• Title/Summary/Keyword: $(La,\

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Structural and Dielectric Properties of PLT Thin Plates (PLT 박편의 구조 및 유전특성)

  • Lee, Jae-Man;Park, Ki-Cheol
    • Journal of Sensor Science and Technology
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    • v.7 no.1
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    • pp.51-60
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    • 1998
  • La-modified $PbTiO_{3}$(PLT) thin plates were prepared for the fabrication of PLT pyroelectric IR sensors. The effects of the preparation parameters such as tile sintering temperature, the La content, and the ambient powder quantity, on the microstructural and dielectric properties of PLT thin plates were investigated by X-ray diffraction, scanning electron microscope, and measurements of relative density and dielectric properties. With an increased La content, the tetragonality c/a was decreased but the densification and the grain size were increased, which is considered to be due to the increased Pb vacancy concentration to maintain charge neutrality at the increased of La content. When the quantity of the ambient powder wvas increased, the tetragonality was slightly increased, which is believed io be due to the reduced evaporation of PbO. But the e(fect is insignificant compared to that of La content. The dielectric constant at room temperature was increased and the Curie temperature was decreased in accordance with the decreased tetragonality ratio c/a with the increase of La content. The dielectric constant and tan ${\delta}$ of $500{\mu}m$ thick PLT thin plate with 10 wt% excess PbO and 10 mol% La contant sintered at $1250^{\circ}C$ for 2 hours in ambient powder of $0.02\;g/cm^{3}$ were 360 and 0.02, respectively.

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Assessing the association of single nucleotide polymorphisms in thyroglobulin gene with age of puberty in bulls

  • Fernandez, Maria Elena;Goszczynski, Daniel Estanislao;Prando, Alberto Jose;Peral-Garcia, Pilar;Baldo, Andres;Giovambattista, Guillermo;Liron, Juan Pedro
    • Journal of Animal Science and Technology
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    • v.56 no.5
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    • pp.17.1-17.4
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    • 2014
  • Puberty is a stage of sexual development determined by the interaction of many loci and environmental factors. Identification of genes contributing to genetic variation in this character can assist with selection for early pubertal bulls, improving genetic progress in livestock breeding. Thyroid hormones play an important role in sexual development and spermatogenic function. The objective of this study was to evaluate the association between single nucleotide polymorphisms (SNPs) located in thyroglobulin(TG) gene with age of puberty in Angus bulls. Four SNPs were genotyped in 273 animals using SEQUENOM technology and the association between markers and puberty age was analyzed. Results showed a significant association (P < 0.05) between these markers and puberty age estimated at a sperm concentration of 50 million and a progressive motility of 10%. This is the first report of an association of TG polymorphisms with age of puberty in bulls, and results suggest the importance of thyroidal regulation in bovine sexual development and arrival to puberty.

The Effect of La2O3 Loading on the Performance of Ni-La2O3-Ce0.8Zr0.2O2 Catalysts for Steam Reforming of Methane (수증기 개질 반응에서 Ni-La2O3-Ce0.8Zr0.2O2 촉매의 La2O3 함량이 촉매의 성능에 미치는 영향)

  • YOO, SEONG-YEUN;KIM, HAK-MIN;KIM, BEOM-JUN;JANG, WON-JUN;ROH, HYUN-SEOG
    • Transactions of the Korean hydrogen and new energy society
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    • v.29 no.5
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    • pp.419-426
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    • 2018
  • $Ni-La_2O_3-Ce_{0.8}Zr_{0.2}O_2$ catalysts with various $La_2O_3$ loading were investigated for hydrogen production from steam reforming of methane (SRM). The $La_2O_3$ loading influenced the physicochemical properties of $Ni-La_2O_3-Ce_{0.8}Zr_{0.2}O_2$ catalysts such as BET surface area, Ni dispersion, Ni size and reducibility. Among the prepared catalysts, $Ni-70La_2O_3-Ce_{0.8}Zr_{0.2}O_2$ catalyst showed the highest activity and stability at a very high gas hourly space velocity (GHSV) of $932,556h^{-1}$. This is mainly due to high Ni dispersion, small Ni size and high reducibility.

A Confirmation of the Minimum Moving Time to the Stop-Motion in the (sLa-Camera-pLa)Type ((sLa-Camera-pLa)타입에서 Stop-Motion 방식의 최소 구동 시간 입증)

  • Kim, Soon Ho;Kim, Chi Su
    • KIPS Transactions on Software and Data Engineering
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    • v.6 no.5
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    • pp.223-228
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    • 2017
  • SMT is an device that picks up electronic components and does precise placing onto PCBs. In order to do this, it stops in front of a camera installed in the middle to go over vision inspection. And after that it is move for placing. There are 16 different types of routes in this process. This paper compared to the moving time of three methods in the (sLa-Camera-pLa)type. The first method is stopping in front of the camera for vision inspection and placing components onto PCBs(stop-motion). The second method is moving in front of the camera for vision inspection without stopping(fly1-motion). The third method is inspecting the components when the speed of the X axis, the Y axis is the best and is placing components onto PCBs(fly2-motion). This paper shows the moving time of three methods is same. Therefore we proved that the stop-motion method can be placing in the fastest time without changing structure of the device in the (sLa-Camera-pLa)type.

