We have prepared diamine-benzoquinone polymer which was known to excellent water proofing, high adhesion strength and good anti-corrosive effect, and have investigate with the possibility of application as a high performance resin for coatings. First of all, the reactivity of diamine-benzoquinone has been described an example of polymer reaction with research trend. The polymer reaction was divided into the polymerization with several diamine-benzoquinone and urethane group. The synthetic resin was shown a high solubility. In case of polymer containing urethane, water absorption content, water proofing and mechanical properties were controlled with the content, water proofing and mechanical properties were controlled with the content of quinone. It was shown that an use of choice was a possible result for various coatings. Diamine-quinone polymer can be used as a new resin for coatings. In addition, the polymer containing a functional group was shown a useful applicability as a high performance resin.

The liposomes have been developed in many drugs and cosmetics fields. The liposomes prepared with main compounds of the intercellular lipids and lecithin. Amphiphile nonionic surfactants used for (PEG) n-sitosterol(n=5), diethanolamine cetylphosphate. The effect of gelation for liposomes have been on swelling reaction which have been mixed phospholipid with polyol-group at the high temperature. There were very good encapsulated properties of the active ingredients whether hydrophilic-group(magnesium ascorbyl phosphate, allantoin, sodium hyaluronate) and hydrophobic-group(vitamin-E acetate, vitamin-A palmitate). Optimum condition of liposomes were passed five times in the microfluidizer(700bar), wetting reaction temperature was at $95{\pm}5^{\circ}C$ for a hours. Particle size distribution of the vesicles should be within range 50-560nm(mean 200nm). The stability of liposomes for the course of time was stabilized for six months at $45^{\circ}C$. Application of the cosmetic was prepared moisturizing cream with liposomes of the phospholipid base.

박과식물(科植物) 종실(種實)에는 총지질량(總脂質量)이 $21.9{\sim}50.7%$의 범위(範圍)로 비교적(比較的높았으며, 특(特)히 박, 하늘타리의 경우는 41.9%와 50.7%로 조사(調査)한 시료(試料)중에 제일 높았으며, 또 모든 시료(試料)가 약(約) 98% 이상(以上)의 중성지질(中性脂質)을 함유(含有)하고 있었다. 호박, 수세미오이, 수박, 참외, 오이 및 박종자(種子)의 총지질(總脂質)에는 리놀산(酸)의 함량(含量)이 제일(第一) 많아 $56.8{\sim}84.0%$이였으며, ${\alpha}$-리놀레산(酸)의 함량(含量)은 0.0${\sim}$0.6%로 매우 적었고, 올레산(酸)이 주성분(主成分)인 모노엔산(酸)과 팔미트산(酸)이 대부분(大部分)인 포화지방산(飽和脂肪酸)은 그 함량(含量)이 각각(各各) 5.7${\sim}$22.2%와 9.9${\sim}$20.6%로 시료(試料)에 따라 심한 차이(差異)를 보였다. 하늘타리 종자(種子)의 총지질(總脂質)에는 $C_{18:2{\omega}6}$과 $_{9c.11t.13c-}C_{18:3}$(Punicic acid)이 40.5%와 34.9%로 주요(主要) 성분(成分)이였고, 그 다음으로 $C_{18:1{\omega}9$가 13.8% 함유(含有)되어 있었으며, 그러나 $_{9c/11t.13t-}C_{18:3}$(${\alpha}-eleostearic$ acid)는 2.2%에 지나지 않았다. 한편 여주의 경우(境遇)에는 $_{9c.11t.13c-}C_{18:3}$이 66.9%로 제일(第一) 많았으며, 그 다음으로 $C_{18:1{\omega}9$와 $C_{18:1{\omega}6$이 17.7%, 10.4% 각각(各各) 함유(含有)되어 있었고, 하늘타리에 많이 함유(含有)되어 있는 $_{9c.11t.13c}-C_{18:3}$는 $_{9t.11t.13c-}C_{18:3}$(${\beta}-eleostearic$ acid)와 함께 1.1% 정도(程度)로 소량(少量) 포함(包含)되어 있었다. ${9c.11t.13c-}C_{18:3}$와 $_{9c.11t.13t-}C_{18:3}$와 같은 conugate trienoic acid는 여타시료(餘他試料)에서는 전연 검출(檢出)되지 않았다. 하늘타리와 여주의 종자유(種子油)의 극성지질(極性脂質)에는 이틀의 중성지질(中性脂質)에 다량(多量)으로 존재(存在)하는 conjugate trienoic acid가 극(極)히 소량(少量)밖에 존재(存在)하지 않는 것은 매우 특징적(特徵的)이며, 포화지방산(飽和脂肪酸)이 중성지질(中性脂質)(9.9${\sim}$20.6%)에 비(比)하여 극성지질(極性脂質)(25.0${\sim}$29.4%) 에 보다 많이 함유(含有)되어 있다는 사실(事實)을 나머지 시료(試料)에서 공통적(共通的)으로 찾아볼 수 있었다. 박과식물(科植物) 종자(種子)는 리놀산(酸)을 많이 함유(含有)하고 있는 군(群)과, $_{9c.11t.13c}-C_{18:3}$ 및 $_{9c.11t.13t-}C_{18:3}$와 같은 conjugate trienoic acid를 가진 군(群)으로 대별(大別)할 수 있었다.

