Browse > Article
http://dx.doi.org/10.3746/jkfn.2006.35.10.1412

Analysis of Formaldehyde and Acetaldehyde in Alcoholic Beverage  

Park, Young-Seok (Dept. of Food Science and Technology, Chungnam National University)
Lee, Yun-Jeung (Dept. of Food Science and Technology, Chungnam National University)
Lee, Ki-Teak (Dept. of Food Science and Technology, Chungnam National University)
Publication Information
Journal of the Korean Society of Food Science and Nutrition / v.35, no.10, 2006 , pp. 1412-1419 More about this Journal
Abstract
Concentrations of formaldehyde and acetaldehy de were respectively analysed in forty-five alcoholic beverages obtained from the market. After derivatization with PFBHA, GC-ECD and GC-MSD were employed for analysis. The peak area of aldehyde oximes (derivatives with PFBHA) increased with the increasing ethanol content (5%, 10%, 15%, 20% and 40%). When three-point calibration corves for the selected ethanol concentration (5, 13, 21 and 40%, v/v) were studied, suitable linearity against ethanol concentration was observed only under 5, 13, and 21% (ethanol, v/v). After analysis, maximum content of formaldehyde (average of 0.272 ppm) and acetaldehyde (average of 15.262 ppm) among the observed 45 alcoholic beverages was found from whisk (2 species) while minimum content of formaldehyde (average of 0.009 ppm) and acetaldehyde (average of 0.805 ppm) was found from diluted soju (4 species).
Keywords
formaldehyde; acetaldehyde; oxime derivatization; alcoholic beverages;
Citations & Related Records
연도 인용수 순위
  • Reference
1 Ng L-K, Lafontaine P, Harnois J. 2000. Gas chromato graphic-mass spectrometric analysis of acids and phenols in distilled alcohol beverages: Application of anion-exchange disk extraction combined with in-vial elution and silylation. J Chromatogr A 873: 29-38   DOI   ScienceOn
2 Borzani WM, Vairo LR, Koskimizu IH, Melo Cruz MRD, Perego LJ. 1981. Kinetics of amyl alcohol production during ethanol fermentation of blackstrap molasses. Biomass 1: 115-126   DOI   ScienceOn
3 장동석, 신동화, 정덕화, 김창민, 이인선. 2003. 자세히 쓴 식품위생학. 정문각, 서울
4 Cho YH, Park SO, Woo SM, Hahm TS. 2003. Studies on the content of formaldehyde in food packaging paper. J Kor Soc Environmental Anal 6: 213-217
5 Yang ST, Lee HS. 2000. A study for determination of formaldehyde in water. J KSWQ 16: 275-282
6 Helander A, Tottmar O. 1988. Effect of acute ethanol administration on human blood aldehyde dehydrogenase activity. Alcohol Clin Exp Res 12: 643-646   DOI   ScienceOn
7 Jeong JY, Park SH, Yi GY, Oh SM. 2000. Analytical method for analyzing formaldehyde using 2,4-DNPH and gas chromatograghy/FID,NPD. J Korean Ind Hyg Assoc 10: 126- 146
8 Wardencki W, Sowinski P, Curylo J. 2003. Evaluation of headspace solid-phase microextraction for the analysis of volatile carbonyl compounds in spirits and alcoholic beverages. J Chromatogr A 984: 89-96   DOI   ScienceOn
9 US Environmental Protection Agency Method 554. 1992. Determination of carbonyl compounds in drinking water by dinitrophenylhydrazine derivatization and high performance liquid chromatography
10 환경부. 2004. 먹는 물 수질 감시항목 운영 지침 및 시험방법
11 Korea Food and Drug Administration. 2005. Food Code
12 Kim KW, Yang JS, Lee JS, Cho YS. 1994. Activity of alcohol dehydrogenase and ethanol, acetaldehyde levels in normal adults blood. J Korean Ind Hyg Assoc 4: 240-247
13 US Environmental Protection Agency Method 556. 1998. Determination of carbonyl compounds in drinking Water by pentafluorobenzylhydroxylamine derivatization and capillary gas chromatography with electron capture detection
14 Kim JH, Cho ES, Park SK, Kim JH, Lim YT, Pyo HS. 2004. A study on the unregulated contaminants management of drinking water-1,4-dioxane, monochloroacetic acid, monobromoacetic acid, dibromoacetic acid, formaldehyde. 대한상하수도학회, 한국물환경학회 2004년도 공동추계학술발표회. p 72-75
15 Huh K, Lee TK, Park JM, Shin US. 1989. Preventive effect of ginseng butanol fraction against acetaldehyde-induced acute toxicity. Korea J Ginseng Sci 13: 5-7   과학기술학회마을
16 Sowinski P, Wardencki W, Partyka M. 2005. Development and evaluation of headspace gas chromatography method for the analysis of carbonyl compounds in spirits and vodkas. Analytica Chimica Acta 539: 17-22   DOI   ScienceOn
17 Cancho B, Ventura F, Galceran T. 2001. Determination of aldehydes in drinking water using pentafluorobenzylhydroxylamine derivatization and solid-phase microextraction. J Chromatogr A 943: 1-13   DOI   ScienceOn
18 국세청. 2001. 주세법, 인지세법, 증권거래세법 해석편람
19 Shin SH, Ahn SH. 2006. The study on the measurement of formaldehyde in saliva and urine by GC-MS. Anal Sci Tech 19: 149-154