An alpha-lipoic acid-decursinol hybrid compound attenuates lipopolysaccharide-mediated inflammation in BV2 and RAW264.7 cells

  • Kwon, Mi-Youn;Park, Jiwon;Kim, Sang-Min;Lee, Jooweon;Cho, Hyeongjin;Park, Jeong-Ho;Han, Inn-Oc
    • BMB Reports
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    • v.52 no.8
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    • pp.508-513
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    • 2019
  • In this study, the anti-inflammatory effects of ${\alpha}-lipoic$ acid (LA) and decursinol (Dec) hybrid compound LA-Dec were evaluated and compared with its prodrugs, LA and Dec. LA-Dec dose-dependently inhibited lipopolysaccharide (LPS)-induced nitric oxide (NO) generation in BV2 mouse microglial cells. On the other hand, no or mild inhibitory effect was shown by the Dec and LA, respectively. LA-Dec demonstrated dose-dependent protection from activation-induced cell death in BV2 cells. LA-Dec, but not LA or Dec individually, inhibited LPS-induced increased expressions of induced NO synthase (iNOS) and cyclooxygenase-2 (COX-2) proteins in a dose-dependent manner in both BV2 and mouse macrophage, RAW264.7 cells. Furthermore, LA-Dec inhibited LPS-induced expressions of iNOS, COX-2, interleukin-6, tumor necrosis $factor-{\alpha}$, and $interleukin-1{\beta}$ mRNA in BV2 cells, whereas the same concentration of LA or Dec was ineffective. Signaling studies demonstrated that LA-Dec inhibited LPS-activated signal transducer and activator of transcription 3 and protein kinase B activation, but not nuclear factor-kappa B or mitogen-activated protein kinase signaling. The data implicate LA-Dec hybrid compound as a potential therapeutic agent for inflammatory diseases of the peripheral and central nervous systems.

Left Atrial Velocity Vector Imaging Can Assess Early Diastolic Dysfunction in Left Ventricular Hypertrophy and Hypertrophic Cardiomyopathy

  • Se-Jung Yoon;Sungha Park;Eui-Young Choi;Hye-Sun Seo;Chi Young Shim;Chul Min Ahn;Sung-Ai Kim;Jong-Won Ha
    • Journal of Cardiovascular Imaging
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    • v.31 no.1
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    • pp.41-48
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    • 2023
  • BACKGROUND: The function of left atrium (LA) is difficult to assess because of its ventricle-dependent, dynamic movement. The aim of this study was to assess LA function using velocity vector imaging (VVI) and compare LA function in patients with hypertrophic cardiomyopathy (HCMP) and left ventricular hypertrophy (LVH) with normal controls. METHODS: Fourteen patients with HCMP (72% male, mean age of 52.6 ± 9.8), 15 hypertensive patients with LVH (88% male, mean age of 54.0 ± 15.3), and 10 age-matched controls (83% male, mean age of 50.0 ± 4.6) were prospectively studied. Echocardiographic images of the LA were analyzed with VVI, and strain rate (SR) was compared among the 3 groups. RESULTS: The e' velocity (7.7 ± 1.1; 5.1 ± 0.8; 4.5 ± 1.3 cm/sec, p = 0.013), E/e' (6.8 ± 1.6; 12.4 ± 3.3; 14.7 ± 4.2, p = 0.035), and late diastolic SR at mid LA (-1.65 ± 0.51; -0.97 ± 0.55; -0.82 ± 0.32, p = 0.002) were significantly different among the groups (normal; LVH; HCMP, respectively). The e' velocity, E/e', and late diastolic SR at mid LA were significantly different between normal and LVH (p = 0.001; 0.022; 0.018), whereas LA size was similar between normal and LVH (p = 0.592). The mean late diastolic peak SR of mid LA was significantly correlated with indices of diastolic function (E/e', e', and LA size). CONCLUSIONS: The SR is a useful tool for detailed evaluation of LA function, especially early dysfunction of LA in groups with normal LA size.

Magnetic properties of Sr-ferrite by La-Co substitution (La-Co 치환량에 따른 스트론튬 페라이트의 자기특성)

  • 장세동
    • Resources Recycling
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    • v.11 no.5
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    • pp.16-20
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    • 2002
  • This experiment was carried out to examine the effects of La-Co substitution on Sr-ferrite. The magnetic properties of calcined and sintered materials varied with the substitutional amount of La and Co elements in Sr-ferrite. Anisotropy field and coercivity for Sr ferrite were increased with raising La-Co substitution amounts. The microstructure observation for Sr ferrite substituted by La-Co revealed that La-Co inhabited grain growth during calcination and promoted lateral grain growth during sintering. The relationship between $B_{r}$ and $_{i}$ /$H_{c}$ for La-Co substituted Sr-ferrite was found to be $B_{r}$$≒0.097_{i}$ /$H_{c}$/+4500. In case of $SrFe_{12}$ $O_{19}$, $B_{r} was 4090 G and $_{ i}$$H_{c}$ was 3560 Oe, but $B_{r}$ was 4080 G and and $_{i}$ $H_{c}$ was 4800 Oe for $Sr_{0.7}$ $La_{0.3}$ $Fe_{11.7}$ /$Co_{0.3}$ $O_{19}$.

