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마이크로버블 장치를 이용한 하수처리장 바이오가스의 황화수소 제거

Hydrogen Sulfide Removal of Biogas from Sewage Treatment Plant with Micro-bubble Generation System

  • 정재억 (부산가톨릭대학교 환경공학과) ;
  • 정용준 (부산가톨릭대학교 환경공학과)
  • Jung, Jae-Ouk (Department of Environmental Engineering, Catholic University of Pusan) ;
  • Jung, Yong-Jun (Department of Environmental Engineering, Catholic University of Pusan)
  • 투고 : 2020.09.16
  • 심사 : 2020.10.16
  • 발행 : 2020.11.30

초록

혐기성소화조에서 발생하는 바이오가스는 열과 전력을 생산하는데 사용되기 전에 불순물, 특히 황화물 제거 공정이 수반 되어야 한다. 본 연구에서는 시설용량 46,000㎡/d의 하수처리장을 대상으로 습식스크러빙 장치를 활용하여 운전 조건의 변화에 따른 메탄감소율과 황화수소 및 이산화탄소의 제거율을 평가하였다. 부분순환에서 장치 유입전 평균 59.7%의 CH4은 처리후 57.4%로 감소하여 3.9%의 감소율을 나타내어 마이크로버블 산화에도 불구하고 천천히 기화되는 것을 알 수 있었다. CO2의 경우 38%가 장치로 유입되어 32%로 배출됨에 따라 15.8%의 제거율을 나타냈다. 1,400ppm의 H2S는 DIWS장치로 유입되어 334ppm으로 배출되어 76.1%의 감소율을 나타냈다.

Prior to utilization of energy and power generation, the biogas from anaerobic digestion of sewage treatment plant(46,000㎡/d) should be purified particularly hydrogen sulfide among the various kinds of impurities. This study has focused on the methane decreasing rate and the removal of both hydrogen sulfide and carbon dioxide. In the case of partial circulation, 59.7% of methane gas was decreased to 57.4% in spite of oxidation process with micro-bubble. Carbon dioxide was removed from 38% to 32% and 76.1% of hydrogen sulfide was removed where 1,400ppm was introduced to the DIWS system, which indicated that DIWS system can be of use for the hydrogen sulfide removal of biogas from sewage treatment plant.

키워드

참고문헌

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