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Determination of Analytical Approach for Ambient PM2.5 Free Amino Acids using LC-MSMS

LC-MSMS를 이용한 대기 중 PM2.5 유리아미노산 분석 방법 연구

  • Bae, Min-Suk (Department of Environmental Engineering, Mokpo National University) ;
  • Park, Da-Jeong (Department of Environmental Engineering, Mokpo National University) ;
  • Lee, Kwon-Ho (Department of Atmospheric Environment Science, Gangneung-Wonju National University) ;
  • Cho, Seung-Sik (Department of Pharmacy, College of Pharmacy, Mokpo National University) ;
  • Lee, Kwang-Yul (School of Earth Sciences and Environmental Science and Engineering, Gwangju Institute of Science and Technology) ;
  • Park, Kihong (School of Earth Sciences and Environmental Science and Engineering, Gwangju Institute of Science and Technology)
  • 배민석 (목포대학교 환경공학과) ;
  • 박다정 (목포대학교 환경공학과) ;
  • 이권호 (강릉원주대학교 대기환경학과) ;
  • 조승식 (목포대학교 약학대학 약학과) ;
  • 이광열 (광주과학기술원 지구환경공학부) ;
  • 박기홍 (광주과학기술원 지구환경공학부)
  • Received : 2016.12.20
  • Accepted : 2017.01.16
  • Published : 2017.02.28

Abstract

Atmospheric nitrogen containing organic compounds(e.g. amino acids) has attracted considerable attention from the viewpoint of the oceanic biogeochemical cycle of nitrogen as well as the long range transfer. However, only a few measurements of organic nitrogen compounds have been conducted due to analytical difficulties. In this study, total of nine amino acids such as Glutamic acid, Histidine, Arginine, Tyrosine, Cystine, Valine, Methionine, Phenylalanine, Lysine have been analytically determined by Liquid Chromatography - Mass Spectrometry Mass Spectrometry (LC-MSMS). As results, Fragmentor Voltage (FV), Precursor Ion, Collision Energy, Product Ion related to individual amino acid compounds are shown. Based on the operational conditions, Lysine, Glutamine Acid, Tyrosine were analyzed during the China Oriented Smog Period. High concentrations of Lysine, Glutamine Acid, and Tyrosine are discussed with organic carbon (OC), elemental carbon (EC), and water soluble ions. The results can provide to understand the sources with aging process related to amino acids influenced by the long-range transport from the Yellow Sea area.

Keywords

References

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