동력기계공학회지 (Journal of Power System Engineering)

  • 제19권5호
  • /
  • Pages.86-92
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  • 2015
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  • 2713-8429(pISSN)
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  • 2713-8437(eISSN)
한국동력기계공학회 (The Korean Society for Power System Engineering)
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p-DCPD 제조 및 보트소재적용 연구

A Study on the Polymerization of Dicyclopentadiene Production and Applied to Boats Materials

  • 김시영 (부경대학교 기계시스템공학과) ;
  • 구수진 (부경대학교 방위과학기술연구소) ;
  • 주창식 (부경대학교 화학공학과) ;
  • 박주영 (경남지역산업 평가단)
  • Kim, Si-Young (Department of Mechanical System Engineering Department, Pukyong National University) ;
  • Koo, Su-Jin (Institute of Defense Science & Technology, Pukyong National University) ;
  • Ju, Chang-Sik (Department of Chemical Engineering, Pukyong National University) ;
  • Park, Joo-Young (Foundation of Gyeongnam Institute for Regional Evaluation)
  • 투고 : 2015.09.08
  • 심사 : 2015.10.05
  • 발행 : 2015.10.31
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초록

p-DCPD were prepared by in-suit ROMP polymerization using $MoCl_5$ and $Et_2AlCl$. The results showed that $MoCl_5:Et_2AlCl:DCPD$ mole ratio of 1:2.0:350 had the curing-time of 60sec and crosslinking degree of 90.44%. The curing time of DCPD polymerization by $MoCl_5/Et_2AlCl$ was shortened, and monomer conversion and crosslinking degree were decreased with temperature and the number of moles of $MoCl_5$ and $Et_2AlCl$. $MoCl_5$ and $Et_2AlCl$ is damaged its function by the reaction with the air in the atmosphere and did't proceed the polymerization properly.

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참고문헌

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피인용 문헌

  1. Mechanical Properties and Curing Characteristic of Epoxy Resin by Diluent Addition vol.31, pp.5, 2015, https://doi.org/10.13000/jfmse.2019.10.31.5.1317