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주조 오스테나이트 스테인리스강 상경계 균열부 산화물 분석

Analysis of Oxide Layers in Phase Boundary Crack of Cast Austenitic Stainless Steel

  • 최민재 (한국원자력연구원 재료안전기술연구부) ;
  • 김성우 (한국원자력연구원 재료안전기술연구부)
  • Min-Jae Choi ;
  • Sung-Woo Kim
  • 투고 : 2023.12.01
  • 심사 : 2023.12.21
  • 발행 : 2023.12.30

초록

For the phase boundary crack found in the gasket made of cast austenitic stainless steel in the nuclear power plant, the oxide layers were analyzed through SEM and TEM. The results showed that cracks initiated and propagated along the austenite/δ-ferrite phase boundary, the propagation path was changed to penetrate the inside of the phase. The oxide layer located at the periphery of the crack along the phase boundary was identified as a complex multi-layered spinel structure, and Cr-rich carbides were also detected in the oxide. The cracks that propagated inside the austenite matrix were attributed to the presence of high external stresses and impurities.

키워드

과제정보

이 논문은 정부(과학기술정보통신부)의 재원으로 한국연구재단의 지원을 받아 수행된 연구임(2021M2E4A1037979).

참고문헌

  1. Byun, T. S. and Busby, J. T., 2012, "Cast Stainless Steel Aging Research Plan," Oak Ridge National Laboratory, Oak Ridge, TN, ORNL/LTR-2012/440. 
  2. Chen, T. and Yang, J., 2002, "Microstructural Characterization of Simulated Heat Affected Zone in a Nitrogen-Containing 2205 Duplex Stainless Steel," Mater. Sci. Eng. A, Vol. 338, No. 1-2, pp. 166-181. doi:https://doi.org/10.1016/S0921-5093(02)00065-5 
  3. Muthupandi, V., Srinivasan, P. B., Seshadri, S. and Sundaresan, S., 2003, "Effect of Weld Metal Chemistry and Heat Input on the Structure and Properties of Duplex Stainless Steel Welds," Mater. Sci. Eng. A, Vol. 358, No. 1-2, pp. 9-16. doi:https://doi.org/10.1016/S0921-5093(03)00077-7 
  4. Park, Y. and Sung, P., 1985, "Stress Corrosion Cracking Behavior of STS 304 Steel Weldments," J. Corros. Sci. Soc. Korea, Vol. 14, No. 3, pp. 9-20. 
  5. Abe, H. and Watanabe, Y., 2012, "Role of δ-Ferrite in Stress Corrosion Cracking Retardation near Fusion Boundary of 316NG Welds," J. Nucl. Mater., Vol. 424, No. 1-3, pp. 57-61. doi:https://doi.org/10.1016/j.jnucmat.2012.02.006 
  6. Xu, Y., Jing, H., Xu, L., Han, Y. and Zhao, L., 2019, "Effect of δ-Ferrite on Stress Corrosion Cracking of CF8A Austenitic Stainless Steels in a Simulated Pressurised Water Reactor Environment," J. Mater. Res. Technol., Vol. 8, No. 6, pp. 6420-6426. doi:https://doi.org/10.1016/j.jmrt.2019.10.052 
  7. Li, S., Wang, Y., Wang, H., Xin, C. and Wang, X., 2016, "Effects of Long-Term Thermal Aging on the Stress Corrosion Cracking Behavior of Cast Austenitic Stainless Steels in Simulated PWR Primary Water," J. Nucl. Mater., Vol. 469, pp. 262-268. doi:https://doi.org/10.1016/j.jnucmat.2015.11.043 
  8. Lai, C.-L., Lu, W.-F. and Huang, J.-Y., 2014, "Effect of δ-Ferrite Content on the Stress Corrosion Cracking Behavior of Cast Austenitic Stainless Steel in High-Temperature Water Environment," Corrosion, Vol. 70, No. 6, pp. 591-597. doi:https://doi.org/10.5006/1155 
  9. Yu, W., Fan, M., Gao, H., Yu, D., Xue, F. and Chen, X., 2018, "Effect of Long-Term Aging on the Fracture Toughness of Primary Coolant Piping Material Z3CN20.09M," Nucl. Eng. Des., Vol. 327, pp. 150-160. doi:https://doi.org/10.1016/j.nucengdes.2017.12.022 
