한국토양비료학회지 (Korean Journal of Soil Science and Fertilizer)

  • 제50권6호
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  • Pages.497-508
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  • 2017
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  • 0367-6315(pISSN)
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  • 2288-2162(eISSN)
한국토양비료학회 (Korean Society of Soil Science and Fertilizer)
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Identification of a Proper Phytoavailable Arsenic Extraction Method Associated with Arsenic Concentration in Edible Part of three Crops in Soils Near Abandoned Mining Areas

  • Yoon, Jung-Hwan (Department of Environmental Horticulture, University of Seoul) ;
  • Kim, Young-Nam (Department of Entomology, the Ohio State University, OARDC) ;
  • Lee, Dan-Bi (Department of Environmental Horticulture, University of Seoul) ;
  • Kim, Kwon-Rae (Department of Agronomy & Medicinal Plant Resources, Gyeong Nam National University of Science and Technology) ;
  • Kim, Won-Il (National Academy of Agricultural Science) ;
  • Kim, Kye-Hoon (Department of Environmental Horticulture, University of Seoul)
  • 투고 : 2017.10.15
  • 심사 : 2017.11.06
  • 발행 : 2017.12.31
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초록

This study aimed to investigate correlations between concentrations of extractable Arsenic (As) with varying chemical solutions (0.1 M $Ca(NO_3)_2$, 0.1 M $(NH_4)2HPO_4$, 0.5 M EDTA, Mehlich 3, and 0.5 M $NaHCO_3$) and those of As in crops, and then to seek the most suitable soil extraction method for predicting the potential of As uptake in crops cultivated in soils contaminated with As. For a mesocosm experiment, pepper (Capsicum annuum L.), soybean (Glycine max L.), and rice (Oryza sativa L.) were cultivated for three months in pots containing soils taken from the arable areas near abandoned mines in Korea. Following the cultivation, soil pH and DOC significantly increased by treatments of lime and lime plus compost, respectively, while insignificant influences in changing total and all extractable As concentrations were found in all soils. Arsenic concentration in edible part of all crops considerably depended on the extractable As concentration in the soils, particularly with Mehlich 3. All extractable As concentrations in the soils of C. annuum and G. max were significantly correlated with As concentration in their edible parts. For O. sativa, the extractable concentrations of Mehlich 3 ($R^2$: 0.18 at p: 0.006) and EDTA ($R^2$: 0.11 at p: 0.036) showed only marked relationships with As concentration in the edible part. These results may indicate that the Mehlich 3 and EDTA are soil extractants to determine phytoavailable As in soil that provide better prediction for As transfer from soil to crop.

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