Membrane and Water Treatment

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A Separation of manganese (II) and cobalt (II) ions by D2EHPA/TBP-immobilized PolyHIPE membrane

  • Chen, Jyh-Herng (Department of Materials and Mineral Resources Engineering, National Taipei University of Technology) ;
  • Mai, Le Thi Tuyet (College of Engineering, National Taipei University of Technology)
  • Received : 2018.08.17
  • Accepted : 2018.12.06
  • Published : 2019.03.25
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Abstract

The D2EHPA/TBP co-extractants immobilized PolyHIPE membrane can be used for the selective separation of Mn (II) from Co (II). By solvent-nonsolvent method, D2EHPA/TBP co-extractants can be effectively immobilized into PolyHIPE membrane. The pore structure of PolyHIPE membrane and the presence of TBP enhance the stability of immobilized co-extractants. The optimal operating conditions for the separation of Mn (II) and Co (II) are feeding phase at pH 5.5, sulfuric acid concentration in the stripping phase of about 50 g/L and stirring speed at 400 rpm. The D2EHPA/TBP co-extractants ratio of 5:1 shows synergetic effect on Mn/Co separation factor about 22.74. The removal rate and recovery rate of Mn (II) is about 98.4 and 97.1%, respectively, while for Co (II) the transport efficiency is insignificant. The kinetic study of Mn (II) transport shows that high initial flux, $J_f^o=80.1({\mu}mol/m^2s)$, and maxima stripping flux, $J_s^{max}=20.8({\mu}mol/m^2s)$, can be achieved with D2EHPA/TBP co-extractants immobilized PolyHIPE membrane. The stability and reusability study shows that the membrane can maintain a long term performance with high efficiency. High purity of Co (II) and Mn (II) can be recovered from the feeding phase and stripping phase, respectively.

Keywords

References

  1. Akita, S. and Takeuchi, H. (1992), "Sorption and separation of divalent metals by a macromolecular resin containing organophosphorus acids", J. Chem. Eng., 37(3), 303-306.
  2. Alguacil, F.J. (2002), "Facilitated transport and separation of manganese and cobalt by a supported liquid membrane using DP-8R as a mobile carrier", Hydrometall., 65(1), 9-14. https://doi.org/10.1016/S0304-386X(02)00059-2
  3. Alguacil, F.J. and Alonso, M. (2005), "Separation of zinc (II) from cobalt (II) solutions using supported liquid membrane with DP-8R (di(2-ethylhexyl) phosphoric acid) as a carrier", Sep. Purif. Technol., 41(2), 179-184. https://doi.org/10.1016/j.seppur.2004.06.010
  4. Alguacil, F.J., Alonso, M. and Sastre, A.M. (2005), "Facilitated supported liquid membrane transport of gold(I) and gold (III) using Cyanex(R)921", J. Membr. Sci., 252(1-2), 237-244. https://doi.org/10.1016/j.memsci.2004.12.011
  5. Baaden, M., Burgard, M. and Wipff, A.G. (2001), "TBP at the water-oil interface: The effect of TBP concentration and water acidity investigated by molecular dynamics simulations", J. Phys. Chem. B, 105(45), 11131-11141. https://doi.org/10.1021/jp011890n
  6. Baba, Y., Kubota, F., Goto, M., Cattrall, R.W. and Kolev, S.D. (2016), "Separation of cobalt (II) from manganese (II) using a polymer inclusion membrane with N-[N,N-di(2-ethylhexyl) aminocarbonyl methyl) glycine(D2EHAG) as the extractant/carrier", J. Chem. Technol. Biotechnol., 91(5), 1320-1326. https://doi.org/10.1002/jctb.4725
  7. Bao, S., Zheng, R., Zhang, Y. and Chen, B. (2018), "Adsorption of vanadium (IV) on the synthesized D2EHPA-TBP impregnated resin", J. Chem. Appl. Chem. Eng., 2(1), 1-4.