  10. Li, Z., Lo, W.-Y., Chen, Y., Pakarinen, J., Wu, Y., Allen, T. and Yang, Y., 2015, "Irradiation Response of Delta Ferrite in as-Cast and Thermally Aged Cast Stainless Steel," J. Nucl. Mater., Vol. 466, pp. 201-207. doi:https://doi.org/10.1016/j.jnucmat.2015.08.006 
  11. Kawamura, H., Hirano, H., Shirai, S., Takamatsu, H., Matsunaga, T., Yamakota, K. and Takiguchi, H., 1998, "The Effect of Zinc Addition to Simulated PWR Primary Water on the Pwscc Resistance, Crack Growth Rate and Surface Oxide Films Characteristics of Prefilmed Alloy 600", CORROSION 98, San Diego, CA, March 22-27, NACE-98141. 
  12. Fujiwara, K., Tomari, H., Shimogori, K. and Fukuzuka, T., 1982, "An Electrochemical Study on the Role of Dissolved Oxygen in the IGSCC of Sensitized Type 304 Stainless Steel in Dilute Na2SO4 Solution at 285℃," Corrosion, Vol. 38, No. 2, pp. 69-76. doi:https://doi.org/10.5006/1.3577328 
  13. Terachi, T., Fujii, K. and Arioka, K., 2005, "Microstructural Characterization of SCC Crack Tip and Oxide Film for SUS 316 Stainless Steel in Simulated PWR Primary Water at 320℃," J. Nucl. Sci. Technol., Vol. 42, No. 2, pp. 225-232. doi:https://doi.org/10.3327/jnst.42.225 
  14. Terachi, T., Yamada, T., Miyamoto, T., Arioka and K., Fukuya, K., 2008, "Corrosion Behavior of Stainless Steels in Simulated PWR Primary Water-Effect of Chromium Content in Alloys and Dissolved Hydrogen-," J. Nucl. Sci. Technol., Vol. 45, No. 10, pp. 975-984. doi:https://doi.org/10.3327/jnst.45.975 
  15. Andresen, P. L., 2014, "Aging of Core Internals and Piping Systems," Oak Ridge National Laboratory, Oak Ridge, TN, ORNL/TM-2013/532. 
  16. Amman, T., 2010, "Gas-Shielded Arc Welding of Ferrite-Austenitic Steels," Weld. Int., Vol. 24, No. 11, pp. 861-866. doi:https://doi.org/10.1080/09507111003655101 
  17. Jepson, M. and Higginson, R., 2009, "The Influence of Microstructure on the Oxidation of Duplex Stainless Steels in Simulated Propane Combustion Products at 1000℃," Corros. Sci., Vol. 51, No. 3, pp. 588-594. doi:https://doi.org/10.1016/j.corsci.2008.11.023 
  18. Jin, Q., Li, J., Xu, Y., Xiao, X., Zhang, W. and Jiang, L., 2010, "High-Temperature Oxidation of Duplex Stainless Steels S32101 and S32304 in Air and Simulated Industrial Reheating Atmosphere," Corros. Sci., Vol. 52, No. 9, pp. 2846-2854. doi:https://doi.org/10.1016/j.corsci.2010.04.033 
  19. Blair, M. and Stevens, T., 1995, "Corrosion-Resistant High Alloy Steels," Steel Castings Handbook, 6th Edition, Steel Founders' Society of America and ASM International, IL. 
  20. Stellwag, B., 1998, "The Mechanism of Oxide Film Formation on Austenitic Stainless Steels in High Temperature Water," Corros. Sci., Vol. 40, No. 2-3, pp. 337-370. doi:https://doi.org/10.1016/S0010-938X(97)00140-6 
  21. Han, G., Lu, Z., Ru, X., Chen, J., Zhang, J. and Shoji, T., 2016, "Properties of Oxide Films Formed on 316L SS and Model Alloys with Modified Ni, Cr and Si Contents in High Temperature Water," Corros. Sci., Vol. 106, pp. 157-171. doi:https://doi.org/10.1016/j.corsci.2016.02.001 
  22. Stoter, L., 1981, "Thermal Ageing Effects in AISI Type 316 Stainless Steel," J. Mater. Sci., Vol. 16, pp. 1039-1051. doi:https://doi.org/10.1007/BF00542750 
  23. Chasse, K., Raji, S. and Singh, P., 2012, "Effect of Chloride Ions on Corrosion and Stress Corrosion Cracking of Duplex Stainless Steels in Hot Alkaline-Sulfide Solutions," Corrosion, Vol. 68, No. 10, pp. 932-949. doi:https://doi.org/10.5006/0642