal, and 0.71mm mesial to the geometric center of the horizontally sectioned surface at the cementoenamel junction. This point was 0.36mm apical, 1.20mm buccal, and 0.71mm mesial to the trifurcation point, indicating that it was not on the tooth root. 2. As the alveolar bone level was reduced, the center of resistance of the maxillary first molar was moved to the apical direction.

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Study on R-l34a, R-407C, and R-410A Condensation Performance in the Oblong Shell and Plate Heat Exchanger (오블롱 셀 플레이트 열교환기에서의 R-l34a, R-407C, R-410A의 응축성능에 관한 실험적 연구)

  • Park, Jae-Hong;Kim, Young-Soo
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.28 no.12
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    • pp.1535-1548
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    • 2004
  • Condensation heat transfer experiments were conducted with the oblong shell and plate heat exchanger without oil in a refrigerant loop using R-l34a, R-407C and R-410A. An experimental refrigerant loop has been developed to measure the condensation heat transfer coefficient h$_{r}$ and frictional pressure drop $\Delta$p$_{f}$ of the various refrigerants in a vertical oblong shell and plate heat exchanger. The effects of the refrigerant mass flux(40∼80kg/$m^2$s), average heat flux(4∼8kW/$m^2$), refrigerant saturation temperature(30∼4$0^{\circ}C$) and vapor quality of refrigerants on the measured data were explored in detail. Similar to the case of a plate heat exchanger, even at a very low Reynolds number, the flow in the oblong shell and plate heat exchanger remains turbulent. A comparison of the performance of the various refrigerants revealed that R-410A had the highest heat transfer performance followed by R-l34a, and R-407C had the lowest performance of the refrigerants tested. The pressure drops were also reported in this paper. The pressure drops for R-410A were approximately 45% lower than those of R-l34a. R-407C had 30% lower pressure drops than R-l34a. Experimental results were compared with several correlations which predicted condensation heat transfer coefficients and frictional pressure drops. Comparison with the experimental data showed that the previously proposed correlations gave unsatisfactory results. Based on the present data, empirical correlations of the condensation heat transfer coefficient and the friction factor were proposed.tor were proposed.sed.

The Fatigue Evaluation of Structural Steel Members under Variable-Amplitude Loading (변동하중을 받는 강구조부재의 피로거동 해석)

  • Chang, Dong Il;Kwak, Jong Hyun;Bak, Yong Gol
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.8 no.2
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    • pp.167-175
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    • 1988
  • The principle objective of this study is to evaluate the fatigue behavior of structural steel components of highway bridges subjected to service stresses. The main aspects of this investigation are; 1) a measurement and statistical analysis of service stress cycles observed in highway bridge. 2) fatigue tests under equivalent constant-amplitude(CA) loading and simulated variable-amplitude(VA) loading 3) a evaluation of the fatigue behavior under VA-loading by eqivalent root mean cube (RMC) stress range. Theoretically, the RMC model is adequate in evaluation of fatigue behavior under VA-loading, because the regression coefficient (m) of crack growth rate is 3 approximately. The result of fatigue test shows that the RMC model is fitter than the current RMS model in fatigue evaluation under VA-loading. The interaction effects and sequence effects under VA-loading affect little fatigue life of structural components. As the transition rate of stress ranges is higher, the crack growth rate is higher.

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A Study on the Stress Relief Cracking of HSLA-100 and HY-100 steels (HSLA-100강 및 HY-100강의 응력제거처리 균열에 관한 연구)

  • 박태원;심인옥;김영우;강정윤
    • Journal of Welding and Joining
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    • v.14 no.3
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    • pp.48-57
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    • 1996
  • A study was made to examine the characteristics of base metal and stress relief cracking(SRC) of heat affected zone(HAZ) for HY-100 and Cu-bearing HSLA-100 steels. The Gleeble thermal/mechanical simulator was used to simulate the SRC/HAZ. The details of mechanical properties of base plate and SRC tested specimens were studied by impact test, optical microscopy and scanning electron microscopy. The specimens were aged at $650^{\circ}C$ for HSLA-100 steel and at $660^{\circ}C$ for HY-100 steel and thermal cycled from $1350^{\circ}C$ to $25^{\circ}C$ with a cooling time of $\Delta$t_${800^{circ}C/500^{circ}C}$=21sec. corresponds to the heat input of 30kJ/cm. The thermal cycled specimens were stressed to a predetermined level of 248~600MPa and then reheated to the stress relief temperatures of $570~620^{\circ}C$. The time to failure$(t_f)$ at a given stress level was used as a measure of SRC susceptibility. The strength, elongation and impact toughness of base plate were greater in HSLA-100 steel than in HY-100 steel. The time to failure was decreased with increasing temperature and/or stress. HSLA-100 steel was more susceptible to stress relief cracking than HY-100 steel under same conditions. It is thought to be resulted from the precipitation of $\varepsilon$-Cu phase by dynamic self diffusion of solute atoms. By the precipitation of $\varepsilon$-Cu phase, the differential strengthening of grain interior relative to grain boundary may be greater in the Cu-bearing HSLA-100 steel than in HY-100 steel. Therefore, greater strain concentration at grain boundary of HSLA-100 steel results in the increased SRC susceptibility. The activation energies for SRC of HSLA-100 steel are 103.9kcal/mal for 387MPa and 87.6kcal/mol for 437MPa and that of HY-100 steel is 129.2kcal/mol for 437MPa.

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