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Compact, Wavelength-selectable, Energy-ratio Variable Nd:YAG Laser at Mid-ultraviolet for Chemical Warfare Agent Detection

  • Received : 2019.01.30
  • Accepted : 2019.05.07
  • Published : 2019.06.25

Abstract

We have developed a compact, wavelength-selectable, Q-switched Nd:YAG laser at mid ultraviolet for chemical warfare agent detection. The fundamental wave at 1064 nm is delivered by a pulsed solid state laser incorporating with a square-type Nd:YAG rod in a resonator closed by two crossed Porro prisms for environmental reliability. The output energy at 213 nm ($5{\omega}$) and 266 nm ($4{\omega}$) by ${\chi}^{(2)}$ process in the sequentially disposed BBO crystals are measured to be 6.8 mJ and 15.1 mJ, respectively. The output wavelength is selected for $5{\omega}$ and $4{\omega}$ by a motorized wavelength switch. The energy ratio of the $5{\omega}$ to the $4{\omega}$ is varied from 0.05 to 0.85 by controlling the phase matching temperature of the nonlinear crystal for sum-frequency generation without change of the output pulse parameters.

Keywords

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FIG. 1. (a) Experimental schematic of the pulsed Nd:YAG laser at mid-ultraviolet. PP, Porro prism; M, mirror; P, polarizer; QWP, quarter-wave plate; HWP, half-wave plate; PC, Pockels cell; DMs, dichroic mirrors; NLC, non-linear crystal; λ-switch, wavelength switch. (b) Details in the wavelength-switch. The output wavelength is selected to be 213 nm or 266 nm by a motorized linear stage. (c) The exterior of the UV laser with the dimensions of 200(W) × 401(L) × 202 (H) mm3 and the weight of 11 kg including the power supply as well as the control electronics.

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FIG. 2. The output energy per pulse at 1064 nm as a function of the pump energy. The slope efficiency is estimated to be 33%. Inset, the measured pulse shape with the FWHM of 21 ns.

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FIG. 3. The measured width of the infrared beam as a function of the distance for the horizontal (the vertical) direction. The M-squared in horizontal and vertical direction are deduced to be 2.4 and 1.7, respectively. Inset, the observed beam profile of the fundamental beam.

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FIG. 4. The measured harmonic energy (black rectangles for 2ω, red circles for 4ω, blue triangles for 5ω) and the calculated energy (black line for 2ω, red line for 4ω, blue line for 5ω) by SNLO program as a function of the pumping energy at the fundamental wave.

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FIG. 5. (a) The output wavelength selection for 213 nm and 266 nm. (b) The measured variation of the energy ratio (black rectangular) at 5ω to the 4ω by controlling the phase-matching temperature for the 3rd nonlinear crystal. The red line is calculated energy ratio by the SNLO program.

