Korean Chemical Engineering Research

  • 제56권4호
  • /
  • Pages.536-541
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  • 2018
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  • 0304-128X(pISSN)
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  • 2233-9558(eISSN)
한국화학공학회 (The Korean Institute of Chemical Engineers)
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Application of Flory-Treszczanowicz-Benson model and Prigogine-Flory-Patterson theory to Excess Molar Volumes of Isomers of Propanol with Cyclohexane or n-Hexane

  • Gahlyan, Suman (Department of Chemistry, Deenbandhu Chhotu Ram University of Science and Technology) ;
  • Verma, Sweety (Department of Chemistry, Deenbandhu Chhotu Ram University of Science and Technology) ;
  • Rani, Manju (Department of Chemical Engineering, Deenbandhu Chhotu Ram University of Science and Technology) ;
  • Maken, Sanjeev (Department of Chemistry, Deenbandhu Chhotu Ram University of Science and Technology)
  • 투고 : 2018.02.20
  • 심사 : 2018.06.04
  • 발행 : 2018.08.01
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초록

Excess molar volumes ($V_m^E$) of binary mixtures of 1-propanol or 2-propanol (1) + cyclohexane or n-hexane (2) were measured with V-shaped dilatometer at 303.15 K. The $V_m^E$ data for these mixtures varied as: 2-propanol > 1-propanol and were higher for cyclohexane than n-hexane for both propanol systems. The experimental data were correlated with Redlich-Kister polynomial. The $V_m^E$ data were interpreted qualitatively as well as quantitatively in terms of Flory-Treszczanowicz-Benson model and Prigogine-Flory-Patterson theory. Both models correctly described the sign and shape of $V_m^E$ vs $x_1$ curves. The values calculated by both the models agree well with the experimental data.

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참고문헌

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피인용 문헌

  1. Optical and Acoustic Properties of Binary Mixtures of Butanol Isomers as Oxygenates with Cyclohexane, Benzene and Toluene at 308.15 K vol.56, pp.5, 2018, https://doi.org/10.9713/kcer.2018.56.5.663