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http://dx.doi.org/10.9713/kcer.2018.56.4.536

Application of Flory-Treszczanowicz-Benson model and Prigogine-Flory-Patterson theory to Excess Molar Volumes of Isomers of Propanol with Cyclohexane or n-Hexane  

Gahlyan, Suman (Department of Chemistry, Deenbandhu Chhotu Ram University of Science and Technology)
Verma, Sweety (Department of Chemistry, Deenbandhu Chhotu Ram University of Science and Technology)
Rani, Manju (Department of Chemical Engineering, Deenbandhu Chhotu Ram University of Science and Technology)
Maken, Sanjeev (Department of Chemistry, Deenbandhu Chhotu Ram University of Science and Technology)
Publication Information
Korean Chemical Engineering Research / v.56, no.4, 2018 , pp. 536-541 More about this Journal
Abstract
Excess molar volumes ($V_m^E$) of binary mixtures of 1-propanol or 2-propanol (1) + cyclohexane or n-hexane (2) were measured with V-shaped dilatometer at 303.15 K. The $V_m^E$ data for these mixtures varied as: 2-propanol > 1-propanol and were higher for cyclohexane than n-hexane for both propanol systems. The experimental data were correlated with Redlich-Kister polynomial. The $V_m^E$ data were interpreted qualitatively as well as quantitatively in terms of Flory-Treszczanowicz-Benson model and Prigogine-Flory-Patterson theory. Both models correctly described the sign and shape of $V_m^E$ vs $x_1$ curves. The values calculated by both the models agree well with the experimental data.
Keywords
Excess volume; Propanol; Cyclohexane; n-Hexane; Flory-Treszczanowicz-Benson model; Prigogine-Flory-Patterson theory;
Citations & Related Records
Times Cited By KSCI : 3  (Citation Analysis)
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