• Applied Chemistry for Engineering
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• v.10 no.8
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• pp.1129-1135
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• 1999

The reduction of $SO_2$ by CO over supported cobalt catalysts was investigated within the temperature range of $350{\sim}550^{\circ}C$, initial $SO_2$ concentration of 1000~10000 ppm, $CO/SO_2$ molar ratio of 1.0~3.0 and space velocity of $5000{\sim}15000h^{-1}$. Several types of supports such as ${\gamma}-Al_2O_3$, $TiO_2$ were tested. The $SO_2$ conversion and selectivity to elemental sulfur were investigated using a differential fixed bed reactor at atmospheric pressure. The catalyst prepared by wet impregration of 5 wt % cobalt on ${\gamma}-Al_2O_3$ showed $SO_2$ conversion higher than 90% and COS yield lower than 6% at temperature above $400^{\circ}C$. The optimum $CO/SO_2$ molar ratio was investigated as 2.0. At higher $CO/SO_2$ molar ratio, the $SO_2$ conversion became higher but the main product was COS. The effect of $SO_2$ concentration and space velocity over $SO_2$ conversion and COS yield was not appreciable in the experimental range. The activated cobalt phase was detected as $CoS_2$ and the $CoS_2$ phase unchanged even after reaction.

• Journal of the Korean Ceramic Society
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• v.39 no.8
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• pp.721-727
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• 2002

In order to overcome trade-off among compositions, process and properties of the glasses with high PbO-base composition for PDP Rib, we studied glass crystallization and crystallization kinetics by Differential Thermal Analysis(DTA). Glass powder was obtained through melting/cooling/grinding, with 3 wt%TiO2 addition for the crystal nucleation and growth in $62PbO-19B_2O_3-10SiO_2-9(Al_2O_3-K_2O-BaO-ZnO)$(in wt%) composition glass. This powder was heat-treated for 1 to 10 h at $445^{\circ}C$ for nucleation. DTA measurements were performed to obtain the crystallization peak with $5∼25^{\circ}C/min$ heating rates. DTA crystallization peak temperature increased with increasing the heating rate and decreased with increasing the heating time. Because the Avrami parameter (n) was approximately 1, the surface crystallization occurred. The maximum nucleation time was 2 h.

• KSBB Journal
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• v.6 no.4
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• pp.425-429
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• 1991

Porous glasses were prepared from $TiO_2$ containing borosilicate glass by the phase separation. Pore distribution and surface area of porous glasses were invesigated by SEM and porosimeter. As temperature and heating time increase. The pore size and volume increased, but the specific surface area decreased above the critical temperature. The specific surface area and pore size showed more sensitive change on the variation of heating temperature than of heating time.

• Journal of Conservation Science
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• v.22
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• pp.43-60
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• 2008

This study is investigated the characteristics and the comparison on blackware and whiteware at Gilmyeong-ri kilns, located Poncheon-si, Geonggi province at AD 19c using scientific analysis. It is measured by scientific analysis classified as microstructure observation, physical methods which involved chromaticity, specific gravity, absorption ratio and porosity, and chemical analysis of components of body and glaze. As a result, a particle and a pore of body surface appeared differently by the degree of vitrification. In glaze, Blackware have better on good vitrification than whiteware in the microstructure observation. The physical characteristics of chromaticity, specific gravity, absorption ratio and porosity differed according to degree of vitrification rather than porcelain types. In composition, body of blackware have higher ratio of $Fe_2O_3$ and $TiO_2$ than of whiteware. Also glaze of blackware have higher ratio of $Fe_2O_3$ and $TiO_2$, and lower ratio of $SiO_2$ and $Al_2O_3$ than whiteware. Especially, blackware have higher ratio in the composition of CaO and $P_2O_5$ by which ash is used or not.

• Korean Journal of Soil Science and Fertilizer
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• v.34 no.6
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• pp.373-379
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• 2001

The weathering rates and change of chemical composition of 6 residual Entisols derived from granite, granite-gneiss, limestone, sandstone, shale, amd basalt in Korea were studied. The chemical composition of each profile with parent rocks were determined using XRF with the physico-chemical properties and the morphology of soils. In the A horizons of all the soils except Euiseong series, the content of clay, organic matter and cation exchange capacity(CEC) showed higher than those of C horizon, but bulk density and pH showed lower than C horizon. Clay content in the soil from sandstone was decrease with soil depth, which may caused by the elluriation. In total element analysis. $SiO_2$ was high in the soil from granite. granite-gneiss, sandstone and compare with basalt and limestone. $Fe_2O_3$ and MgO was high in the soil from basalt, limestone and shale compare with granite. granite-gneiss and sandstone. And ignition loss was particularly high in the soil from basalt and limestone. The rate of element loss was higher in base cations(Ca, K, Mg, Na) than Si, Al, Fe in the soils. The concentrations of $TiO_2$ in the A horizon compare with that of the C horizon was due to resulting from losses of other less stable elements existed. Considering with relative rate of each elements in soils, $SiO_2$ and $Al_2O_3$ which originated from sandstone and granite, granite-gneiss, sandstone, shale, and basalt were lost higher than those from lime tone, but loss of basic cations were more in the soil from limestone which may be rapid weathering of calcite. The magnitude of losses of the overall elements were increased in the order of the soils from sandstone and granite ${\gg}$ limestone and shale) granite-gneiss and basalt.