References

  1. D. B. Coyle, R. B. Kay, P. R. Stysley, and D. Poulios, "Efficient, reliable, long-lifetime, diode-pumped Nd:YAG laser for space-based vegetation topographical altimetry," Appl. Opt. 43, 5236-5242 (2004). https://doi.org/10.1364/AO.43.005236
  2. D. Carr and G. Tuell, "Estimating field-of-view loss in bathymetric lidar: application to large-scale simulations," Appl. Opt. 53, 4716-4721 (2014). https://doi.org/10.1364/AO.53.004716
  3. B. Tan, "Deep microhole drilling in a silicon substrate using multi-bursts of nanosecond UV laser pulses," J. Micromech. Microeng. 16, 1-4 (2006). https://doi.org/10.1088/0960-1317/16/1/001
  4. A. Bertsch, H. Lorenz, and P. Renaud, "3d microfabrication by combining microstereolithography and thick resist UV lithography," Sens. Actuators, A 73, 14-23 (1999). https://doi.org/10.1016/S0924-4247(98)00249-0
  5. J. Kim, D. Haubrich, and D. Meschede, "Efficient sub-Doppler laser cooling of an indium atomic beam," Opt. Express 17, 21216-21221 (2009). https://doi.org/10.1364/OE.17.021216
  6. A. Okamoto, H. Kuniyasu, and T. Hattori, "Detection of 30-40 nm particles on bulk -silicon and SOI wafers using deep UV laser scattering," IEEE Trans. Semicond. Manuf. 19, 372-380 (2006). https://doi.org/10.1109/TSM.2006.884600
  7. R. T. Rewick, M. L. Schumacher, and D. L. Haynes, "UV absorption spectra of chemical agents and simulants," Appl. Spectrosc. 40, 152-156 (1986). https://doi.org/10.1366/0003702864509493
  8. S. D. Christesen, "Raman cross sections of chemical agents and simulants," Appl. Spectrosc. 42, 318-321 (1988). https://doi.org/10.1366/0003702884428220
  9. V. Pajcini, C. H. Munro, R. W. Bormett, R. E. Witkowski, and S. A. Asher, "UV Raman microspectroscopy: Spectral and spatial selectivity with sensitivity and simplicity," Appl. Spectrosc. 51, 81-86 (1997). https://doi.org/10.1366/0003702971938803
  10. R. Bhartia, W. F. Hugb, and R. D. Reid, "Improved sensing using simultaneous deep UV Raman and fluorescence detection," Proc. SPIE 8358, 83581A (2012).
  11. S. Jin, Z. Feng, F. Fan, and C. Li, "UV Raman spectroscopic characterization of catalysts and catalytic active sites," Catal. Lett. 145, 468-481 (2015). https://doi.org/10.1007/s10562-014-1416-0
  12. Y. C. Ha, J. H. Lee, Y. J. Koh, S. K. Lee, and Y. K. Kim, "Development of an ultraviolet Raman spectrometer for standoff detection of chemicals," Curr. Opt. Photon. 1, 247-251 (2017). https://doi.org/10.3807/COPP.2017.1.3.247
  13. S. D. Christesen, J. P. Jones, J. M. Lochner, and A. M. Hyre, "Ultraviolet raman spectra and cross-sections of the G-series nerve agents," Appl. Spectrosc. 62, 1078-1083 (2008). https://doi.org/10.1366/000370208786049024
  14. F. Kullander, L. Landstrom, H. Lunde, A. Mohammed, G. Olofsson, and P. Wasterby, "Measurements of Raman scattering in the middle ultraviolet band from persistent chemical warfare agents," Proc. SPIE 9073, 90730C (2014).
  15. W. R. Bosenberg, L. K. Cheng, and C. L. Tang, "Ultraviolet optical parametric oscillation in ${\beta}-BaB_2O_4$," Appl. Phys. Lett. 54, 13-15 (1989). https://doi.org/10.1063/1.101434
  16. R. B. Bapna, C. S. Rao, and K. Dasgupta, "Low-threshold operation of a 355-nm pumped nanosecond ${\beta}-BaB_2O_4$ optical parametric oscillator," Opt. Laser Technol. 40, 832-837 (2008). https://doi.org/10.1016/j.optlastec.2007.11.009
  17. F. Kullander, L. Landstrom, H. Lunde, and P. Wasterby, "Experimental examination of ultraviolet Raman cross sections of chemical warfare agent simulants," Proc. SPIE 9455, 94550S (2015).
  18. M. K. Chun and E. A. Teppo, "Laser resonator: an electrooptically Q-switched Porro prism device," Appl. Opt. 15, 1942-1946 (1976). https://doi.org/10.1364/AO.15.001942
  19. I. Singh, A. Kumar, and O. P. Nijhawan, "Design of a high-power Nd:YAG Q-switched laser cavity," Appl. Opt. 34, 3349-3351 (1995). https://doi.org/10.1364/AO.34.003349
  20. A. Rapaport, L. Weichman, B. Brickeen, S. Green, and M. Bass, "Laser resonator design using optical ray tracing software: comparison with simple analytical models and experimental results," IEEE J. Quantum Electron. 37, 1041-1048 (2001).
  21. K. Lee, Y. Yoon, J. Lee, K. Cho, J. Kim, and J. Cho, "Linearly aligned multiple pumping apparatus for solid-state solid lasers," KR Patent 10-2018-0106942 (2018).
  22. Y. Yoon, K. Cho, K. Lee, J. Yoo, J. Lee, J. Kim, S. Lee, and P. Jung, "Laser gain medium assembly solid-state solid lasers and assembling method thereof," KR Patent 10-2019-0001547 (2019).
  23. Y. Ha, J. Lee, Y. Kang, K. Cho, J. Kim, and J. Cho, "High-order harmonic wave generation apparatus capable of selecting wavelength," U.S. Patent US9620927B2 (2017).
  24. W. Koechner, Solid-State Laser Engineering (Springer-Verlag, 1996).
  25. SNLO Program, http://www.as-photonics.com/snlo.
  26. J. P. Phillips, S. Banerjee, J. Smith, M. Fitton, T. Davenne, K. Ertel, P. Mason, T. Butcher, M. Vido, J. Greenhalgh, C. Edwards, C. H. Gomez, and J. Collier, "High energy, high repetition rate, second harmonic generation in large aperture DKDP, YCOB, and LBO crystals," Opt. Express 24, 19682-19694 (2016). https://doi.org/10.1364/OE.24.019682
  27. A. V. Smith and M. Bowers, "Phase distortions in sum- and difference-frequency mixing in crystals," J. Opt. Soc. Am. B 12, 49-57 (1995). https://doi.org/10.1364/JOSAB.12.000049
  28. A. V. Smith, W. J. Alford, T. D. Raymond, and M. S. Bowers, "Comparison of a numerical model with measured performance of a seeded, nanosecond KTP optical parametric oscillator," J. Opt. Soc. Am. B 12, 2253-2267 (1995). https://doi.org/10.1364/JOSAB.12.002253