한국응용과학기술학회지 (Journal of the Korean Applied Science and Technology)

  • 제32권3호
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  • Pages.461-468
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  • 2015
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  • 1225-9098(pISSN)
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  • 2288-1069(eISSN)
한국응용과학기술학회 (The Korean Society of Applied Science and Technology)
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역상 HPLC에 의한 Fatty quaternary ammonium salt 4종 동시분석

Simultaneous determination of Fatty quaternary ammonium salt by RP-HPLC

  • 이용화 (호서대학교 한방화장품과학과) ;
  • 양재찬 (목원대학교 테크노과학대학 생의약화장품학부) ;
  • 김재광 (청운대학교 식품영양학과) ;
  • 이용섭 (호서대학교 한방화장품과학과)
  • Lee, Yong-Hwa (Hoseo University. Dept. of Herbal Cosmetic Science) ;
  • Yang, Jae-Chan (Mokwon University, College of Sciences & Technology, Division of Biomedicinal & Cosmetics) ;
  • Kim, Chi-Kwang (Chungwoon University, Department of human nutrition and food science) ;
  • Lee, Yong-Sub (Hoseo University. Dept. of Herbal Cosmetic Science)
  • 투고 : 2015.07.31
  • 심사 : 2015.09.21
  • 발행 : 2015.09.30
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초록

역상 HPLC에 의한 Cetyltrimetyl ammonium chloride(CTM), Stearamidopropyl dimetylamine(SAP), Behentriammonium chloride(BHT), Dihexadeyldimethyl ammonium chloride (DHDDM)의 양이온계면활성제 4종 동시 정량분석 방법을 개발하였다. 분석조건으로 분리관은 Alltech $C_{18}$($250mm{\times}4.6mm$ i.d., $5{\mu}m$)을 사용하였고, 검출기는 ELSD를 사용하였으며, 이동상은 0.2% TFA/Methanol의 기울기 용리에 의해 분석되었다. 이때 검량선의 상관계수($r^2$)는 $130{\sim}1980.5{\mu}g/mL$농도 범위에서 0.997이상 이었고, 검출한계, 정밀성이 우수하였다. 이 방법은 fatty quaternary ammonium salt 4종의 정량분석 가능함을 보여 주었다.

Simultanious quantitative determination of Cetyltrimetyl ammonium chloride(CTM), Stearamidopropyl dimetylamine(SAP), Behentriammonium chloride(BHT), Dihexadeyldimethyl ammonium chloride(DHDDM) was carried out by reversed phase HPLC. The 0.2% TFA/Methanol was used for the mobile phase of gradient conditions. An Alltech $C_{18}$($250mm{\times}4.6mm$ i.d., $5{\mu}m$)and the selected ELSD detector was applied. The analysis results of HPLC showed good linearity with correlation coefficient of $r^2=0.997$ in the rage of $130{\sim}1980.5{\mu}g/mL$ and detection limit.

키워드

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