DOI QR코드

DOI QR Code

미세 구조 변화에 따른 ZnS 세라믹의 중적외선 투과 특성 연구

A Study of Middle Infrared Transparent Properties of ZnS Ceramics by the Change of Micro Structure

  • 박창순 (한국세라믹기술원 전자소재부품센터) ;
  • 여서영 (한국세라믹기술원 전자소재부품센터) ;
  • 권태형 (한국세라믹기술원 전자소재부품센터) ;
  • 박운익 (한국세라믹기술원 전자소재부품센터) ;
  • 윤지선 (한국세라믹기술원 전자소재부품센터) ;
  • 정영훈 (한국세라믹기술원 전자소재부품센터) ;
  • 홍연우 (한국세라믹기술원 전자소재부품센터) ;
  • 조정호 (한국세라믹기술원 전자소재부품센터) ;
  • 백종후 (한국세라믹기술원 전자소재부품센터)
  • Park, Chang-Sun (Electronic Materials & Component Center, Korea Institute of Ceramic Engineering & Technology) ;
  • Yeo, Seo-Yeong (Electronic Materials & Component Center, Korea Institute of Ceramic Engineering & Technology) ;
  • Kwon, Tae-Hyeong (Electronic Materials & Component Center, Korea Institute of Ceramic Engineering & Technology) ;
  • Park, Woon-ik (Electronic Materials & Component Center, Korea Institute of Ceramic Engineering & Technology) ;
  • Yun, Ji-Sun (Electronic Materials & Component Center, Korea Institute of Ceramic Engineering & Technology) ;
  • Jeong, Young-Hun (Electronic Materials & Component Center, Korea Institute of Ceramic Engineering & Technology) ;
  • Hong, Youn-Woo (Electronic Materials & Component Center, Korea Institute of Ceramic Engineering & Technology) ;
  • Cho, Jeong-Ho (Electronic Materials & Component Center, Korea Institute of Ceramic Engineering & Technology) ;
  • Paik, Jong-Hoo (Electronic Materials & Component Center, Korea Institute of Ceramic Engineering & Technology)
  • 투고 : 2017.10.11
  • 심사 : 2017.10.17
  • 발행 : 2017.11.01

초록

Transparent ZnS ceramics were synthesized by hydrothermal synthesis ($180^{\circ}C$ for 70 h), and were sintered by a hot press process at $950^{\circ}C$. To confirm the optical properties of the ZnS ceramics after sintering for various sintering holding times, we performed X-ray diffraction analysis, scanning electron microscopy, and Fourier-transform-infrared spectroscopy. The ZnS nanopowders was found to be single-phase (cubic) without any hexagonal phase. However, the hexagonal phase is formed and increases in content with increasing sintering holding time. The density of the ZnS ceramics was above 99.7%, except for the unsintered one. The ZnS ceramics showed high transmittance (~70%) when sintered for more than 2 h.

키워드

참고문헌

  1. Y. Li and Y. Wu, J. Am. Ceram. Soc., 98, 2972 (2015). [DOI: https://doi.org/10.1111/jace.13781]
  2. W. L. Davidson, Phys. Rev., 74, 116 (1948).
  3. J. Huang, Y. Yang, S. Xue, B. Yang, S. Liu, and J. Shen, Appl. Phys. Lett., 70, 2335 (1997). [DOI: https://doi.org/10.1063/1.118866]
  4. S. Okur, N. Uzar, N. Tekguzel, A. Erol, and M. C. Arikan, Physica E, 44, 1103 (2012). [DOI: https://doi.org/10.1016/j.physe.2010.08.015]
  5. M. Bredol and J. Merikhi, J. Mater. Sci., 33, 471 (1998). [DOI: https://doi.org/10.1023/A:1004396519134]
  6. P. Calandra, M. Goffredi, and V. T. Liveri, Colloids Surf. A, 160, 9 (1999). [DOI: https://doi.org/10.1016/S0927-7757(99)00256-3]
  7. P. Biswas, R. S. Kumar, P. Ramavath, V. Mahendar, G.V.N. Rao, U. S. Hareesh, and R. Johnson, J. Alloys Compd., 496, 273 (2010). [DOI: https://doi.org/10.1016/j.jallcom.2010.01.120]
  8. C. Chlique, G. Delaizir, O. Merdrignac-Conance, C. Roucau, M. Dolle, P. Rozier, V. Bouquet, and X. H. Zhang, Opt. Mater., 33, 706 (2011). [DOI: https://doi.org/10.1016/j.optmat.2010.10.008]
  9. Y. D. Kim, K. Sonezaki, H. Maeda, and A. Kato, J. Mater. Sci., 32, 5101 (1997). [DOI: https://doi.org/10.1023/A:1018613316157]
  10. Z. Shizen, M. A. Hongli, R. Jean, M. C. Odile, A. Jean-Luc, L. Jacques, and Z. Xianghua, Optoelectron. Adv. Mater. Rapid Commun., 1, 667 (2007). [DOI: https://hal.archives-ouvertes.fr/hal-01465328]
  11. J. S. McCloy and B. G. Potter, Opt. Mater. Express, 3, 1273 (2013). [DOI: https://doi.org/10.1364/OME.3.001273]
  12. C. I. Kim, Y. B. Kim, S. Y. Yeo, Y. W. Hong, J. S. Yun, W. I. Park, Y. H. Jeong, J. H. Cho, and J. H. Paik, J. Korean Inst. Electr. Electron. Mater. Eng., 30, 349 (2017). [DOI: https://doi.org/10.4313/JKEM.2017.30.6.349]
  13. T. Ueno, M. Hasegawa, M. Yoshimura, H. Okada, T. Nishioka, K. Teraoka, A. Fujii, and S. Nakayama, SEI Tech. Rev., 69, 48 (2009).
  14. X. Fang, T. Zhai, U. K. Gautam, L. Li, L. Wu, Y. Bando, and D. Golberg, Prog. Mater Sci., 56, 175 (2011). [DOI: https://doi.org/10.1016/j.pmatsci.2010.10.001]
  15. B. H. Hwang, H. B. Xu, S. J. Park, S. E. Choi, S. Nahm, Y. W. Hong, J. H. Paik, T, H. Shin, and J. S. Kang, Ceram. Int., 42, 11700 (2016). [DOI: https://doi.org/10.1016/j.ceramint.2016.04.088]