보존과학회지 (Journal of Conservation Science)

  • 제35권2호
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  • Pages.159-168
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  • 2019
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  • 1225-5459(pISSN)
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  • 2287-9781(eISSN)
한국문화재보존과학회 (The Korean Society Of Conservation Science For Cultural Heritage)
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연질 PVC 작품 보존을 위한 가소제 종류별 열화 특성 및 화학적 세척법 연구

Study on Degradation Characteristics and Chemical Cleaning Methods of Plasticized PVC for Conservation of Plastic Artifact

  • 이나라 (한국전통문화대학교 문화유산전문대학원 문화재수리기술학과) ;
  • 정용재 (한국전통문화대학교 문화유산전문대학원 문화재수리기술학과)
  • Lee, Na Ra (Department of Heritage Conservation and Restoration, Graduate School of Cultural Heritage, Korea National University of Cultural heritage) ;
  • Chung, Yong Jae (Department of Heritage Conservation and Restoration, Graduate School of Cultural Heritage, Korea National University of Cultural heritage)
  • 투고 : 2019.03.15
  • 심사 : 2019.04.18
  • 발행 : 2019.04.20
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초록

플라스틱에 첨가된 가소제는 플라스틱이 열화되면서 표면으로 빠져나오는 삼출 현상을 야기한다. 가소제가 첨가된 플라스틱 작품은 이 현상으로 인해 표면이 끈적해지고 먼지와 이물질이 부착되어 표면 오염이 발생할 수 있다. 이에 본 연구에서는 가소제가 가장 많이 사용되는 PVC를 대상으로 가소제 종류별 열화 양상 및 화학적 세척법을 연구하고자 하였다. 각각 다른 가소제가 첨가된 PVC 시편을 열화시킨 후 현미경 관찰, 색도 및 중량 측정, 적외선분광분석을 통해 열화 양상을 평가하였으며 동일한 방법으로 가소제가 삼출된 시편의 세척효과와 안정성을 평가하였다. 연구 결과, DOP 첨가 시편은 변색, DOA 첨가 시편은 중량 감소가 두드러졌으며 TOTM 첨가 시편은 변색과 더불어 가소제 삼출현상이 발생하였다. 가소제가 삼출된 TOTM 시편을 대상으로 화학적 세척법을 비교한 결과 에틸 알코올과 KOH 수용액은 세척효과는 좋았으나 안정성이 떨어졌으며 계면활성제는 세척효과와 안정성이 모두 준수한 것으로 나타났다. 본 연구 결과는 향후 가소제가 첨가된 플라스틱 보존처리에 활용될 수 있을 것으로 기대하는 바이다.

Plasticizers, which are added to plastics, can cause exudation, which means that the plasticizer comes out from surface of the plastics. This causes the surface of plastic artworks to become sticky, and this allows dust and pollutants to become attached to the surface. Therefore, in this study, the degradation characteristics and chemical cleaning methods of each type of plasticizer are evaluated using PVC specimens. To evaluate the degradation characteristics and chemical cleaning methods, microscopic observation, chromaticity and weight measurement, and FT-IR spectroscopy were performed. The results showed that PVCs containing different plasticizers have different degradation patterns. Especially, the PVC containing TOTM showed discoloration and exudation. In the evaluation of the chemical cleaning methods, ethyl alcohol and KOH solution showed good effects, but their stability was not good. Surfactant was found to have a good cleaning effect and stability as a cleaner for exudated plasticizers.

키워드

참고문헌

  1. Bertrand, L., Alban, F. and Graham, M., 2012, Preservation of plastic artefacts in museum collections. CTHS, Paris, 109-137.
  2. Bernard, L., Cueff, R., Breysse, C., Decaudin, B., Saautou, V. and Armed Study Group, 2015, Migrability of PVC plasticizers from medical devices into a simulant of infused solutions. International Journal of Pharmaceutics, 485(1), 341-347. https://doi.org/10.1016/j.ijpharm.2015.03.030
  3. Chung, Y.J., Yu, J.A. and Kang, D.I., 2013, Preservation values and effects on cleaning and adhesive agents for plastic artifacts. Journal of Conservation Science, 29(2), 127-138. (in Korean with English abstract) https://doi.org/10.12654/JCS.2013.29.2.04
  4. Jeong, J.C., 2010, Chemistry and polymers in life. Jayuacademy, Paju, 250-300.(in Korean)
  5. Joel, R.F., 1996, Polymer science and technology(Kim, W.S., trans.). Jayuacademy, Paju, 250-254. (Original work published 1996)
  6. Kim, W. and Gye, M.C., 2017, Maleficent effects of phthalates and current states of their alternatives: A review. Korean Journal of Environmental Biology, 35(1), 21-36. (in Korean with English abstract) https://doi.org/10.11626/KJEB.2017.35.1.021
  7. Kondyli, E., Demertzis, P.G. and Kontominas, M.G., 1992, Migration of dioctylphthalate and dioctyladipate plasticizers from food-grade PVC films into ground-meat products. Food Chemistry, 45(3), 163-168. https://doi.org/10.1016/0308-8146(92)90108-E
  8. Lee, S.J., Yuk, J.S., Kim, A.R., Choung, J.S., Shin, J.H. and Kim, Y.W., 2017, Polyvinylchloride plasticized with acetylated monoglycerides derived from plant oil. Applied Chemistry for Engineering, 28(1), 42-49. (in Korean with English abstract) https://doi.org/10.14478/ace.2016.1099
  9. Marcilla, A., Garcia, S. and Gracia-Quesada, J.C., 2007, Migrability of PVC plasticizers. Polymer Testing, 27(2), 221-233. https://doi.org/10.1016/j.polymertesting.2007.10.007
  10. Mark, H.F., 2013, Encyclopedia of polymer science and technology. Wiley, Hoboken, 498-525.
  11. Munoz, C.M., 2010, Surface modification of plasticized PVC by dry cleaning methods: Consequences for artworks. Applied Surface Science 256(11), 3567-3572. https://doi.org/10.1016/j.apsusc.2009.12.156
  12. Munoz, C.M., Egsgaard, H., Landaluze, J.S. and Dietz, C., 2014, A model approach for finding cleaning solutions for plasticized poly (vinyl chloride) surfaces of collections objects. Journal of the American Institute for Conservation, 53(4), 236-251. https://doi.org/10.1179/0197136014Z.00000000040
  13. Sale Jr, D., 1988, The effect of solvent on four plastics found in museum collections: a treatment dilemma. Modern Organic Materials Meeting, Edinburgh, April 14-15, 105-114.
  14. Shashoua, Y.R., 2001, Inhibiting the deterioration of plasticized poly (vinl chloride) - A museum perspective. Ph. D. thesis, The Technical University of Denmark, Kongens Lyngby, 16-27
  15. Son, T.M. and Lee, C.Y., 2008, Paint base engineering. Donghwa Technology, Paju, 176-180. (in Korean)
  16. Wikes, C.E., Summers, J.W. and Daniels, C.A., 2005, PVC handbook. Hanser, Munich, 173-193.