In this study, sensitizing dye was prepared by the reaction of 2-methyl-3-sulfopropyl-4, 5-naphthothiazolium(inner salt) with triethyl orthoformate in the presence of triethylamine. The product was identified by using various analytical tools such as Elemental analyzer, IR spectrophotometer, UV-Vis spectrophotometer, $^1H-NMR$ spectrometer, TGA and DSC. Therefore, it was concluded that naphthothiazolo carbocyanine dye can be used as red-sensitizing dye for the spectral sensitization of photographic emulsion.

Durable softening water repellents such as PODCWs were prepared by blending cationized compound of poly(octadecyl methacrylate-co-2-diethylaminoethyl methacrylate), of which synthetic methods were reported in the previous paper, activated polythylene, waxes, and emulsifiers. Water repellency of prepared PODCWs was measured by performing water repellent finish to various fabrics, PODCWs showed a good water repellency for P/C blended fabrics and their repelling tendency was in the order of P/C blended fabrics>cotton fabrics>nylon taffeta. The initial water repellencies of PODCW-1 and PODCW-2 were 100 and $100^{-}$ points, respectively, for P/C blended fabrics. And also, PODCW-1 and PODCW-2 were confirmed as durable water repellents with the results of making little difference of water repellency as ${\pm}5$ point after and before washing.

Cinnamoyl ester(PGEFC) of poly(phloroglucinol-formaldehyde) glycidyl ether which has photosensitive functional group was prepared to apply to photoresist. Photosensitivity of PGEFC was estimated by the solubility difference in organic solvent before and after exposure to light. The yield of residual film was calculated by immersing the sample-coated quartz plates in the solvent which was used in coating. The yield of the residual film which was closely related to the sensitivity of the film, was affected by the degree of polymerization of the backbone resin, sensitizers and their concentration. The sensitivity was depended upon the degree of polymerization. Most of effective sensitizer for PGEFC among the sensitizers was 2, 6-dichloro-4-nitroaniline.

저 분자량($M_{w}=1970$)의 poly(styrene)(PS)와 poly(vinylmethylether)(PVME)의 블렌드를 열 산화시킬 때 저 분자량의 PS의 첨가량이 증가할수록 유도기간이 증가하며 열 산화속도는 감소함을 알 수 있었다. 열 산화과정 동안 저 분자량 PS와 PVME 블렌드는 상 분리를 보이지 않았다. 저 분자량을 갖는 PS와 PVME 블렌드에서 PVME의 산화 속도는 높은 분자량을 갖는 PS와 PVME 블렌드에서 PVME의 열 산화 속도보다 훨씬 느려짐을 보였다.

This study was conducted to find a catalyst system which has high conversion and selectivity for the oxidative coupling of methane to produce ethane and ethylene. Various catalysts were tested in a fixed bed reactor ar $750^{\circ}C$, 1 atm, and the feed ratio($CH_4/O_2$) of 2/1. Under the reaction condition, 10wt%$PbSO_4/MgO$ catalyst showed the highest catalytic activity : methane conversion, $C_2$ selectivity and yield were 50, 40 and 20%, respectively. Catalysts containing sulfate compounds, 10wt%$PbSO_4/MgO$, 10wt%$MgSO_4/MgO$ and $Na_2SO_4/MgO$ revealed a moderate methane conversions such as 38, 50 and 50%, respectively and low $C_2$ selectivities such as 18, 5 and 9%, respectively. Catalysts containing carbonate compounds, 10wt%$PbCO_3/MgO$, 10wt%$Li_2CO_3/MgO$ and $NaCO_3/MgO$, also showed a moderate methane conversions such as 64, 44 and 51%, respectively and low $C_2$ selectivities such as 5, 6 and 2%, respectively. With the existence of chlorine and mercury, $C_2$ selectivity was decreased.

