This study has been carried out on the Pegmatites, Naedeogri Granites, Nonggeori Granites and Metasedimentary rocks in the middle area of Taebaeksan region to investigate the geochemical properties and possibility of productivity. Pegmatites are characterized by metamorphosed anatectic pegmatite and differentiated magmatic pegmatite, and are mixed type of rare-element pegmatite and mica-bearing pegmatite by the classification of Ginsburg(1979). The petrological type of the igneous rocks is thought to be calcalkali, subalkaline and peralumious. According to chemical variations against D. I., differentiation trends from Naedeogri and Nonggeori Granites through non-mineralized pegmatites to mineralized pegmatites are supposed. From the relationship between oxided and $SiO_2$, pegmatites and Nonggeori Granite have shown similar tendencies and bulk composition of pegmatites and similar to metasedimentary rocks near the intrusives. By judging the correlations of trace elements, it is elucidated that pegmatites adjacent to Naedeogri and Nonggeori Granites have been originated in magma differentiation from these granites and the others have been differentiated by remelting or partial melting from metasedimentary rocks. $Sp_5$, $Sp_8$, and $Sp_9$ pegmatites are considered as productive rocks, and $Sp_4$, $Sp_6$, $Sp_7$, $Sp_{10}$, $Sp_{11}$, and $Sp_{12}$ pegmatites and granites are supposed to have a weak productivity, in terms of element ratios related with Sn mineralizations. Tourmalines in productive pegmatites are formed under the circumstance of Li-poor granitoids and associated with pegmatites, and the others are seemed to be originated in metapelites and metapsammites which are not coexisting with an Al-saturating phase. Three types of chemical zoning are noticed in tourmalines: (1) apparently homogeneous compositional patterns, (2) a continuous core-to-rim zoning and, (3) a discontinuous core-to-rim zoning. From results of EPMA of tourmalines, Al, Mg and Ca increase closer to rim, while Fe decreases.