  8. Batchu, N.K., Sone, C.H. and Lee, M.S. (2014), "Solvent extraction in equilibrium and modeling studies of manganese from sulfate solutions by a mixture of Cyanex 301 and TBP", Hydrometall., 144, 1-6. https://doi.org/10.1016/j.hydromet.2014.01.009
  9. Benjjar, A., Hor, M., Riri, M., Eljaddi, T., Kamal, O., Lebrun, L. and Hlaibi, M. (2012), "A new supported liquid membrane (SLM) with methyl cholate for facilitated transport of dichromate ions from mineral acids: Parameters and mechanism relating to the transport", J. Mater. Environ. Sci., 3(5), 826-839.
  10. Biswas, R.K., Habib, M.A. and Mondal, M.G.K. (2005), "Kinetics and mechanism of stripping of Mn (II)-D2EHPA complex by sulphuric acid solution", Hydrometall., 80(3), 186-195. https://doi.org/10.1016/j.hydromet.2005.06.013
  11. Bruce, A.M. (2013), Ion Exchange and Solvent Extraction-Volume 21, Supramolecular Aspects of Solvent Extraction, 1st Edition, Taylor & Francis Group, CRC Press, Boca Raton.
  12. Chen, J.H., Hsu, K.C. and Chang, Y.M. (2013), "Surface modification of hydrophobic resin with tricaprylmethylammonium chloride for the removal of trace hexavalent chromium", Ind. Eng. Chem. Res., 52(33), 11685-11694. https://doi.org/10.1021/ie401233r
  13. Chen, J.H., Le, T.T.M. and Hsu, K.C. (2017), "Cr (VI) separation by PolyHIPE membrane immobilized with Aliquat 336 by solvent-nonsolvent method", Membr. Water Treat., 8(6), 575-590. https://doi.org/10.12989/MWT.2017.8.6.575
  14. Chen, J.H., Le, T.T.M. and Hsu, K.C. (2018), "Application of PolyHIPE membrane with Tricaprylmethylammonium chloride for Cr (VI) ions separation: Parameters and mechanism of transport relating to the pore structure", Membr., 8(1), 11. https://doi.org/10.3390/membranes8010011
  15. Colthup, N.B., Daly, L.H. and Wiberley, S.E. (1990), Introduction to Infrared and Raman Spectroscopy, 3rd Edition, Academic Press, New York, U.S.A., London, U.K.
  16. Derrick, M.R., Stulik, D. and Landry, J.M. (1999), Infrared Spectroscopy in Conservation Science: Scientific Tools for Conservation, Getty Conservation Institute, Los Angeles, California, U.S.A.
  17. Dinkar, A.K., Singh, S.K., Tripathi, S.C., Gandhi, P.M., Verma, R. and Reddy, A.V.R. (2013), "Carrier facilitated transport of thorium from HCl medium using Cyanex 923 in n-dodecane containing supported liquid membrane", J. Radioanal. Nucl. Chem., 298(1), 707-715. https://doi.org/10.1007/s10967-013-2576-x
  18. Draa, M.T., Belaid, T. and Benamo, M. (2004), "Extraction of Pb (II) by XAD7 impregnated resins with organophosphorus extractants (DEHPA, IONQUEST 801, CYANEX 272)", Sep. Sci. Technol., 40(1), 77-86.
  19. Epstein, N. (1989), "On tortuosity and the tortuosity factor in flow and diffusion through porous media", Chem. Eng. Sci., 44(3), 777-779. https://doi.org/10.1016/0009-2509(89)85053-5
  20. Fatmehsari, D.H., Darvishi, D., Etemadi, S., Hollagh, A.E., Alamdari, E.K. and Salardini, A.A. (2009), "Interaction between TBP and D2EHPA during Zn, Cd, Mn, Cu, Co and Ni solvent extraction: A thermodynamic and empirical approach", Hydrometall., 98(1-2), 143-147. https://doi.org/10.1016/j.hydromet.2009.04.010
  21. Ferraz, H.C., Duarte, L.T., Alves, M. Di Luccio, T.L.M., Habert, A.C. and Borges, C.P. (2007), "Recent achievements in facilitated transport membranes for separation processes", Braz. J. Chem. Eng., 24(1), 101-118. https://doi.org/10.1590/S0104-66322007000100010
