DOI QR코드

DOI QR Code

Removal of Total Organic Carbon and Micropollutants in Tertiary Treated Sewage by Medium Pressure UV/H2O2

중압 자외선과 과산화수소 공정을 이용한 하수 3차 처리수중 총유기탄소와 미량오염물질 제거

  • Lee, Jai-Yeop (Department of Land, Water and Environment Research, Korea Institute of Civil Engineering and Building Technology) ;
  • Kim, Ilho (Department of Land, Water and Environment Research, Korea Institute of Civil Engineering and Building Technology)
  • 이재엽 (한국건설기술연구원 국토보전연구본부) ;
  • 김일호 (한국건설기술연구원 국토보전연구본부)
  • Received : 2020.06.01
  • Accepted : 2020.07.21
  • Published : 2020.07.30

Abstract

This study evaluated the applicability of UV-AOP process using medium-pressure UV lamp and H2O2 to remove TOC and emerging micropollutants in the effluent from a sewage treatment plant. The UV lamp with higher output(1.6~8.0 kW) showed slightly higher amount of power in removing TOC of 1 mg/L(0.09 kWh/mg/L~0.11 kWh/mg/L), however it was found that there was no significant difference for each cases. In addition, under the condition that the H2O2 concentration is sufficient, as the power consumption of the UV lamp increases, the unit TOC removal concentration per unit H2O2 decomposition concentration also increases, resulting in effective removal of TOC. The removal rate of 7 new trace contaminants, such as antibiotics by the UV-AOP tested, was at least 89.4%, and the ability to remove the emerging micro pollutants in the process was very effective. But, it was judged that it could not be excluded that the probablity of transforming to oxidated by-product in the case of a low TOC removal efficiency. Depending on the operating conditions of the UV and H2O2 processes, a higher BOD concentration is found in the treated water than in the influent, and it is necessary to review the UV power and proper injection conditions of H2O2 to maintain the BOD concentration increase below a certain level.

