Journal of Conservation Science (보존과학회지)

The Korean Society Of Conservation Science For Cultural Heritage (한국문화재보존과학회)
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Mineral Compositions of Korean Dancheong Pigment Products using Quantitative XRD

정량 X-선 회절분석을 이용한 국내시판 단청안료의 광물조성 연구

  • Moon, Dong Hyeok (Division of Conservation Science, National Research Institute of Cultural Heritage) ;
  • Han, Min Su (Division of Conservation Science, National Research Institute of Cultural Heritage) ;
  • Jeong, Hye Young (Division of Restoration Technology, National Research Institute of Cultural Heritage) ;
  • Go, In Hee (Division of Restoration Technology, National Research Institute of Cultural Heritage) ;
  • Cho, Hyen Goo (Department of Geology, Gyeongsang National University)
  • 문동혁 (국립문화재연구소 보존과학연구실) ;
  • 한민수 (국립문화재연구소 보존과학연구실) ;
  • 정혜영 (국립문화재연구소 복원기술연구실) ;
  • 고인희 (국립문화재연구소 복원기술연구실) ;
  • 조현구 (경상대학교 지질과학과)
  • Received : 2016.08.05
  • Accepted : 2016.09.19
  • Published : 2016.09.20
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Abstract

Mineral composition and content of 22 Korean Dancheong pigment products were obtained by Rietveld quantitative analysis. Jubosa, Hwang, Seokrok, Seokcheong and Hobun consist of pure cinnabar, orpiment, malachite, azurite and calcite (or aragonite), respectively. Whereas Seokganju, Hwangto, Noerok, Lapis lazuli, Baekto and Cockie hobun mainly consist of hematite, goethite, celadonite, lazurite, kaolin mineral and portlandite, respectively. And they all consist of soil minerals (quartz, feldspar, sericite and vermiculite) and filler minerals in the industry field (calcite, gypsum and anhydrite) at a different content. Quantitative XRD proved more useful method to determined exact mineral composition and content than chemical or microscopical data. If this method utilize for specification of natural pigment product, it is considered to be applicable in restoration technology and conservation science field.

본 연구는 현재 단청시공에 실제 사용되고 있는 국산 천연안료 제품 총 22종을 대상으로 리트벨트법을 활용한 정량 X-선 회절분석을 실시하여 구성성분의 조성과 함량 특성을 밝히고자 하였다. 분석결과, 주보사와 황, 석록, 석청, 호분 등의 제품들은 각각 거의 순수한 진사, 웅황, 공작석, 남동석 및 방해석 또는 아라고나이트로 구성된 것으로 판단된다. 반면, 석간주와 황토, 뇌록, 라피스라즐리, 백토, 꼬막호분 등의 제품들은 각각 적철석, 침철석, 뇌록석, 라주라이트, 고령석 및 포틀랜드석 등이 주구성광물이며, 그 외 석영, 장석, 견운모, 질석 등 일반적인 토양에 풍부한 광물과 방해석, 석고 및 경석고 등과 같이 산업계에서 충진제로 활용되는 광물들이 각 제품에 다양한 비율로 함유되어 있는 것으로 나타났다. 이와 같이 정량 X-선 회절분석을 통하여 화학조성분석이나 현미경관찰만으로는 획득하기 쉽지 않은 보다 구체적인 안료 제품들의 광물조성 및 그 함량 비에 대한 정보를 획득할 수 있었으며, 추후 이를 천연안료제품의 품질기준 설정에 활용하거나 대체원료수급 및 품질향상을 통한 보존과학연구 등에 다양한 방법으로 적용이 가능할 것으로 사료된다.

Keywords

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