The absorption spectra of synthesis of long chain fatty acid containing azobenzene start from p-(p'-hydroxy phenyl azo)-benzoic acid was investigated by ultraviolet spectrophotometery in chloroform solvent at the various temperature. In addition, The pressure-area of the water-air interface was obtained and the LB film was fabricated onto a quartz slide and quartz crystal by conventional Langmuir-Blodgett(LB) method. The UV absorption spectra of Langmuir-Blodgett(LB) film on quartz slide and spectrum of monolayer formed on quartz crystal have been measured. Long chain fatty acid containing azobenzene are induced phtoisomerization by the application of u. v. and visible light irradiation alternatively the reversibility of phtoisomerization was more clear difference when the number of $C_{n}$ increased but, not so good at $C_{14}-azo$. At the pressure-area isotherms, the value of surface pressure increment were decreased when the number of $C_{n}$ increased. A surface pressure of 20mN/m was obtained as a proper one for a film deposition. The photoisomerization at LB films were induced by application of UV and visible light irradiation alternatively. So the LB film of long chain fatty acid containing azobenzene has possibility to being applied to functional molecular devices such as photomemory and light switching.

In this study, benzoxazolo carbocyanine dye was used as sensitizer for photographic emulsion, and the photographic characteristics were examined. The basic properties of sensitizer such as stability in various solvents were examined. The sensitizer was very stable in methanol, acetonitrile, acetone, dimethylformamide, and chloroform solution. Absorption spectra of benzoxazolo carbocyanine dye $2.5{\times}10^{-6}M$ and $5{\times}10^{-6}M$ concentrations in 10% aqueous methanol solutions containing $10^{-2}M$ potassium chloride show the monomer-J-aggregation characteristics. Compared to the absorption peak of the monomer in pure methanol solution, the red shifts of the monomer-J-aggregate peaks of benzoxazolo carbocyanine dye of $2.5{\times}10^{-6}M$ and $5{\times}10^{-6}M$ concentrations in 10% aqueous methanol solutions containing $10^{-2}M$ potassium chloride are 34nm respectively, and the sensitizing peak of benzoxazolo carbocyanine dye in photographic emulsion has red shift of 34nm. Therefore, if was concluded that benzoxazolo carbocyanine dye can be used as green sensitizing dye for the spectral sensitization of photographic emulsion.

Furfurylidene acetophenone derivatives were synthesis, it was measured that hydrolysis made use of UV at a wide pH $1.0{\sim}13.0$ range in 30% $dioxane-H_2O$ solution, $25{\pm}1^{\circ}C$. On the basis of general base catalysis, substitutent effect, confirmation of hydrolysis products, it was measured the reaction rate of furfurylidene acetophenone derivatives for the pH change. It maybe concluded that a part was unrelated to pH and another part was in proportion to concentration of hydroxide ion : Above pH 10.0, It was in proportion to concentration of hydroxide ion, a part having no concern with pH was added to the neutral $H_2O$ molecule. From the result of measurement the reaction rate, hydrolysis of furfurylidene acetophenone derivatives confirmed to the irreversible first order. Through measurement the substituent effect, It found that reaction rate was accelerated by electron attracting group. Also, From the result of final product, There were furfural and acetophenone. On the basis of these findings, Hydrolysis for the furfurylidene acetophenone derivative was proposed a fitting mechanisms.

Fluorenylidene chalcone derivatives were synthesized by condensation. The structure of these compounds were ascertained by means of UV, melting point, IR and $^1H-NMR$ spectra. The nucleophilic addition reaction kinetics of Thioglycolic acid to fluorenylidene chalcone was investigate by UV in 20% $dioxane-H_2O$ at $25^{\circ}C$. The rate equation which were applied over a wide $pH1.0{\sim}13.0$ range. On the basis of general base catalysis and confirmation of addition reaction product, the nucleophilic addtion reaction kinetics of thioglycolic acid to fluorenylidene chalcone were measured by the pH change. From the result of the above caption, a plausible nucleophilic addition reaction mechanism of thioglycolic acid to fluorenylidene chalcone was proposed. These compounds may be used as the starting materials for the preparation of the engineering plastics or the germicide.