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Studies on Transparent Sunscreen of Water-in-Oil Emulsion Type

유중수 타입의 외관이 투명한 자외선 차단 화장료에 관한 연구

  • Kwak, Jae-Hoon (Department of Cosmeceutical Science, Daegu Hanny University) ;
  • Cho, Yong-Hun (Department of Cosmeceutical Science, Daegu Hanny University) ;
  • Byun, Sang-Yo (Cosmetic Science Major, Dept. of Applied Biotechnology, Ajou University) ;
  • Kim, Tae Hoon (Department of Food Science and biotechnology, Daegu University)
  • Received : 2015.08.03
  • Accepted : 2015.09.24
  • Published : 2015.09.30

Abstract

This study is related to the developing method of a transparent sunscreen cosmetic which has waterproofing property and no white turbidity when applied to skin. The transparent sunscreen is prepared by exploiting refractive index difference between oil-phase and water-phase of water-in-oil(W/O) emulsion. The sunscreen according to this study is prepared as a W/O type emulsion so that it is water-stable and water resistance. Also, the stability of W/O type emulsion is developed by adjusting the content of oil phase part and water phase part. As a result of this studying, the transparent W/O emulsion is prepared by adjusting the refractive index of oil-phase and water-phase within 0.004 and it is found that the stability of the transparent sunscreen is increasing when the water phase part is over 75% (w/w) of the W/O emulsion. Through clinical test of transparent sunscreen, the value of sun protection Factor(SPF) and Protection Factor of UVA(PFA) were determined. SPF and PFA values of transparent sunscreen were indicated $30.99{\pm}1.65$ and $3.01{\pm}0.30$.

본 연구는 내수성을 지니고 사용 시 백탁 현상이 없는 투명한 외관을 가지는 자외선 차단 화장료 제재를 개발 하는 방법이다. 외관이 투명한 자외선 차단제는 유화물의 수상부와 유상부의 굴절률 차이에 따른 투명도를 통하여 외관이 투명한 유중수 타입의 자외선 차단제를 연구하였다. 지속성 및 내수성이 우수한 유중수 타입의 에멀젼을 연구하고 제형의 수상부 및 유상부의 비율을 조정하여 유중수형 유화의 안정성을 극대화시키는 방향으로 제형을 설계하는 연구를 수행 하였다. 연구 결과, 수상부와 유상부의 굴절률 차가 0.004이하일 때 투명한 유중수형 에멀전을 형성 할 수 있었으며, 내상부인 수상의 함량이 70% (w/w) 이상에서 안정한 유중수형 에멀젼을 형성하였다. 임상 시험을 통하여 투명한자외선차단제의 자외선 A 차단지수와 자외선 B차단 지수를 측정하였다. 그 결과, 자외선 A 차단지수는 $3.01{\pm}0.30$ 으로 나타났으며, 자외선 B 차단지수는 $30.99{\pm}1.65$로 측정되었다.

Keywords

References

  1. E. M. DeSimone,"Sunscreen and suntan products", handbook of nonpre-sciption drugs, 7th ed., Chapter 26, p.499-511, American Pharmaceutical Association, Washington, D.C(1982).
  2. K. Sato, A mechanism of UVA induced pigmentation and UVA Protection, SOFW J., 7, 12(2007).
  3. D. L. Bissett, D.P. Hannon and T. V. Orr, An animal model of solar-aged skin : histological, physical, and visible changes in UV-irradiated hairless mouse skin, Photochem. Photobiol, 46(3), 367-378 (1987). https://doi.org/10.1111/j.1751-1097.1987.tb04783.x
  4. R. G. Christine, A Edith, C, Monique, J, P, Ortonne, and B Robert, Nitric oxide produced by ultraviolet-irradiated keratinocytes stimulates melanogenesis. J. Clin. Invest., 99(4), 635(1997). https://doi.org/10.1172/JCI119206
  5. L. H. Kligman, and A. M. Kligman, The nature of photoaging : its prevent and repair. Photo-dermatology, 3(4), 215-227 (1986).
  6. M. A. Pathak, Sunscreens and their use in the preventive treatment of sunlight-unduced skin damage. J. dermatol surg. Oncol, 13(7), 739-750(1987). https://doi.org/10.1111/j.1524-4725.1987.tb00544.x
  7. S. R. Plastow, J. A. Harrison, & A. R. Young. Early changes in dermal collagen of mice exposed to chronic UVB irradiation and the effects of a UVB sunscreen. J investigative dermatology, 91(6), 590-592(1988). https://doi.org/10.1111/1523-1747.ep12477108
  8. F. O. Opawale, and D. J. Burgess, Influence of inter-facial properties of lipophilic surfactants on water-in-oil emulsion stability, J. Colloid and interface Sci., 8(4), 137(1998).
  9. M. J. Rosen, Relationship of sturcture to properties in surfactants. J. Am. Oil Chem. Soc, 51, 461-169(1974). https://doi.org/10.1007/BF02635155
  10. B. Tal-Figiel, The formation of stable W/O, O/W. W/O/W cosmetic emulsions in an ultrasonic field, Chem. Eng. Res. Des, 85(5), 730-734(2007). https://doi.org/10.1205/cherd06199
  11. M. P. Aronson, M. F. Petko, High concentrated water-in-oil emulsion : Influence of electrolyte on their properties and stability. J. Colloid and Interface Sci, 159(1), 134-149(1993). https://doi.org/10.1006/jcis.1993.1305
  12. G. A. van Aken, and F. D. Zoet, Coalescence in highly concentrated coarse emulsions. Langmuir, 16(18), 7131-7138 (2000). https://doi.org/10.1021/la0000419
  13. J. Z. Sun, M. C. E. Erickson and J. W. Parr, Refractive index matching and clear emulsions. J. Cosmet. Sci, 56, 253-265 (2005).
  14. J. M. Suk, et al, Characteristic of MED measurement Value of Trial Subjects from Ultraviolet Irradiation, J. Soc. Cosmet. Sci. Kor 39(3), 251-257(2013) https://doi.org/10.15230/SCSK.2013.39.3.251
  15. C. H. Villa, L. B. Lawson, Y. Li, and K. D. Papadopoulos, Internal coalescence as a mechanism of instability in water-in-oil-in-water double-emulsion globules, Langmuir, 19(2), 244-249(2003). https://doi.org/10.1021/la026324d
  16. J. M. Williams, High Iternal Phase Water-in-Oil Emulsions: Influence of surfactants and Cosurfactants on Emuldion Stability and Foam Quality, Langmuir, 7(7), 1370-1377(1991). https://doi.org/10.1021/la00055a014
  17. J. Czarnecki and K. Moran, On the stability Mechanism of Water-in-Oil Emulsion in Petroleum Systems, Energy Fuels, 19(5), 2074-2079(2005). https://doi.org/10.1021/ef0501400
  18. K. J. Lissant, Structure of high-internal-phase-ratio emulsions, J. Colloid Interface Sci., 47(2), 416(1974). https://doi.org/10.1016/0021-9797(74)90273-2