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http://dx.doi.org/10.3746/jkfn.2006.35.7.874

Analysis of Enantiomeric Composition of Chiral Flavor Components from Dried Ginger (Zingiber afficinale Roscoe)  

Seo, Hye-Young (Dept. of Food and Nutrition, Chosun University)
No, Ki-Mi (Dept. of Food and Nutrition, Chosun University)
Shim, Seong-Lye (Dept. of Food and Nutrition, Chosun University)
Ryu, Keun-Young (Dept. of Food and Nutrition, Chosun University)
Han, Kyu-Jae (Dept. of Applied Science, Chosun University)
Gyawali, Rajendra (Dept. of Applied Science, Chosun University)
Kim, Kyong-Su (Dept. of Food and Nutrition, Chosun University)
Publication Information
Journal of the Korean Society of Food Science and Nutrition / v.35, no.7, 2006 , pp. 874-880 More about this Journal
Abstract
The volatile compounds of Zingiber officinale Roscoe were extracted by simultaneous steam distillation and extraction (SDE) method and identified with gas chromatigraphy/mass spectrometer (GC/MS) analysis. Enantiomeric compositions of chiral compounds were determined by multidimensional gas chromatography/mass spectrometer (MDGC/MS). A total of 57 compounds were indentified and quantified, including zingiberene, ${\beta}-sesquiphellandrene$, ${\beta}-bisabolene$, $(E,E)-{\alpha}-farnesene$ and ${\alpha}-curcumene$. Among them, zingiberene (38.41%) was founds as the predominantly abundant component. ${\alpha}-Pinene$ and nerolidol in dried ginger were detected by high enantiomeric purity (>96%) for (S)-form, and ${\beta}-pinene$ was detected only (R)-form. The enantiomeric composition of ${\alpha}-terpineol$ revealed 72.0% for (R)-form, and linalool and 4-terpineol showed mixtures of both enantiomers. (S)-Enantiomer was the major enantiomer of limonene having enatiomeric excess of 17.2%. Hence the enantiomeric composition of these compounds can be used as parameter for authenticty control of Zingiber officinale.
Keywords
Zingiber officinale; chiral compounds; enantiomeric composition; MDGC;
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