  22. Gambill, W.R. (1959), "How to estimate mixtures viscosities", Chem. Eng., 66(5), 151-152.
  23. Huang, D., Huang, K., Chen, S., Liu, S. and Yu, J. (2008), "Rapid reaction diffusion model for the enantio separation of phenylalanine across hollow fiber supported liquid membrane". Sep. Sci. Technol., 43(2), 259-272. https://doi.org/10.1080/01496390701787057
  24. Huang, T.C. and Juang, R.S. (1986), "Extraction equilibrium of zinc from sulfate media with Bis(2-ethylhexyl) phosphoric acid", Ind. Eng. Chem. Fundam., 25(4), 752-757. https://doi.org/10.1021/i100024a046
  25. Jerabek, K., Hankova, L., Strikovsky, A.G. and Warshawsky, A. (1996), "Solvent impregnated resins: Relation between impregnation process and polymer support morphology I. Di-(2-ethylhexyl) dithiophosphoric acid", React. Funct. Polym., 28(2), 201-207. https://doi.org/10.1016/1381-5148(95)00082-8
  26. Juang, R.S. (1993), "Modeling of the competitive permeation of cobalt and nickel in a di(2-thylhexyl)phosphoric acid supported liquid membrane process", J. Membr. Sci., 85(2), 157-166. https://doi.org/10.1016/0376-7388(93)85164-R
  27. Kongolo, K., Mwema, D.M., Kyony, P.M. and Mfumu, K. (2000), Proceedings of the XXI International Mineral Processing Congress, Rome, Italy, July.
  28. Lee, J.C., Jeong, J., Chung, K.S. and Kobayashi, M. (2004), "Active facilitated transport and separation of Co in Co-Ni sulfate solution by hollow fiber supported liquid membrane containing HEH(EHP)", Sep. Sci. Technol., 39(7), 1519 -1533. https://doi.org/10.1081/SS-120030794
  29. Li, H., Wang, Z., Chen, L. and Huang, X. (2009), "Research on advanced materials for li-ion batteries", Adv. Mater., 21(45), 4593-4607. https://doi.org/10.1002/adma.200901710
  30. Mehmet, K., Hamza, K.A., Ahmet, K., Nurcan, A., Ahmet, O.G. and Mustafa, A. (2011), "A kinetic study of mercury (II) transport through a membrane assisted by new transport reagent", Chem. Cent. J., 5(1), 43-49. https://doi.org/10.1186/1752-153X-5-43
  31. Mulder, M. (1991), Basic Principles of Membrane Technology, Kluer Academic Publishers Dordrecht/Boston/London.
  32. Nitta, N., Wu, F., Lee, J.T. and Yushin, G. (2015), "Li-ion battery materials: Present and future", Mater. Today, 18(5), 252-264. https://doi.org/10.1016/j.mattod.2014.10.040
  33. Othman, N., Harruddin, N., Idris, A., Ooi, Z., Fatiha, N. and Sulaiman, R.N.R. (2016), "Fabrication of polypropylene membrane via thermally induced phase separation as a support matrix of tridodecylamine supported liquid membrane for red 3BS dye removal", Desalinat. Water Treat., 57(26), 12287-12301. https://doi.org/10.1080/19443994.2015.1049554
  34. Pospiech, B. (2014a), "Selective recovery of cobalt (II) towards lithium (I) from chloride media by transport across polymer inclusion membrane with triisooctylamine", Pol. J. Chem. Technol., 16(1), 15-20. https://doi.org/10.2478/pjct-2014-0003
  35. Pospiech, B. (2014b), "Synergistic solvent extraction and transport of Zn(II) and Cu(II) across polymer inclusion membranes with mixture of TOPO and Aliquat 336", Sep. Sci. Technol., 49(11), 1706-1712. https://doi.org/10.1080/01496395.2014.906456
  36. Rajewski, J. and Łobodzin, P. (2016), "An experimental analysis of the transport mechanism of chromium(III) ions in the polymer inclusion membrane system stract", Problemy Eksploatacji, 1, 105-117.
