공업화학 (Applied Chemistry for Engineering)

  • 제32권3호
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  • Pages.229-236
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  • 2021
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  • 1225-0112(pISSN)
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  • 2288-4505(eISSN)
한국공업화학회 (The Korean Society of Industrial and Engineering Chemistry)
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전기화학적 방법을 통한 금속 유기 골격체 합성

Electrochemical Synthesis of Metal-organic Framework

  • 문상현 (경북대학교 미래과학기술융합학과) ;
  • 김지영 (경북대학교 나노소재공학부) ;
  • 최현국 (경북대학교 나노소재공학부) ;
  • 김문갑 (경북대학교 나노소재공학부) ;
  • 이영세 (경북대학교 나노소재공학부) ;
  • 이기영 (경북대학교 미래과학기술융합학과)
  • Moon, Sanghyeon (Department of Advanced Science and Technology Convergence, Kyungpook National University) ;
  • Kim, Jiyoung (School of Nano & Materials Science and Engineering, Kyungpook National University) ;
  • Choi, Hyun-Kuk (School of Nano & Materials Science and Engineering, Kyungpook National University) ;
  • Kim, Moon-Gab (School of Nano & Materials Science and Engineering, Kyungpook National University) ;
  • Lee, Young-Sei (School of Nano & Materials Science and Engineering, Kyungpook National University) ;
  • Lee, Kiyoung (Department of Advanced Science and Technology Convergence, Kyungpook National University)
  • 투고 : 2021.04.20
  • 심사 : 2021.05.11
  • 발행 : 2021.06.10
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⟨ 이전 논문 다음 논문 ⟩

초록

금속 유기 골격체는 최근 20년간 센서, 촉매, 에너지 저장과 같은 많은 응용분야에서 관심을 받아온 물질이다. 이 물질을 합성하기 위해 수열 합성, 유기용매열과 같은 합성법이 제시되어 왔으나, 그 공정이 복잡하면서 고비용·장시간이 소요된다는 문제점이 제기되어 왔다. 이를 해결하기 위한 전기화학적 합성법이 새롭게 제시되었는데, 간단한 준비절차와 특정한 온도·압력 조건 없이 합성할 수 있어 기존 합성법의 단점을 보완한다는 특징이 있다. 이에 본 총설논문에서는 전기화학적으로 합성 가능한 금속 유기 골격체의 종류와 전기화학적 합성 메커니즘을 다루고 있다. 전기화학적 합성법을 통해 형성된 금속 유기 골격체를 적용한 응용분야 연구동향을 정리하였다.

During the last two decades, metal-organic frameworks (MOFs) have been drawn attention due to their high specific surface area, porosity, and catalytic activities that allow to use in many applications such as sensor, catalysis, energy storage, etc. To synthesize MOFs hydrothermal or solvothermal method were generally used. However, these methods require high-cost equipment and long time-spend for the synthesis with multi-step process. In contrast, electrochemical synthesis has been considered as a simple and easy process under the ambient conditions. In this review, we described the mechanism of electrochemical MOFs synthesis by the number of configured electrodes system, with the recent reports of various applications.

키워드

과제정보

This research was supported by the National Research Foundation of Korea Grant funded by the Korean Government (NRF-2019R1I1A3A01041454) and the Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education (NRF-2018R1A6A1A03024962).

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