Applied Chemistry for Engineering (공업화학)

The Korean Society of Industrial and Engineering Chemistry (한국공업화학회)
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Recent Trend in Catalysis for Degradation of Toxic Organophosphorus Compounds

유기인 계열 독성화합물 분해를 위한 촉매반응의 최신 연구 동향

  • Kye, Young-Sik (Department of Physics and Chemistry, Korea Military Academy) ;
  • Jeong, Keunhong (Department of Physics and Chemistry, Korea Military Academy) ;
  • Kim, Dongwook (Department of Physics and Chemistry, Korea Military Academy)
  • 계영식 (육군사관학교 물리화학과) ;
  • 정근홍 (육군사관학교 물리화학과) ;
  • 김동욱 (육군사관학교 물리화학과)
  • Received : 2019.08.30
  • Accepted : 2019.09.19
  • Published : 2019.10.10
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Abstract

Catalysts based on organic compounds, transition metal and metal-organic frameworks (MOFs) have been applied to degrade or remove organophosphorus toxic compounds (OPs). During the last 20 years, various MOFs were designed and synthesized to suit application purposes. MOFs with $Zr_6$ based metal node and organic linker were widely used as catalysts due to their tunability for the pore size, porosity, surface area, Lewis acidic sites, and thermal stability. In this review, effect on catalytic efficiency between MOFs properties according to the structure, stability, particle size, number of connected-ligand, organic functional group, and so on will be discussed.

유기물질, 전이금속 및 유기-금속 구조체(MOFs)를 기반으로 하는 촉매들이 유기인 계열 독성물질들을 분해하고 제거하는데 효과적임이 보고되어 왔다. 최근 20년간 독성물질 분해연구를 위해 다공성 MOFs들이 응용 목적에 맞게 디자인되고 합성되었다. $Zr_6$ 기반의 금속노드와 유기결합체를 가지는 MOFs들은 세공크기, 공극률, 표면적, Lewis acidic 자리 그리고 열적 안정성 등과 같은 기본구조내의 변형이 가능하기 때문에 화학작용제, 살충제 및 제초제를 제거하는 촉매로 널리 사용되어왔다. 본 리뷰에서는 구조, 안정성, 입자크기, 연결된 리간드 수, 유기 기능기 등에 따른 MOFs들의 촉매효율과의 연관성을 다루게 될 것이다.

Keywords

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