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http://dx.doi.org/10.9726/kspse.2015.19.5.086

A Study on the Polymerization of Dicyclopentadiene Production and Applied to Boats Materials  

Kim, Si-Young (Department of Mechanical System Engineering Department, Pukyong National University)
Koo, Su-Jin (Institute of Defense Science & Technology, Pukyong National University)
Ju, Chang-Sik (Department of Chemical Engineering, Pukyong National University)
Park, Joo-Young (Foundation of Gyeongnam Institute for Regional Evaluation)
Publication Information
Journal of Power System Engineering / v.19, no.5, 2015 , pp. 86-92 More about this Journal
Abstract
p-DCPD were prepared by in-suit ROMP polymerization using $MoCl_5$ and $Et_2AlCl$. The results showed that $MoCl_5:Et_2AlCl:DCPD$ mole ratio of 1:2.0:350 had the curing-time of 60sec and crosslinking degree of 90.44%. The curing time of DCPD polymerization by $MoCl_5/Et_2AlCl$ was shortened, and monomer conversion and crosslinking degree were decreased with temperature and the number of moles of $MoCl_5$ and $Et_2AlCl$. $MoCl_5$ and $Et_2AlCl$ is damaged its function by the reaction with the air in the atmosphere and did't proceed the polymerization properly.
Keywords
DCPD(Dicyclopentadiene); p-DCPD; $Et_2AlCl$(Diethylalumiumchloride); $MoCl_5$; ROMP;
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Times Cited By KSCI : 3  (Citation Analysis)
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