자원환경지질 (Economic and Environmental Geology)

  • 제56권3호
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  • Pages.217-227
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  • 2023
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  • 1225-7281(pISSN)
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  • 2288-7962(eISSN)
대한자원환경지질학회 (The Korean Society of Economic and Environmental Geology)
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탄산칼슘 동질이상체의 수용액 기반 합성법 및 형태학적 특성 리뷰

Review of Water-Based Synthetic Methods of Calcium Carbonate Polymorphs and Their Morphological Features

  • 김영재 (부경대학교 지구환경시스템과학부 환경지질과학전공 ) ;
  • 이선용 (고려대학교 지구환경과학과) ;
  • 이영재 (고려대학교 지구환경과학과)
  • YoungJae Kim (Division of Earth and Environmental System Sciences, Major of Environmental Geosciences, Pukyong National University) ;
  • Seon Yong Lee (Department of Earth and Environmental Sciences, Korea University) ;
  • Young Jae Lee (Department of Earth and Environmental Sciences, Korea University)
  • 투고 : 2023.04.17
  • 심사 : 2023.05.22
  • 발행 : 2023.06.28
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⟨ 이전 논문 다음 논문 ⟩

초록

결정질 탄산칼슘(CaCO3)은 방해석(calcite), 아라고나이트(aragonite), 바테라이트(vaterite) 세 동질이상체로 다양한 지질 및 수중 환경에서 흔하게 발생한다. 또한, 탄산칼슘 광물은 기능성 재료로 사용될 수 있어 공학적인 용도로 많은 관심을 받고 있다. 자연계와 공학적인 세팅에서 생성되는 탄산칼슘의 형성 및 그 반응을 이해하고 다양한 생약 및 생의학 물질로 활용하기 위한 탄산칼슘 광물 형성에 대한 실험적 모사 방법(즉, 합성법)에 관한 연구가 활발히 진행되어왔다. 합성법에서 물을 용매로 탄산칼슘 결정 형성을 유도하는 방식(수용액-기반 합성법)은 자연계에서 발생하는 탄산염광물 형성 조건과 유사하므로 지질학 연구에서도 그 의미성이 매우 크다. 본 리뷰 논문에서는 문헌에서 보고되는 수용액-기반 탄산칼슘 합성법을 탄산칼슘 동질이상체 별로 분류한다. 또한, 여러 합성법에서 나타나는 결정의 형상 및 구조적 특성을 동질이상체 별로 분류하고 결정화 메커니즘을 통해 그 특성들을 토론하고자 한다.

Crystalline calcium carbonate (CaCO3) occurs in various geological and aqueous environments as calcite, aragonite, and vaterite. These minerals also have practical applications in engineered settings. Synthetic methods of calcium carbonate have been developed for scientific research and technical applications. For example, these methods have become widely adopted for studying the formation of CaCO3 minerals and (geo-)chemical processes involving these minerals in natural and engineered systems. Furthermore, these methods have the potential to be applied in various technical and biomedical fields. Water-based synthesis is particularly important for simulating the formation of calcium carbonate minerals in natural aqueous environments. This review paper describes the procedures and experimental conditions for water-based synthetic methods of each calcium carbonate polymorph, compares the morphological and structural features of the resulting crystals, and analyzes the crystallization mechanisms.

키워드

과제정보

This work was supported by a Research Grant of Pukyong National University(2022).

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