• Journal of the Korean Ceramic Society
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• v.26 no.5
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• pp.682-690
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• 1989

Fine mullite powder was prepared by colloidal sol-gel route. Boehmite as a starting material of Al2O3 and silica sol or fumed silica as a starting material of SiO2 were used. $\alpha$-Al2O3, TiO2 and ZrO2 were used as seeding materials. The combination of boehmite and silica was found to be the stoichiometric mullite powder. Techniques for drying used were spray drying, freeze drying, reduced pressure evaporation and drying in a oven. The gelled powder was heated at 130$0^{\circ}C$ for 100min and was attrition-milled for 1~3hrs. The mullite powder obtained was composed of submicrometer, uniform and spherical particles with a narrow size distribution. The mullite powder was characterized by BET, SEM, XRD and IR spectroscopy.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2010.06a
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• pp.11-11
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• 2010

Thin-film-transistors (TFTs) that can be deposited at low temperature have recently attracted lots of applications such as sensors, solar cell and displays, because of the great flexible electronics and transparent. Transparent and flexible transistors are being required that high mobility and large-area uniformity at low temperature [1]. But, unfortunately most of TFT structures are used to be $SiO_2$ as gate dielectric layer. The $SiO_2$ has disadvantaged that it is required to high driving voltage to achieve the same operating efficiency compared with other high-k materials and its thickness is thicker than high-k materials [2]. To solve this problem, we find lots of high-k materials as $HfO_2$, $ZrO_2$, $SiN_x$, $TiO_2$, $Al_2O_3$. Among the High-k materials, $Al_2O_3$ is one of the outstanding materials due to its properties are high dielectric constant ( ~9 ), relatively low leakage current, wide bandgap ( 8.7 eV ) and good device stability. For the realization of flexible displays, all processes should be performed at very low temperatures, but low temperature $Al_2O_3$ grown by sputtering showed deteriorated electrical performance. Further decrease in growth temperature induces a high density of charge traps in the gate oxide/channel. This study investigated the effect of growth temperatures of ALD grown $Al_2O_3$ layers on the TFT device performance. The ALD deposition showed high conformal and defect-free dielectric layers at low temperature compared with other deposition equipments [2]. After ITO was wet-chemically etched with HCl : $HNO_3$ = 3:1, $Al_2O_3$ layer was deposited by ALD at various growth temperatures or lift-off process. Amorphous InGaZnO channel layers were deposited by rf magnetron sputtering at a working pressure of 3 mTorr and $O_2$/Ar (1/29 sccm). The electrodes were formed with electron-beam evaporated Ti (30 nm) and Au (70 nm) bilayer. The TFT devices were heat-treated in a furnace at $300^{\circ}C$ and nitrogen atmosphere for 1 hour by rapid thermal treatment. The electrical properties of the oxide TFTs were measured using semiconductor parameter analyzer (4145B), and LCR meter.

• Journal of Hydrogen and New Energy
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• v.25 no.3
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• pp.247-254
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• 2014

The synthesis of Fischer-Tropsch oil is the catalytic hydrogenation of CO to give a range of products, which can be used for the production of high-quality diesel fuel, gasoline and linear chemicals. Our cobalt based catalyst was prepared Co/alumina, silica and titania by the incipient wet impregnation of the nitrates of cobalt and promoter with supports. Cobalt catalysts was calcined at $350^{\circ}C$ before being loaded into the FT reactors. After the reduction of catalyst has been carried out under $450^{\circ}C$ for 24hrs, FT reaction of the catalyst has been carried out at GHSV of 4,000/hr under $200^{\circ}C$ and 20atm. From these test results, we have obtained the results as following ; in case of 12wt% Co-supported $Al_2O_3$, $SiO_2$ and $TiO_2$ catalysts, maximum activities of the catalysts were appeared at the promoters of Mn, Mo and Ce respectively. The activity of 12wt% $Co/Al_2O_3$ added a Mn promoter was about 3 times as high as that of 12wt% $Co/Al_2O_3$ catalyst without promoters. When it has been the experiment at the range of reaction temperature of $200{\sim}220^{\circ}C$ and GHSV of 1,546~5,000/hr, the results have shown generally increasing the activities with the increase of reaction temperature and GHSV.

• Journal of the Korean Magnetics Society
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• v.3 no.1
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• pp.23-28
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• 1993

Thin films of soft magnetic Fe-Hf-C alloys with nanoscale crystallites were investigated in this study. The films were fabricated by an RF diode magnetron sputtering apparatus and subsequently annealed in vacuum. The soft magnetic properties of the films were observed to differ depending on the different substrates such as Corning 7059, $CaTiO_3$ and $Al_2O_3-TiC$ with various underlayer(Cr, $SiO_2$) thickness. This results may be due to the interdiffusion between the substrate and the magnetic layer and/or between the underlayer and the magnetic layer, rather than the microstructural change such as grain size. The Fe-Hf-C films with high permeability up to 4000(at 1 MHz) and saturation magnetization up to 16 kG were obtained in the vicinity of phase boundary between the crystalline and amorphous state when the size of ${\alpha}-Fe$ grains is about 5 nm. And also the films were found to have thermal stability up to $600^{\circ}C$.

• Journal of the Korean Ceramic Society
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• v.31 no.9
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• pp.981-988
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• 1994

Crystallizable glasses with precipitation of celsian were prepared for the purpose of insulating dielectric layers for the devices such as integrated circuit substrates. Crystallization behavior of these glasses were studied by DTA, SEM, XRD analysis and by the measurement of dielectric properties. The base composition of the glass-ceramic consists in weight percent of 30% SiO2, 10% Al2O3, 26% BaO, 10% CaO, 10% ZnO, 8%TiO2 and 6% B2O3. 2-6 wt% Y2O3 were selected as the nucleating agent to promote monoclinic celsian formation. As a result, in barium-rich glasses containing 4~6wt% Y2O3 , monoclinic celsian was developed as major crystalline phase in the temperature range of 850~90$0^{\circ}C$. Also, the dielectric constant and quality factor of these glass-ceramics were about 9 and more than 1000, respectively.