Preparation of Metal Hydrides Using Chemical Synthesis and Hydriding Kinetics (화학적 합성법에 의한 금속수소화물의 제조 및 수소화 속도론적 연구)

  • Lee, Yun Sung;Oh, Jae Wan;Moon, Sung Sik;Nahm, Kee Suk
    • Applied Chemistry for Engineering
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    • v.9 no.2
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    • pp.255-260
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    • 1998
  • Metal hydrides, $LaNi_5$ and $LaNi_{4.5}Al_{0.5}$, were prepared using chemical synthetic method, and their physical properties were examined using various analytic techniques such as TGA, XRD, SEM and EDX. The activation of the chemically prepared $LaNi_5$ and $LaNi_{4.5}Al_{0.5}$ was achieved by two hydriding/dehydriding cycles only. The miasurements of P-C-T curves revealed that 6 and 5.5 hydrogen atoms were stored in LaNi5and $LaNi_{4.5}Al_{0.5}$, respectively. The hydriding reaction rated for $LaNi_{4.5}Al_{0.5}$ were measured by the method of initial rates. It was found that the shrinking unreacted core model could be applied for the analysis of hydriding kinetics of $LaNi_5$. The rate controlling step of this reaction was the dissociative chemisorption of hydrogen molecules on the surface of $LaNi_5$. The activation energy was $9.506kcal/mol-H_2$. The rates measured in the temperature range from 273 to 343K and in pressure difference ($P_o-P_{eq}$) range form 0.25 to 0.66atm could be expressed as the following equation ; $\frac{dX}{dt}=4.636(P_o-P_{eq})$ exp($\frac{-9506}{RT}$).

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Preparation of dielectric Bi4-xLaxTi3O12 (x~2) from K2La2Ti3O10 via exfoliation and restacking routes (박리화와 재적층법을 통한 K2La2Ti3O10부터 유전성 Bi4-xLaxTi3O12(x~2)의 합성)

  • Jeon, A Young;Ko, Jieun;Kim, Jong-Young
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.23 no.1
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    • pp.14-19
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    • 2013
  • We have successfully synthesized $Bi_{4-x}La_xTi_3O_{12}$ (x~2) having Aurivillius-type layered perovskite structure from exfoliated layered perovskite oxide of $K_2La_2Ti_3O_{10}$ with Ruddlesden-Popper structure. The reaction between the exfoliated lanthanum titanate nanosheets and BiOCl nanocrystal resulted in the formation of polycrystalline $Bi_{4-x}La_xTi_3O_{12}$ (x~2) after heating above $700^{\circ}C$. Colloidal suspension of the nanosheets could be obtained by intercalating ethylamine (EA) into the protonated lanthanum titanate, $H_2La_2Ti_3O_{10}$, derived from $K_2La_2Ti_3O_{10}$. Transmission electron microscopic (TEM) analysis show that the exfoliated lanthanium titanate nanosheets have a thickness of a few nano meters. According to X-ray diffraction (XRD) analysis, the exfoliated lanthanium titanate was found to be transformed into $Bi_{4-x}La_xTi_3O_{12}$ (x~2) after restacking with BiOCl and subsequent thermal treatment at > $700^{\circ}C$.

Microstructure and dielectric properties in the La2O3-doped BaTiO3 system (La2O3 첨가에 따른 BaTiO3의 미세구조 및 유전특성)

  • Choi, Woo-Jin;Moon, Kyoung-Seok
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.30 no.3
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    • pp.103-109
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    • 2020
  • The effect of La2O3 addition on the crystalline phase, microstructure, and dielectric properties of BaTiO3 has been studied as a function of the amounts of La2O3. 0.3 mol% TiO2-excess BaTiO3 powder was synthesized by solid-state reaction, and then the powder compacts with various amounts of La2O3 were sintered at 1250℃ for 2 hours. Room temperature XRD showed changes in the lattice parameters and a decrease of tetragonality (c/a) as the amounts of La2O3 increased. It can be explained that the phase transition from tetragonal to cubic phase occurred because La3+ replaced Ba2+ site, which increased the instability of the tetragonal phase. As La2O3 was added over 0.1 mol%, the critical driving force for growth (Δgc) increased over maximum driving force (Δgmax). As the result, the grain size decreased with La2O3 addition. Dielectric constant decreased as the amounts of La2O3 increased, which was analyzed with crystal structure and microstructure.