Keywords

References

  1. Ali, F., Khan, J. A., Shah, N. S., Sayed, M., and Khan, H. M. (2018). Carbamazepine degradation by UV and UV-assisted AOPs: Kinetics, mechanism and toxicity investigations, Process Safety and Environmental Protection, 117, 307-314. https://doi.org/10.1016/j.psep.2018.05.004
  2. Chen, S., Zhou, Y., Meng, J., and Wang, T. (2018). Seasonal and annual variations in removal efficiency of perfluoroalkyl substances by different wastewater treatment processes, Environmental Pollution, 242(Part B), 2059-2067. https://doi.org/10.1016/j.envpol.2018.06.078
  3. Chen, T., Ma, J., Zhang, Q., Xie, Z., Zeng, Y., Li, R., Liu, H., Liu, Y., Lv, W., and Liu, G. (2019). Degradation of propranolol by UV-activated persulfate oxidation:Reaction kinetics, mechanisms, reactive sites, transformation pathways and Gaussian calculation, Science of the Total Environment, 690, 878-890. https://doi.org/10.1016/j.scitotenv.2019.07.034
  4. Dodd, M. C., Buffle, M. O., and von Gunten, U. (2006). Oxidation of antibacterial molecules by aqueous ozone: moiety-specific reaction kinetics and application to ozone-based wastewater treatment, Environmental Science and Technology, 40, 1969-1977. https://doi.org/10.1021/es051369x
  5. Hong, Y. M., Lee, I. G., Lee, W. S., and Kim, H. W. (2019). Mass-balance-model-based evaluation of sewage treatment plant contribution to residual pharmaceuticals in environmental waters, Chemosphere, 225, 378-387. https://doi.org/10.1016/j.chemosphere.2019.03.046
  6. Huang, Y., Kong, M., Coffin, S., Cochran, K. H., Westerman, D. C., Schlenk, D., Richardson, S. D., Lei, L., and Dionysiou, D. D. (2020). Degradation of contaminants of emerging concern by $UV/H_2O_2$ for water reuse: Kinetics, mechanisms, and cytotoxicity analysis, Water Research, 174, 115587. https://doi.org/10.1016/j.watres.2020.115587
  7. Huber, M. M., Canonica, S., Park, G. Y., and von Gunten, U. (2003). Oxidation of pharmaceuticals during ozonation and advanced oxidation processes, Environmental Science and Technology, 37, 1016-1024. https://doi.org/10.1021/es025896h
  8. Jallouli, N., Pastrana-Martinez, L. M., Ribeiro, A. R., Moreira, N. F. F., Faria, J. L., Hentati, O., Silva, A. M. T., and Ksibi, M. (2018). Heterogeneous photocatalytic degradation of ibuprofen in ultrapure water, municipal and pharmaceutical industry wastewaters using a $TiO_2/UV-LED$ system, Chemical Engineering Journal, 334, 976-984. https://doi.org/10.1016/j.cej.2017.10.045
  9. Jeong, D. H., Cho, Y., Ahn, K., Chung, H. M., Park, H., Shin, H., Hur, J., and Han, D. (2016). A study on the determination method of TOC effluent limitation for public sewage treatment plants, Journal of Korean Society of Water and Wastewater, 30(3), 241-251. [Korean Literature] https://doi.org/10.11001/jksww.2016.30.3.241
  10. Keen, O. S., Dotson, A. D., and Linden, K. G. (2013). Evaluation of hydrogen peroxide chemical quenching agents following an advanced oxidation process, Journal of Environmental Engineering, 139(1), 137-140. https://doi.org/10.1061/(ASCE)EE.1943-7870.0000619
  11. Li, B. and Zhang, T. (2010). Biodegradation and adsorption of antibiotics in the activated sludge process, Environmental Science and Technology, 44(9), 3468-3473. https://doi.org/10.1021/es903490h
  12. Li, W., Xu, X., Lyu, B., Tang, Y., Zhang, Y., Chen, F., and Korshin, G. (2019). Degradation of typical macrolide antibiotic roxithromycin by hydroxyl radical: kinetics, products, and toxicity assessment, Environmental Science and Pollution Research, 26, 14570-14582. https://doi.org/10.1007/s11356-019-04713-1
  13. Lima, V. B., Goulart, L. A., Rocha, R. S., Steter, J. R., and Lanza, M. R. V. (2020). Degradation of antibiotic ciprofloxacin by different AOP systems using electrochemically generated hydrogen peroxide, Chemosphere, 247, 125807. https://doi.org/10.1016/j.chemosphere.2019.125807
  14. Monteoliva-Garcia, A., Martin-Pascual, J., Munio, M. M., and Poyatos, J. M. (2020). Effects of carrier addition on water quality and pharmaceutical removal capacity of a membrane bioreactor-Advanced oxidation process combined treatment, Science of The Total Environment, 708, 135104. https://doi.org/10.1016/j.scitotenv.2019.135104
  15. Navarro, I., Torre, Adrian, Sanz, P., and Angeles Martinez, M. (2020). Perfluoroalkyl acids (PFAAs): Distribution, trends and aquatic ecological risk assessment in surface water from Tagus River basin (Spain), Environmental Pollution, 256, 113511. https://doi.org/10.1016/j.envpol.2019.113511
  16. Rodriguez-Chueca, J., Giustina, S. V., Rocha, J., Fernandes, T., Pablos, C., Encinas, A., Barcelo, D., Rodriguez-Mozaz, S., Manaia, C. M., and Marugan, J. (2019). Assessment of full-scale tertiary wastewater treatment by UV-C based-AOPs: Removal or persistence of antibiotics and antibiotic resistance genes?, Science of The Total Environment, 652, 1051-1061. https://doi.org/10.1016/j.scitotenv.2018.10.223
  17. Roy, K. and Moholkar, V. S. (2019). Sulfadiazine degradation using hybrid AOP of heterogeneous Fenton/persulfate system coupled with hydrodynamic cavitation, Chemical Engineering Journal, 386, 121294. https://doi.org/10.1016/j.cej.2019.03.170
  18. Ruan, Y., Wu, R., Lam, James C. W., Zhang, K., and Lam, Paul K. S. (2019). Seasonal occurrence and fate of chiral pharmaceuticals in different sewage treatment systems in Hong Kong: Mass balance, enantiomeric profiling, and risk assessment, Water Research, 149(1), 607-616. https://doi.org/10.1016/j.watres.2018.11.010
  19. Shu, Z., Singh, A., Klamerth, N., McPhedran, K., Bolton, J. R., Belosevic, M., and El-Din, M. G. (2016). Pilot-scale $UV/H_2O_2$ advanced oxidation process for municipal reuse water: Assessing micropollutant degradation and estrogenic impacts on goldfish (Carassius auratus L.), Water Research, 101, 157-166. https://doi.org/10.1016/j.watres.2016.05.079
  20. Sellers, R. M. (1980). Spectrophotometric determination of hydrogen peroxide using potassium titanium(IV) oxalate, The Analyst, 105(1255), 950. https://doi.org/10.1039/an9800500950
  21. Song, W. H., Cooper, W. J., Mezyk, S. P., Greaves. J., and Peake, B. M. (2008). Free radical destruction of $\beta$-blockers in aqueous solution, Environmental Science and Technology, 42(4), 1256-1261. https://doi.org/10.1021/es702245n
  22. Wols, B. A., Hofman-Caris, C. H. M., Harmsen, D. J. H., and Beerendonk, E. F. (2013). Degradation of 40 selected pharmaceuticals by $UV/H_2O_2$, Water Research, 47, 5876-5888. https://doi.org/10.1016/j.watres.2013.07.008
  23. Yoo, J., Lee, B., Hur, J., and Jung, J. (2014). Physicochemical and toxicological properties of effluent organic matters from sewage and industrial treatment plants, Journal of Korean Society on Water Environment, 30(1), 80-86. [Korean Literature] https://doi.org/10.15681/KSWE.2014.30.1.080
  24. Zhu, S., Dong, B., Wu, Y., Bu, L., and Zhou, S. (2019), Degradation of carbamazepine by vacuum-UV oxidation process: Kinetics modeling and energy efficiency, Journal of Hazardous Materials, 368, 178-185. https://doi.org/10.1016/j.jhazmat.2019.01.043