  37. Rhlalou, T., Ferhat, M., Frouji, M.A., Langevin, D., Metayer, M. and Verchere, J.F. (2000), "Facilitated transport of sugars by a resorcinarene through a supported liquid membrane", J. Membr. Sci., 168(1-2), 63-73. https://doi.org/10.1016/S0376-7388(99)00301-4
  38. Richard, W.B. (2012), Membrane Technology and Applications, 3rd Edition, McGraw-Hill.
  39. Silverstein, M.S. (2014), "PolyHIPEs: Recent advances in emulsion-templated porous polymers", Prog. Polym. Sci., 39(1), 199-234. https://doi.org/10.1016/j.progpolymsci.2013.07.003
  40. Singare, P.U., Lokhande, R. and Madyal, R.S. (2011), "Thermal degradation studies of some strongly acidic", O. J. Phys. Chem., 1(2), 45-54. https://doi.org/10.4236/ojpc.2011.12007
  41. Swain, B., Sarangi, K. and Das, R.P. (2004a), "Effect of different anions on separation of copper and zinc by supported liquid membrane using TOPS-99 as mobile carrier", J. Membr. Sci., 243(1-2), 189-194. https://doi.org/10.1016/j.memsci.2004.06.016
  42. Swain, B., Sarangi, K. and Das, R.P. (2004b), "Separation of cadmium and zinc by supported liquid membrane using TOPS-99 as mobile carrier", Sep. Sci. Technol., 39(9), 2171-2188. https://doi.org/10.1081/SS-120039305
  43. Swain, B.S., Jeong, J., Lee, J.C. and Lee, G.H. (2007), "Separation of Co (II) and Li (I) by supported liquid membrane using Cyanex 272 as mobile carrier", J. Membr. Sci., 297(1-2), 253-261. https://doi.org/10.1016/j.memsci.2007.03.051
  44. Velicky, M., Tam, K.Y. and Dryfe, R.A.W. (2014), "Mechanism of ion transfer in supported liquid membrane systems: Electrochemical control over membrane distribution", Analy. Chem., 86(1), 435-442. https://doi.org/10.1021/ac402328w
  45. Wilke, C.R. and Chang, P. (1955), "Correlation of diffusion coefficients in dilute solutions", AICHE J., 1(2), 264-274. https://doi.org/10.1002/aic.690010222
  46. Yang, Q., Chung, T.S., Xiao, Y. and Wang, K. (2007), "The development of chemically modified P84 Co-polyimide membranes as supported liquid membrane matrix for Cu(II) removal with prolonged stability", Chem. Eng. Sci., 62(6), 1721-1729. https://doi.org/10.1016/j.ces.2006.12.022
  47. Zha, F.F., Fane, A.G. and Fell, C.J.D. (1995), "Instability mechanisms of supported liquid membranes in phenol transport processes", J. Membr. Sci., 107(1-2), 59-74. https://doi.org/10.1016/0376-7388(95)00104-K
  48. Zhang, W., Liu J., Ren, Z., Wang, S., Du, C. and Ma, J. (2009), "Kinetic study of chromium (VI) facilitated transport through a bulk liquid membrane using tri-n-butyl phosphate as carrier", Chem. Eng. J., 150(1), 83-89. https://doi.org/10.1016/j.cej.2008.12.009
  49. Zhang, W.S., Cheng, C.Y. and Pranolo, Y. (2010), "Investigation of methods for removal and recovery of manganese in hydrometallurgical processes", Hydrometall., 101(1-2), 58-63. https://doi.org/10.1016/j.hydromet.2009.11.018
  50. Zheng, R., Bao, S., Zhang, Y. and Chen, B. (2018), "Synthesis of Di-(2-ethylhexyl) phosphoric acid (D2EHPA)-tributyl phosphate (TBP) impregnated resin and application in adsorption of vanadium (IV)", Miner., 8(5), 206. https://doi.org/10.3390/min8050206