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http://dx.doi.org/10.4313/TEEM.2002.3.3.029

Preparation and Characterization of β-C3N4 in Presence of Seed Carbon Nitride Films Deposited by Laser-Electric Discharge Method  

Kim, J.I. (School of information technology, Korea University of Technology and Education)
Zorov, N.B. (Department of Laser Chemistry, Moscow state University)
Burdina, K.P (Department of Laser Chemistry, Moscow state University)
Publication Information
Transactions on Electrical and Electronic Materials / v.3, no.3, 2002 , pp. 29-33 More about this Journal
Abstract
A procedure was developed for preparing bulk carbon nitride crystals from a polymeric $\alpha$ -C$_3$N$\_$4.2/ at high pressure and temperature in the presence of seeds of crystalline carbon nitride films prepared by a high voltage discharge plasma combined with pulsed laser ablation of graphite target. The samples were evaluated by x-ray photoelectron spectroscopy (XPS), infrared (IR) spectroscopy, Auger electron spectroscopy (AES), secondary-ion mass spectrometry (SIMS), scanning electron microscopy (SEM) and x-ray diffraction (XRD). Notably, XPS studies of the film composition before and after thermobaric treatments demonstrate that the nitrogen composition in $\alpha$ -C$_3$N$\_$4.2/ material initially containing more than 58% nitrogen decreases during the annealing process and reaches a common, stable composition of ~45%. The thermobaric experiments were performed at 10-77 kbar and 350-1200 $\^{C}$.
Keywords
Thermal annealing; Crys talline carbon nitride; XPS; XRD;
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1 M. Tabbal, P. Merel, S. Moisa, M. Chaker, A. Ricard, and M. Moisan, 'X-ray photoelectron spectroscopy of carbon nitride films deposited by graphite laser ablation in a nitrogen postdischarge', Appl. Phys. Lett, Vol. 69, No. 12, p. 1698, 1996   DOI   ScienceOn
2 D. Marton, K. J. Boyd, A. H. Al-Bayati, S. S. Todorov, and J. W. Rabalasis, 'Carbon nitride deposited using energetic species : A tow-phase system', Phys. Rev. Lett, Vol. 73, p. 118, 1994   DOI   ScienceOn
3 P. Hammer, N. M. Victoria, and F. Alvarez, 'Electronic structure of hydrogenated carbon nitride films', J. Vac. Sci. Technol., A, Vol. 16, p.2941, 1998   DOI   ScienceOn
4 C. Jama, V. Rousseau, O. Dessaux, and P. Goudmand, 'Carbon nitride CN$_x$ film deposition by IR laser ablation in a cold remote nitrogen plasma', Thin Solid Films, Vol. 302, p. 58, 1997   DOI   ScienceOn
5 M. Kohzaki, A. Matsumuro, T. Hayashi, M. Muramatsu, and K. Yamaguch, 'Preparation of carbon nitride thin films by ion-beam assisted deposition and their mecanical properties', Thin Solid Films Vol. 308/309, p. 239, 1997   DOI   ScienceOn
6 A. Y. Liu and M. L. Cohen, 'Prediction of new low compressibility', Science, Vol. 245, p. 841, 1989   DOI   ScienceOn
7 Jong-Il Kim and Seon-Gi. Bae, 'Preparation and characterization of crystalline carbon nitride', J. of KIEEME(in Korean), Vol. 14, No. 10, p. 835, 2001
8 H. W. Song, F. Z. Cui, X. M. He, W. Z. Li, and H. D. Li, 'Carbon nitride films synthesized by NHg-ion-assisted', J. Phys.: Conden. Matt., Vol. 6, p. 6125, 1994   DOI   ScienceOn
9 J. I. Kim, PhD. Thesis, 'Preparation of crystalline carbon nithde: thin films and bulk samples', M. V. Lomonosov Moscow State University, Moscow, 1999
10 S. Bhattacharya, C. Carinaud, and G. Turban, 'Spectroscopic determination of the structure of amorphous nitrogenated carbon films', J. Appl. Phys., Vol. 83, No. 8, p. 4491, 1998   DOI   ScienceOn
11 O. V. Kravchenko, K. P. Burdina, K. N. Semenenko, A. M. Matveev, G. M. Tarasova, and S. A. Kulinich 'Synthesis and some properties of amorphous carbon nitride C$_3N_4$', Exp. Geosci., Vol. 6, No. 2, p. 64,1997
12 Jong-Il Kim, 'Effect of a laser ablation on high voltage discharge plasma area for carbon nitride film deposition', J. of KIEEME(in Korean), Vol. 15, No. 6, p. 551,2002
13 Jong-Il Kim and Seon-Gi. Bae, 'Influence of a magnetic field on high voltage discharge plasma area for carbon nitride film deposition', J. of KIEEME(in Korean), Vol. 15, No. 2, p. 184, 2002
14 D. M. Teter and R. J. Hemley, 'Low-Compressibility Carbon Nithdes', Science, Vol. 271,p.53,1996   DOI   ScienceOn
15 P. Hammer, M. A. Baker, C. Lenardi, and W. Gissler, 'Synthesis of carbon nitride films at low temperature', J. Vac. Sci. Technol. A, Vol. 15, No. 1, p.107,1997   DOI   ScienceOn
16 R. Alexandrescu, F. Huisken, A. Crunteanu, S. Petcu, S. Cojocaru, S. Cireasa, and I. Morjan, 'Preparation of carbon lutride film powder by laser induced gas-phase reaction', Appl. Phys. A, Vol. 65, p.207,1997   DOI